原子吸收光谱仪用于沉积物中锡分析的方法研究

１９９４－１９９６年间,利用原子吸收光谱仪,对沉积物中有机锡和总锡的石墨炉原子吸收分析方法进行了优化,探讨了分析过程中的仪器条件和改进剂类型。优化后方法的检出限为 ２．４５μｇ／Ｌ（ＴＰＴ－锡）,特征浓度（相当于产生 １％净吸收或 ０．００４ ４吸光度的待测元素浓度）为４８２μｇ／Ｌ（ＴＰＴ－锡）。在这一条件下,采用盐酸酸化－正己烷萃取－氢氧化钠回洗－硝酸氧化的预处理方法,可以使沉积物样品中三苯基氯化锡（Ｔｒｉｐｈｅｎｙｌｔｉｎ, ＴＰＴ）的检出限达到４１ｎｇ／ｇ（ＴＰＴ－锡）,回收率为 １０６％。应用这一方法对野外模拟实验和黄岛电厂出水口的沉积物样品进行了分析,结果表明,这一方法能够满足对沉积物样品中锡进行分析的要求。     

The formation of large diameter plant fossil moulds and the Walton theory of compaction

Hollow plant organs can react in different ways to the forces exerted during compaction of the surrounding sediments. Large infilled lycophyte stems, lying flat in the sediments, flatten and expand in width. The width of the mould that is ultimately formed will therefore approach half the original circumference of the stem rather than being equal to its original diameter.     

Distribution Characteristics of Heavy Metals and Grain Size of Sediments from Hailing Bay, China

Introduction Hailing Bay located in western Guangdong province is an important marine aquaculture base and a famous scenic spot. Moyang River which flows across Yangjiang is the major runoff and polluted source in the sea area of Hailing Bay. Hailing Bank ( approximately 5 000 m ) which was built to connect Hailing Island and the continent in 1964 has blocked the natural circulation of suspended sand and pollutants in seawater. Water flux through the Yangjiang harbor extensively decreases …     

Extended Sediment Quality Rating for Trace Elements in Urban Waters – Case Study Klinke,Germany

The European Water Framework Directive (WFD) commits European Union member states to achieving good ecological status in all water bodies by 2015. For sediments the definition of good chemical status is based on numerical sediment quality guidelines. The aqua regia fraction is thus used for the evaluation of heavy metal concentrations in sediments. The chemical constituents in sediments responsible for mobility and toxicity are not considered generally. This article presents the combining of the sequential BCR procedure, for determining the chemical species of relevant elements, with the geoaccumulation index principle a numerical classification method for sediment quality guidelines. Using the BCR method it can be demonstrated that changes in element speciation can lead to more highly mobile species of trace elements which may affect the hazardous potential of sediments despite the “good chemical status” classification for aqua regia digestions. The Klinke stream is an urban surface water body located in Magdeburg, the state capital of Saxony‐Anhalt, Germany. Using this stream as an example it is shown that this additional information helps to describe the dynamics and discharge of the trace elements Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Sr, Mo, Pd, Cd, Sb, Ba, Pb, Bi, and U into the Elbe River from urban water bodies.     

Evaluation of sediment contamination in the Red Sea coastal area combining multiple pollution indices and multivariate statistical techniques

In the recent years,the Red Sea coast of Yemen has been severely affected by intensive anthropogenic activities.The current study constitutes a thorough inquiry to evaluate the extent of heavy metals pollution in Yemen's Red Sea coast sediment and identifies the possible sources of pollution.The concentrations of five metals(copper(Cu),zinc(Zn),cadmium(Cd),lead(Pb),and nickel(Ni))collected from nine sites along the Red Sea coast of Yemen were assessed using an atomic absorption spectrophotometer(ASS).Sediment quality indices,such as the sediment quality guidelines(SQGs),potential ecological risk(RI),contamination factor(CF),pollution load index(PLI),geoaccumulation index(Igeo),and modified degree of contamination(mCd)were computed.In addition,multivariate statistical techniques(principal component analysis(PCA),hierarchical cluster analysis,and Pearson's correlation analysis)were applied to identify the potential sources of metals.The mean concentrations of Cu,Zn,Cd,Pb,and Ni were 51.3,61.9,4.02,9.9,and 33.4 mg/kg dry wt,respectively.The spatial distribution revealed that the metals concentrations were high at the middle zone and low southward of Hodeida city.According to the SQGs,the adverse biological effects of metals were occasionally associated with Cu and Cd,frequently associated with Ni,and not expected to occur with Zn and Pb.The RI indicated that the sediment of the studied sites pose low(RI<50)to considerable(100≤RI<200)ecological risk.The mean effect range-median quotient(M-ERM-Q)indicated that the combination of the studied metals had the toxicity probability of 21%at all studied sites.Igeo and CF indicated that the metals concentrations were in the descending order of:Zn>Ni>Pb>Cd>Cu,whereas the PLI and mCd indicated that Ras Isa(Site 5)and Urj village(Site 6)were the most polluted sites.PCA,cluster analysis,and correlation analysis found that Cd,Pb,and Ni mostly originated from anthropogenic sources while Cu and Zn were mainly derived from natural sources.Thus,it is evident that the intensive anthropogenic activities had negative influence on metals accumulation in the sediment of the Red Sea coast of Yemen leading to detrimental effects to the whole ecosystem.These comprehensive findings provide valuable information and data for future monitoring studies regarding heavy metals pollution and sediment quality at the Red Sea coast of Yemen.     

山东省滨州市地下水污染现状研究

水资源是人类赖以生存的不可替代的物质基础,在全球经济和社会可持续发展过程中占有相当重要的地位。近年来,随着工业和农业的快速发展以及城镇人口的快速增长,随之而来的石油类污染、纺织印染污染、城市垃圾和生产生活污水的不合理处置以及农业生产农药、化肥的大量使用,造成本来有限的地下水污染状况日趋加重。以20世纪80年代时期地下水水质测试资料为背景,利用2015年以及近年来取得的大量水质测试资料,采用"污染指数法",对山东省滨州市进行区域地下水污染综合评价。研究表明:滨州市地下水无机污染以硝酸根、亚硝酸根、氯化物和硫酸盐为主,有机污染以二氯甲烷、三氯乙烯、1,1-二氯乙烯、三氯甲烷为主。相比而言黄河以北地区因地下水水位埋藏较浅,包气带岩性以砂岩为主,而且化工和皮革鞣质加工企业较多,因此受到有机污染危害更大一些。