全球锂资源综合评述

发展高效清洁能源是解决能源和环境问题的有效途径,交通电力化和能源储存使全球对锂产品的需求持续快速增加,导致全球对锂资源越来越关注。然而,不同文献报道和不同信息来源的全球锂资源量差别较大,我们在对各种最新报道和公开的信息进行系统分析的基础上,对全球锂资源进行了综合评述。全球卤水锂和矿石锂资源总量为3 190～5 190万吨(以金属锂计),卤水锂和矿石锂分别约占62.6%和37.4%,全球70%以上的卤水锂资源在智利、阿根廷、玻利维亚锂三角地区。以卤水为原料生产锂盐能耗低、成本低,对卤水锂资源会越来越关注,卤水提锂将成为未来锂资源提取的重要方向。     

基于密度泛函理论研究K对Li2CO3晶体影响规律

以盐湖卤水为原料提取并制备Li2CO3的过程中,共存离子对其结晶过程影响较大,尤其西藏盐湖卤水为原料制备碳酸锂的原料中,K/Li约为0.3左右,所以研究K+对Li2CO3晶体的影响具有重要意义。本研究通过实验和计算模拟相结合研究不同K/Li条件下K+对Li2CO3晶体的影响程度,建立晶体中K+含量与比表面积关联式。实验结果表明,K+的存在对Li2CO3的高品质性影响较大,且随着钾离子含量增加,晶体比表面积增大易于吸附杂质离子,表面粗糙度增强,且K+存在对碳酸锂晶体的收率影响较大,而当K/Li控制在0.1以内时,K+对碳酸锂晶体的影响相对较小;通过第一性原理计算,计算并分析了K掺入碳酸锂晶体中的几何结构、缺陷形成能及态密度,结果表明K原子在碳酸锂晶体中更易替代晶体中的Li原子,且K原子的掺入对碳酸锂晶体的晶格参数以及电子结构性质的影响较小。本文对西藏盐湖高效提锂和制备高附加值碳酸锂晶体提供理论依据。     

盐生植物萌发期对盐胁迫的适应研究进展

目前我国盐渍土地面积较大,尤其是青藏高原的盐渍地,常伴有干旱、半干旱的生境,导致植物不易生长,生态环境相对恶劣,这种生态现状亟待解决。盐生植物具有一定的耐盐性和耐旱性,是改善盐渍地的首选植物,种子的活力决定了种子萌发的情况,多数学者为改善严峻的生态环境开始了盐生植物引种的研究。测定种子活力有直接方法和间接方法,大多数学者采用的是直接方法,即在实验室模拟一定条件直接测定萌发率。简述了盐生植物的概况、制造胁迫的主要方法以及检测种子活力的指标,综述了近年来不同学者对盐爪爪、白刺等具有代表性的22种盐生植物在种子萌发期的耐盐性以及抗旱性的相关研究,为改善盐渍地的生态环境、提升盐渍地的生产量提供了理论基础。     

高纯锂盐应用及工艺研究的新进展

阐述了近年来高纯锂盐产品在新能源和新材料等高新技术领域的应用及其制备工艺研究方面取得的新进展,详细介绍了微粉碳酸锂、单晶级碳酸锂、电池级单水氢氧化锂和无水高氯酸锂等几种高纯锂盐产品应用和工艺研究的进展。     

Drying of salt-contaminated masonry: MRI laboratory monitoring

Drying of masonry specimens was monitored by means of a two-dimensional (2D) magnetic resonance imaging (MRI) technique. The external surfaces stayed wet for longer if NaCl was present instead of pure water only. This corroborates many practical observations that salts aggravate dampness in masonry. A slower evaporation process and not hygroscopicity was the cause. That suggests that salt-induced dampness may, in general, arise simply from changes in the drying process of masonry materials. That also implies that the height and depth at which crystallization occurs in walls may depend on the relative equilibrium humidity (RHeq) and other properties of salts that influence drying of porous materials. Evaporation rates of free surfaces of pure water and saturated NaCl solution were measured by a gravimetric technique. The results indicate that slow drying of salt-contaminated materials is not due only to the lower RHeq of salt solutions. The effective surface of evaporation is likely to be reduced perhaps due to blocking of pores by salt crystals. Final salt-distribution maps of the specimens show that: (a) salts may affect the inner materials of the masonry, even in evaporation-induced processes that lead crystallization to occur predominantly on the external surface; (b) distinct internal distribution patterns occur if masonry composition varies. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.     

