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161.
Michiel Rutgers van der Loeff Manmohan M. Sarin Mark Baskaran Claudia Benitez-Nelson Ken O. Buesseler Matt Charette Minhan Dai
rjan Gustafsson Pere Masque Paul J. Morris Kent Orlandini Alessia Rodriguez y Baena Nicolas Savoye Sabine Schmidt Robert Turnewitsch Ingrid Vge James T. Waples 《Marine Chemistry》2006,100(3-4):190
The short-lived thorium isotope 234Th (half-life 24.1 days) has been used as a tracer for a variety of transport processes in aquatic systems. Its use as a tracer of oceanic export via sinking particles has stimulated a rapidly increasing number of studies that require analyses of 234Th in both marine and freshwater systems. The original 234Th method is labor intensive. Thus, there has been a quest for simpler techniques that require smaller sample volumes. Here, we review current methodologies in the collection and analysis of 234Th from the water column, discuss their individual strengths and weaknesses, and provide an outlook on possible further improvements and future challenges. Also included in this review are recommendations on calibration procedures and the production of standard reference materials as well as a flow chart designed to help researchers find the most appropriate 234Th analytical technique for a specific aquatic regime and known sampling constraints. 相似文献
162.
Maurice Reille Valrie Andrieu Jacques-Louis de Beaulieu Pascal Guenet Claude Goeury 《Quaternary Science Reviews》1998,17(12):1107-1123
Pollen analysis was carried out on sediments older than the Würm pleniglacial (OIS 4), in two new sequences (H and I) derived from the centre of Lac du Bouchet, Massif Central. The inferred vegetation history enables, for the first time in France, five temperate episodes to be defined which pre-date the last interglacial. These temperate episodes alternate with episodes during which the changes in vegetation are indicative of glacial climates. Comparison of these climatic episodes with the oceanic isotope record shows that the pollen record of sequences H and I from Lac du Bouchet spans the time interval from OIS 9c (Ussel interstadial) to OIS 5e (Ribains/Eemian interglacial). In the organic sediments from the Amargiers interstadial (OIS 9a), a trachytic layer, Ar/Ar dated to ca 275 ka, enables a correlation to be established with the upper part of a sequence derived from the nearby Praclaux crater, the lower part of this sequence being of Holsteinian age (OIS 11c). The cross-dating of the pollen sequences from Lac du Bouchet (cores H, I and D) and from Praclaux provides a complete record from the Massif Central, southern France, of successive glacial and interglacial episodes that span the last ca. 400 ka, that is the interval from the Holsteinian to the Holocene. 相似文献
163.
Stephen J.Puetz 《地学前缘(英文版)》2018,9(3):877-891
Enhanced understanding of how sampling techniques affect estimates of the global U-Pb age-distribution have, in turn, constrained U-Pb database design. Recent studies indicate that each continent has a unique age-distribution, as determined by zircon ages dated by the U-Pb isotope method. Likewise, broad regions within a continent also exhibit diverse age-distributions. To achieve a reliable estimate of the global distribution, the heterogenous composition of the continental crust requires sampling as many regions as feasibly possible. To attain this goal, and to provide a method for calculating age histograms, the records from a recent global U-Pb compilation are supplemented with 281,631 new records. These additions increase the database size to 700,598 records. In addition, the data are now restructured and made available as a relational database. After filtering the records by the six age-models included with the database, the results reveal two problems that might generally be unrecognized. First, an abrupt switch in the best-age at any given point(such as 1000 Ma) from ~(206)Pb/~(238)U ages to ~(207)Pb/~(206)Pb ages artificially depresses the age-distribution at the cutoff point. Second, rejecting analyses based on either absolute discordance or the magnitude of 2σ precision errors artificially depresses the age-distribution between 900 Ma and 2000 Ma. The results indicate that, when estimating the global U-Pb age-distribution, the methods for determining best-age and for rejecting records both require some attention. Possible solutions include using either an Accuracy Model or a Precision Model for estimating best-age, and then including all U-Pb records in the estimate, rather than rejecting any of them. 相似文献
164.
金矿样品分析中相关问题讨论 总被引:1,自引:0,他引:1
依据金矿石特性,探讨样品在分析过程中要特别注意的加工、测试取样量、样品焙烧、载体灰化等几个关键问题,认为只有处理好以上几个关键问题才能得到准确、可靠检测结果。 相似文献
165.
166.
Tang Limin Xiao Xi
Lecturer 《中国海洋工程》1997,(2)
During the life of an offshore structure,its structural strength declines due to various kinds ofdamages related to the time factor.In this paper,four major kinds of damages,including damages causedby fatigue,dent,corrosion and marine life,are discussed.Based on these analyses,formulas for theevaluation of the damaged structure reliability are derived.Furthermore the computer program ISM forthe analysis of structural reliability is developed by the use of Advanced First Order Second Moment meth-od and Monte-Carlo Importance Sampling method.The reliability of a turbular joint and a beam are stu-died as numerical examples.The results show that the theory and the analysis method given in this paperare reasonable and effective. 相似文献
167.
