硫化物风化产酸对流域岩石风化和碳循环的影响——以黄河支流三川河流域为例

硫化物风化产酸可加速岩溶作用但抑制大气二氧化碳参与流域碳循环,其复杂的地球化学机制和过程待阐明。本文以黄河二级支流三川河流域为例,通过采集20个三川河及其支流地表水点样和30个柳林泉地下水点样,经实验测试获得了流域比较系统的水化学资料和δ¹³C、δ³⁴ S数据,运用碳、硫同位素分析与水化学平衡计量方法,量化了流域硫化物风化产酸对岩石风化作用的贡献以及对碳循环的影响。计算结果表明：煤系地层硫化物和矿床硫化物的氧化及大气酸沉降所形成的硫酸明显促进了流域碳酸盐岩的溶蚀,对碳酸盐岩溶蚀的贡献约占64.59%;柳林泉水石膏溶解来源的SO₄^2-占69%,河水中石膏溶解来源的SO₄^2-占30%,但这些部分SO₄^2-没有参与溶蚀作用,应当扣除;三川河流域平均岩石风化速率为10.02 mm/ka,其中碳酸盐岩、硅酸盐岩的风化速率分别为9.14 mm/ka和0.88 mm/ka,低于国内外很多流域;由于硫酸抵消了碳酸盐岩石风化作用对大气二氧化碳的吸收,流域岩石风化消耗大气/土壤CO₂通量为116.58 mmol/（km² ·a）,不足珠江流域的1/5,且硅酸盐岩风化的贡献占63.3%。

     

天山山区典型内陆河流域径流组分特征分析

通过对天山南北坡的两个典型流域降水、地下水、河流、融冰雪水δD和δ¹⁸O及水化学检测,基于同位素径流分割模型定量分析了年内径流组分特征。结果表明：（1）两条河流的径流组成中地下水为构成径流的主要成分,其次是冰川融水,融雪水及降水,但南北坡径流组分表现出较明显的差异,乌鲁木齐河流域中冰川融水的比重要大于黄水沟流域,对气候变化响应明显。（2）两条河流在不同季节径流组分也表现出较大差异,春季径流组分差异最为明显。     

宁夏河东沙地不同坡度柠条锦鸡儿(Caragana korshinskii)水分利用策略差异

为探讨全球气候变化背景下多元线性混合模型（IsoSource）和贝叶斯混合模型（MixSIAR）解析宁夏河东沙地柠条锦鸡儿（Caragana korshinskii）水分利用策略差异及适用性,利用氢氧稳定同位素技术,结合直接对比法、IsoSource模型和MixSIAR模型对比分析不同坡度（6°、10°、16°和24°）样地柠条锦鸡儿在生长季不同时期对各潜在水源的利用率,并评估两种模型的植物水分溯源效果。结果表明：柠条锦鸡儿对不同土层深度土壤水的利用存在明显的季节性差异,生长季初期,随着坡度的增大,柠条锦鸡儿对中层土壤水的利用率呈现出先增大后减小的趋势;生长季中期,随坡度增大,柠条锦鸡儿主要水分来源由深层土壤转移至浅层土壤;生长季后期,柠条锦鸡儿主要水分来源随着坡度的增大由浅层土壤转移至深层土壤。基于直接对比法的定性判断结果,IsoSource模型和MixSIAR模型计算坡度6°、10°和16°样地柠条锦鸡儿主要水分来源利用率的适用性均较高;而Mix-SIAR模型计算坡度24°样地柠条锦鸡儿主要的水分来源以及其贡献率具有更高的可靠性。Iso-Source模型更适合解析较小坡度（6°和1...     

The place of rural, remote and least-wealthy small islands in international water development: the nexus of geography–technology sustainability in Chuuk State, Federated States of Micronesia

Many least-wealthy, rural, remote and resource-poor small island communities are unlikely to benefit from high-profile global water improvement initiatives. Their small landmasses, geologic composition, geography, social and technological isolation, colonial history, and weak educational and financial resources constitute significant barriers to improving access to safe drinking water. This paper discusses the relatively unique position of such island societies in the international community, providing a case study of the Federated States of Micronesia that integrates data and information pertaining to water resources management and governance, spanning from the island village to national scale. A vision is offered regarding the interaction between small island human and biophysical water systems, manifesting ways to pursue water resource development to improve public health which are constructed to be economically, physically and culturally sustainable.     

云南省金沙江流域土壤流失方程研究

云南金沙江流域是长江中上游水土流失最严重的区域。本项研究以“通用土壤流失方程”(USLE)为蓝本,运用小区实验等手段,综合分析了各个侵蚀因子,建立了云南金沙江流域土壤流失方程A=R·K·LS·c·P,并确定了方程中诸因子的求算方法和数值,以及该流域土壤允许流失量,为方程的应用提供了基本的技术数据。同时,还进行了方程的检验,方程计算值与小区实测值的相对误差在6.3％以下,表明该方程在实际应用中是可靠的。该方程的建立,可为云南金沙江流域预测预报土壤侵蚀,制定土地合理利用规划方案、水土保持措施和土地生态安全格局提供了一套可靠的科学方法和依据。     

Analysis of city centrality based on entropy weight TOPSIS and population mobility: A case study of cities in the Yangtze River Economic Belt