论四川盆地三叠系盐类热融水溶变质对找钾方向的控制

四川盆地蕴藏丰富的盐卤资源。从盆地海相三叠系盐类大量的热融、水溶变质资料 ,阐述了它对盆地三叠系找钾方向的控制 ,提出开辟富钾卤水———液态钾矿的找钾工作 ,是四川盆地至为重要的找钾新方向     

互花米草入侵东滩盐沼对大型底栖无脊椎动物群落的影响

外来种互花米草 (Spartina alterniflora)已经成功入侵崇明东滩 ,正在大量取代潮间带的优势种海三棱草 (Scirpus mariqueter)。采用圆筒取样比较了大型底栖无脊椎动物 (不包含蟹类 )的密度、多样性和群落结构在这两种植物群落的变化差异。大型底栖无脊椎动物的密度在互花米草群落和海三棱草群落中分别为 3119个 /m2 和 345 9个 /m2 ,两者之间没有显著差异 ,但一些常见种的密度在两种植物群落中存在显著差异。从物种的相对多度看 ,两种植物群落中 ,大型底栖无脊椎动物的优势种都是堇拟沼螺 (Assimineaviolacea)和丝异须虫(Heteromastusfiliforms)。物种多样性分析表明 ,互花米草群落中 ,平均每一个圆筒取样中大型底栖无脊椎动物的物种丰富度、香农 -威纳指数、均匀度都显著低于海三棱草群落中 ,而优势度则相反。互花米草群落中 ,食碎屑者的数量百分比显著大于海三棱草群落中 ,食悬浮物者和食植者的数量百分比显著小于海三棱草群落中。这表明互花米草入侵东滩海三棱草群落 ,竞争取代土著植物后 ,显著降低了大型底栖无脊椎动物的物种多样性 ,同时显著改变了营养类群的结构。互花米草入侵所引起的植物群落高度、密度、盖度、生物量的变化可能是造成大型底栖无脊椎动物群落结构改变的主要原因。     

松嫩平原沼泽湿地区多目标地球化学调查方法试验

沼泽湿地属于一种特殊的生态景观条件。为了选择适合沼泽湿地区的多目标地球化学调查采样介质,在松嫩平原西部扎龙保护区开展了方法试验,采样介质主要采取沼泽湿地区的表层腐殖泥和基底冲积土2种介质。通过对比试验,反映出沼泽湿地区表层的腐殖泥是代表该景观区多目标地球化学调查的最佳采样介质。腐殖泥样品中的OrgC、N、S、Se、Hg、TC、U、Br、Au、TFe2O3、Bi、Cr、Ag、Li、Y、Mo、Cu、Sb等元素含量均高于其基底沉积物样品。这与沼泽湿地区的生态环境特征相吻合,而腐殖泥下部的冲积成因的基底物质属于外来物质,不能反映目前沼泽湿地区的生态环境特征,由此确定沼泽湿地区多目标地球化学调查最佳采样介质为表层的腐殖泥。     

挤压作用下盐岩流动的三维物理模拟分析

盐岩的流动性在盐构造的研究中一直颇受关注.本文结合物理模拟实验及模型的三维重建技术分析了影响盐岩流动的区域构造挤压位移负载和沉积差异负载两种作用力因素.研究认为,盐岩在构造挤压作用下存在明显的流动变形.在高挤压构造应变背景下(动力应变率约10-13s-1数量级),盐岩的流动变形主要受区域构造挤压的位移负载制约,其次是同...     

Heterogeneous tectonic inversion of the Mid-Polish Trough related to crustal architecture, sedimentary patterns and structural inheritance

Using a 3-D structural model, we performed a basin-scale analysis of the tectonically inverted Mid-Polish Swell, which developed above the NW–SE-oriented Teisseyre-Tornquist Zone. The later separates the Paleozoic West European Platform from the Precambrian East European Craton. The model permits a comparison between the present depths and sedimentary thicknesses of five layers within the Permian–Mesozoic and Cenozoic successions. The inversion of the NW–SE-trending Mid-Polish Trough during the Late Cretaceous–Paleogene resulted in uplift of a central horst, the Mid-Polish Swell, bounded by two lateral troughs. These structural features are induced by squeezing of a weak crust along the Teisseyre-Tornquist Zone. The swell is characterized by an inherited segmentation which is due to NE–SW transversal faults having crustal roots. From NW to SE, we distinguish the Pomeranian, Kujavian, and Ma opolska segments, that are separated by two transversal faults. During the inversion, the Zechstein salt occurring in the Pomeranian and Kujavian segments in the NW acted as decoupling level between the basement and the post-salt cover, leading to disharmonic deformation. Conversely, because no salt occurs in the SE, both basement and cover were jointly deformed. The vertical tectonic uplift at the surface is estimated to amount to 3 km in the Ma opolska segment. The structural inheritance of the basement is expressed by the heterogeneous geometry of the swell and tectonic instability during Mesozoic sedimentation. The reasons for the inheritance are seen in the mosaic-type Paleozoic basement SW of the Teisseyre-Tornquist Zone, contrasting the Precambrian East European Craton which acted as a stable buttress in the NE. The horst and trough geometry of Cenozoic sediments blanketing the Mid-Polish swell reveals the ongoing intracontinental compressional stress in Poland.