K.R. Fowler J.P. Reese C.E. Kees J.E. Dennis Jr. C.T. Kelley C.T. Miller C. Audet A.J. Booker G. Couture R.W. Darwin M.W. Farthing D.E. Finkel J.M. Gablonsky G. Gray T.G. Kolda 《Advances in water resources》2008
Management decisions involving groundwater supply and remediation often rely on optimization techniques to determine an effective strategy. We introduce several derivative-free sampling methods for solving constrained optimization problems that have not yet been considered in this field, and we include a genetic algorithm for completeness. Two well-documented community problems are used for illustration purposes: a groundwater supply problem and a hydraulic capture problem. The community problems were found to be challenging applications due to the objective functions being nonsmooth, nonlinear, and having many local minima. Because the results were found to be sensitive to initial iterates for some methods, guidance is provided in selecting initial iterates for these problems that improve the likelihood of achieving significant reductions in the objective function to be minimized. In addition, we suggest some potentially fruitful areas for future research. 相似文献
168.
Richard H. T. Garnett 《Marine Georesources & Geotechnology》2002,20(2):137-159
The marine diamond deposits of southern Africa owe their existence to fluvial transport down the Orange River to the South Atlantic. On the coast, they were moved, sorted and concentrated by high-energy sea and wind conditions to create a veneer of diamondiferous gravels on the sea floor. Large scale, offshore production by De Beers Marine commenced in 1989 in Namibian waters. The company now acts as a contractor for Namdeb, a corporation owned jointly with the Namibian governments. Some junior public companies also produce diamonds by large-scale mechanized means and conduct extensive exploration programs. Two important developments have occurred recently. Firstly, equipment for the recovery of diamonds from the seabed has been successfully borrowed from other industries. Large drills from onshore civil engineering have been modified for marine sampling and mining. Remotely controlled, seabed-mounted, excavational systems have assumed a major role. The new systems allow both evaluation sampling and subsequent mining to be undertaken by similar or the same equipment, making the results compatible. They permit highly selective extraction and enhanced recovery of the gravels from irregular bedrock in water approaching 200 m deep. But none is universally applicable offshore, each being the preferred system under different conditions. Secondly, the total output of sea diamonds from Namibian waters has increased to 0.8 million carats annually and now exceeds that from all the country's onshore sources. An industry has become established. Corporate and individual perseverence, government encouragement, new technology, shareholders' risk finance, and De Beers' diamond marketing have all played a role in the success. Future diamond production may increase as companies meet the challenge of working lower grade, higher volume deposits, which will require new approaches to the mining process. With a decrease in the physical risk of marine mining, the most variable inputs in operational planning and production forecasting are recovered grade and throughout rate, together with equipment availability. The importance of reliable grade estimation from sufficient sampling density is widely perceived, but the greatest performance risk can involve the predicted excavation rate and 'mineability' of the seabed sediments. Published reserve statements would benefit from a requirement to specify the planned mining method, the consequent cutoff grade to be employed, and whether or not test mining has been undertaken. 相似文献
169.
The value of high-resolution nutrient monitoring: A case study of the River Frome, Dorset, UK 总被引:1,自引:0,他引:1
The River Frome was sampled at sub-daily sampling interval, with additional storm sampling, through an annual cycle. Samples were analysed for total phosphorus (TP), soluble reactive phosphorus (SRP), total oxidisable nitrogen (TON) and dissolved reactive silicon (Si). The resulting data set was artificially decimated to mimic sampling frequencies from 12 h to monthly time interval. Monthly sampling interval resulted in significant errors in the estimated annual TP and SRP load of up to 35% and 28% respectively, and the resulting data sets were insufficient to observe peaks in P concentration in response to storm events. Weekly sampling reduced the maximum percentage errors in annual load estimate to 15.4% and 6.5%. TON and silicon concentrations were less variable with changing river flow, and monthly sampling was sufficient to predict annual load estimates to within 10%. However, to investigate within-river nutrient dynamics and behaviour, it is suggested that a weekly sampling interval would be the minimum frequency required for TON and Si studies, and daily sampling would be a minimum requirement to adequately investigate phosphorus dynamics. The loss in nutrient-concentration signal due to reduced sampling interval is presented. Hysteresis in the nutrient concentration/flow relationships for all 32 storm events during the study period were modelled and seasonal patterns discussed to infer nutrient sources and behaviour. The high-resolution monitoring in this study identified, for the first time, major peaks in phosphorus concentration in winter that coincide with sudden falls in air temperature, and was associated with biofilm breakdown. This study has shown that to understand complex catchment nutrient processes, accurately quantify nutrient exports from catchments, and observe changes in water quality as a result of nutrient mitigation efforts over time, it is vital that the newly emerging field-based automated sampler/analyzer technologies begin to be deployed, to allow for routine high-resolution monitoring of our rivers in the future. 相似文献
170.
A Kriging-based approach for locating a sampling site—in the assessment of air quality 总被引:1,自引:2,他引:1
Hanefi Bayraktar F. Sezer. Turalioglu 《Stochastic Environmental Research and Risk Assessment (SERRA)》2005,19(4):301-305
Air quality assessment studies have either high sampling or analyses costs. In these studies the representation of a city by a single sampling point is still a serious problem, especially in the metropolitans of developing countries, because of the absence of equipments required for sampling at different locations. In this paper, the smoke data measurements of long years are used in the determination of the region for the representation of the city by drawing contours through the Kriging method. Then, the selection of the sampling site in this region is done on the basis of the criteria recommended by the EPA. By this way, the data taken from this sampling point are used for assessing the average city concentrations with lower sampling and analyses costs. This information is valuable for monitoring the air quality and defining environmental policies, although the local distribution and the extreme concentration values over the city are not measurable. 相似文献