Based on statistical data and population flow data for 2016,and using entropy weight TOPSIS and the obstacle degree model,the centrality of cities in the Yangtze River Economic Belt(YREB)together with the factors influencing centrality were measured.In addition,data for the population flow were used to analyze the relationships between cities and to verify centrality.The results showed that:(1)The pattern of centrality conforms closely to the pole-axis theory and the central geography theory.Two axes,corresponding to the Yangtze River and the Shanghai-Kunming railway line,interconnect cities of different classes.On the whole,the downstream cities have higher centrality,well-defined gradients and better development of city infrastructure compared with cities in the middle and upper reaches.(2)The economic scale and size of the population play a fundamental role in the centrality of cities,and other factors reflect differences due to different city classes.For most of the coastal cities or the capital cities in the central and western regions,factors that require long-term development such as industrial facilities,consumption,research and education provide the main competitive advantages.For cities that are lagging behind in development,transportation facilities,construction of infrastructure and fixed asset investment have become the main methods to achieve development and enhance competitiveness.(3)The mobility of city populations has a significant correlation with the centrality score,the correlation coefficients for the relationships between population mobility and centrality are all greater than 0.86(P<0.01).The population flow is mainly between high-class cities,or high-class and low-class cities,reflecting the high centrality and huge radiating effects of high-class cities.Furthermore,the cities in the YREB are closely linked to Guangdong and Beijing,reflecting the dominant economic status of Guangdong with its geographical proximity to the YREB and Beijing's enormous influence as the national political and cultural center,respectively.     

Test of Hack's slope to bed material relationship in the Southern Eifel Uplands,Germany

The local reach gradient of small gravel bed rivers (drainage area 0-8-110 km²) in the Eifel, West Germany, is adjusted to transport the river bed sediments. Transport of gravel becomes possible under high flow conditions (Shields entrainment factor ≈-03). Mean bed material size for riffle sections increases with distance downstream. For small drainage areas channel slope is a negative exponential function of drainage area, while for the larger region the additional influence of bedload size has to be considered. Good agreement with Hack's data (1957) for Virginia and Maryland, U.S.A., is achieved (S = 0.0066 (D₅₀/A)^{- 40.}, r = 0.67).     

Spatial variation and driving mechanism of soil organic carbon components in the alluvial/sedimentary zone of the Yellow River

Alluviation and sedimentation of the Yellow River are important factors influencing the surface soil structure and organic carbon content in its lower reaches. Selecting Kaifeng and Zhoukou as typical cases of the Yellow River flooding area, the field survey, soil sample collection, laboratory experiment and Geographic Information System(GIS) spatial analysis methods were applied to study the spatial distribution characteristics and change mechanism of organic carbon components at different soil depths. The results revealed that the soil total organic carbon(TOC), active organic carbon(AOC) and nonactive organic carbon(NOC) contents ranged from 0.05–30.03 g/kg, 0.01–8.86 g/kg and 0.02–23.36 g/kg, respectively. The TOC, AOC and NOC contents in the surface soil layer were obviously higher than those in the lower soil layer, and the sequence of the content and change range within a single layer was TOCNOCAOC. Geostatistical analysis indicated that the TOC, AOC and NOC contents were commonly influenced by structural and random factors, and the influence magnitudes of these two factors were similar. The overall spatial trends of TOC, AOC and NOC remained relatively consistent from the 0–20 cm layer to the 20–100 cm layer, and the transition between high-and low-value areas was obvious, while the spatial variance was high. The AOC and NOC contents and spatial distribution better reflected TOC spatial variation and carbon accumulation areas. The distribution and depth of the sediment, agricultural land-use type, cropping system, fertilization method, tillage process and cultivation history were the main factors impacting the spatial variation in the soil organic carbon(SOC) components. Therefore, increasing the organic matter content, straw return, applying organic manure, adding exogenous particulate matter and conservation tillage are effective measures to improve the soil quality and attain sustainable agricultural development in the alluvial/sedimentary zone of the Yellow River.     

不同水淹环境下河口感潮湿地枯落物分解及营养动态

采用分解袋法,以我国东南沿海典型的感潮河口--闽江河口最大的鳝鱼滩湿地为研究区域,选取2个潮水水淹环境差异显著的地段(一个为近潮沟地段,另一个为远潮沟地段)为研究样地,对闽江河口主要的本地种芦苇、短叶茳芏及外来人侵种互花米草枯落物分解过程及影响因素进行研究,结果表明:(1)经常性的潮汐水淹对3种植物枯落物分解速率的影响不显著;(2)经常性的潮汐水淹促进了短叶茳芏和互花米草枯落物N、P元素的损失,但对芦苇的影响不大;(3)在2种不同的水淹环境,3种植物枯落物分解速率由快到慢的顺序均是短叶茳芏>互花米草>和芦苇,分解速率在0.003166～0.005280 d-1之间,95%干物质分解需要的时间在1.56～2.61 a之间;(4)C浓度基本稳定,N浓度呈上升趋势,总N在研究末期表现为净损失,P浓度呈较大的波动,总P在研究末期也表现为净损失;(5)具有最低C/P的短叶茳芏枯落物分解速率最快.