钛酸锶的掺杂研究

采用溶胶 -凝胶方法 ,以 Co(AC) 2 、Zn(AC) 2 、Mg(AC) 2 、Ca(AC) 2 、Y2 O3、L a2 O3为掺杂物 ,对 Sr Ti O3进行了掺杂研究 ,研究结果表明 ,以醋酸盐为掺杂物所制得的样品 ,分散开的颗粒近似呈球形 ,粒径约为5 0 nm ,主相是 Sr Ti O3;以氧化钇为掺杂物所制得的样品 ,颗粒明显呈六边形 ,粒径约为 2 5 0 nm。各样品的阻温曲线显示 ,室温电阻率可达 10 6 欧姆·厘米。各样品的表征都是基于 XRD分析、TEM分析     

熔融法六钛酸钾合成机理研究

本文合成了结晶二钛酸钾纤维．根据化学定量分析、Ｘ—ｒａｙ衍射分析、ＤＴＡ差示热分析等，得到了熔融法六钛酸钾纤维的合成机理．     

Isotopic and hydrochemical studies of groundwater flow and salinity in the Southern Upper Rhine Graben

In order to determine the origin and the propagation mechanisms of highly concentrated chloride brines within the Quaternary aquifer system in the southern part of the Upper Rhine Graben, a combined isotope (H, O, C) and hydrochemical analysis was carried out. Groundwater recharge in this area is a complex system, consisting of local precipitation, river bank filtration, lateral flow from the Graben borders and, to a minor extent, an old Pleistocene component. In some areas, groundwater consists of up to 90% of recent bank filtrate, reaching depths down to at least 100 m. The isotopic and hydrochemical results show, that the elevated chloride concentrations in the Quaternary aquifer mainly result from leaky settling basins charged by the French potash mines until the mid 1970s. Input of natural brines coming from tertiary salt diapirs is of only minor importance. While infiltrating, the anthropogenic brines were strongly diluted by local river bank filtrate of the Rhine. Nevertheless, maximum chloride concentrations nowadays still reach some 10,000 mg/l at the base of the aquifer at a depth of more than 100 m below surface. The main volume of the brines is stored in the less permeable lower part of the quaternary sediments (Breisgau-Formation) whereas only a minor part is transported northwards with the rapid convective groundwater flow. Brines undergoing only dilution preserve their hydrochemical characteristics (NaCl-type). In contrast, brines recirculated from the Breisgau-Formation show a northwards increasing alteration through ion exchange processes. Potassium and sodium may be fixed in the fine grained aquifer material while calcium is set free into the groundwater. After a flow distance of about 12 km, complex hydraulic interactions between groundwater and surface waters lead to the rise of strongly diluted and hydrochemically altered brines with chloride contents up to maximum 700 mg/l. The presented case study is an example for a detailed analysis of a multi-component groundwater mixing system using combined isotope and hydrochemical methods. Furthermore, cation exchange is shown as a major process affecting the hydrochemical evolution of the young groundwater in the southern Upper Rhine Graben which is locally strongly polluted by chloride as a consequence of former potash mining.     

反浮选-冷结晶法生产氯化钾浮选法除钙研究

研究了青海察尔汗盐湖水采光卤石矿生产氯化钾工艺中浮选除钙的方法。实验结果表明,分级浮选法除钙率平均达88.16%,接近原矿的理论可除钙离子量91.58%。     

溶剂萃取法制取硫酸钾中试及其新进展

描述了用工业硫酸和氯化钾为原料,萃取法制取硫酸钾新工艺及其工程化的新进展。研究了该工艺三相萃取过程的基本原理,列出了试验数据及经济技术评价。     

新疆阿尔泰钾长石矿物学特征及开发利用

阿尔泰钾长石是新疆优势非金属矿产资源之一，主要赋存在花岗伟晶岩矿脉、钾长花岗岩和碱性花岗岩中，钾长石资源储量大、品位高，易采易选，但尚未很好开发利用。通过阿尔泰钾长石矿物的物理特征、光学性质、化学成分以及工艺矿物学特征的研究，阐述了钾长石资源在工农业中的应用状况和应用范围，经与国内同类型矿种对比，指出新疆阿尔泰钾长石开发利用有着广阔的前景。     

西部含锂、钾、镁、硼盐卤资源水盐体系相化学研究

从资源特点出发 ,分别回顾了含锂、钾、镁氯化物多元水盐体系 ,镁水泥体系 ,盐卤锂、钾卤化物水盐体系的相化学研究 ,概括了主要研究成果并指出实际应用上的关键问题 ,以及研究的主要内容。     

油泉子钾矿床晶间卤水（KCl）自然蒸发试验研究

油泉子矿床是一个以卤水钾镁盐矿为主的小型综合性盐类矿床,盐湖卤水水化学类型主要为氯化物型,从KCl等组分含量来看,属高钾高钠低镁的卤水。在柴达木盆地与油泉子条件相类似的盐类矿床中,氯化物型卤水钾的选矿工艺已十分成熟,但对于不同矿区不同组分含量的卤水,其结晶路线各不相同,为此,对油泉子矿床氯化物型卤水进行自然蒸发试验,确定盐类结晶析出顺序和钾矿物的最佳分离点,取得钾矿物的产率和钾石盐中KCl含量等基础数据,并对该类型卤水工业利用性能作出评价。     

柴达木盆地宗马海湖地区钾盐矿床成矿规律与成矿预测研究

研究区位于柴达木盆地北部边缘,属柴达木盆地中—新生代盐类成矿区。该次研究了浅部、中深部及深层储层特征、卤水钾盐的赋存规律及构造控矿理论。浅部卤水钾盐依据KCl含量,分为工业品位区、边界品位区、有浅层卤水区及无浅层卤水区。中深部卤水钾盐分布于山间古冲洪积平原(Ⅰ■)和马海湖次级洼陷(Ⅰ■)中,矿层厚度较大的区域在马海湖次级洼陷(Ⅰ■)北部,主要分布于全新统—更新统含盐系中,计算深度297.22m。深部卤水钾盐,厚度较薄者分布于冷湖六号、冷湖七号构造以北地区的一层至数层的砂岩及砂砾岩层中,自南东向北西由深变浅,分布于上新统,含卤水层段厚约50～250m。厚度较大者分布在赛什腾山山前冲洪积带,北至驼南断裂,南大致至ZK4012孔一线,孔隙卤水层累计深度达1265.14m,分布于全新统—上新统,是今后寻找深层卤水钾盐矿最重要的找矿区域。     

Characteristics of biomass burning aerosol and its impact on regional air quality in the summer of 2003 at Gwangju, Korea

The main objective of this study is to investigate the chemical characteristics of biomass burning aerosol and its impact on regional air quality during an agricultural waste burning period in early summer in the rural areas of Korea. A 12-h integrated intensive sampling of biomass burning aerosol in the fine and coarse modes was conducted on 2–20 June 2003 in Gwangju, Korea. The collected samples were analyzed for concentrations of mass, ionic, elemental, and carbonaceous species. Average concentrations of fine and coarse mass were measured to be 67.9 and 18.7 μg m^− 3 during the biomass burning period, 41.9 and 18.8 μg m^− 3 during the haze period, and 35.6 and 13.3 μg m^− 3 during the normal period, respectively. An exceptionally high PM_2.5 concentration of 110.3 μg m^− 3 with a PM_2.5/PM₁₀ ratio of 0.79 was observed on 6 June 2003 during the biomass burning period. The potassium ratio method was used to identify biomass burning samples. The average ratio of potassium in the fine mode to the coarse mode (FK/CK) was 23.8 during the biomass burning period, 6.0 during the haze period, and 4.7 during the normal period, respectively. A FK/CK ratio above 9.2 was considered a criterion for biomass burning event in this study. Particulate matter from the open field burning of agricultural waste has an adverse impact on visibility, human health, and regional air quality.