Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

The Reliability of Assigned Values from the GeoPT Proficiency Testing Programme from an Evaluation of Data for Six Test Materials that have been Characterised as Certified Reference Materials

Assigned values derived from the GeoPT proficiency testing programme were compared with certified values for six certified reference materials that have been used as test materials in the GeoPT programme. Statistical analysis showed that there were few significant differences between these sets of data and that these differences had no significant impact on the GeoPT assessment when fitness‐for‐purpose criteria were taken into account.     

Mise au point d'un milieu de culture pour l'étude de l'altération de silicates en présence de Pseudomonas aeruginosa

The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005).     

Le Silurien de la région d'Oulad Abbou (Meseta occidentale,Maroc) : une sédimentation péritidale sous contrôle tectonique

In the Oulad Abbou syncline, western coastal Meseta, the Silurian deposits exhibit siliciclastic or mixed siliciclastic/carbonate tidal facies that recorded alkaline basalt flows and syn-sedimentary deformations. These facies are staked into peritidal shallowing upward sequences reflecting the evolution from an infratidal to a supratidal environment. These sequences recorded low-amplitude and high-frequency sea-level variations. The built-up of these rhythmic sequences is related to distensive tectonic that allowed the development of isolated platform from extensive siliciclastic influx. This tectonic event is well recorded in the palaeogeographic evolution of the northern Gondwana platform during the Lower Palaeozoic time. To cite this article: A. Attou, N. Hamoumi, C. R. Geoscience 336 (2004).     

In Situ Determination of First‐Row Transition Metal,Ga and Ge Abundances in Geological Materials via Medium‐Resolution LA‐ICP‐MS

An in situ, medium‐resolution LA‐ICP‐MS method was developed to measure the abundances of the first‐row transition metals, Ga and Ge in a suite of geological materials, namely the MPI‐DING reference glasses. The analytical protocol established here hinged on maximising the ablation rate of the ultraviolet (UV) laser system and the sensitivity of the ICP‐MS, as well minimising the production of diatomic oxides and argides, which serve as the dominant sources of isobaric interferences. Non‐spectral matrix effects were accounted for by using multiple external calibrators, including NIST SRM 610 and the USGS basaltic glasses BHVO‐2G, BIR‐1G and BCR‐2G, and utilising ⁴³Ca as an internal standard. Analyses of the MPI‐DING reference glasses, which represent geological matrices ranging from basaltic to rhyolitic in composition, included measurements of concentrations as low as < 10⁰ μg g^?1 and as high as > 10⁴ μg g^?1. The new data reported here were found to statistically correlate with the ‘preferred’ reference values for these materials at the 95% confidence level, though with significantly better precision, typically on the order of ≤ 3% (2s_m). This analytical method may be extended to any matrix‐matched geological sample, particularly oceanic basalts, silicate minerals and meteoritic materials.     

AVO analysis with partial stacking to detect gas anomalies in the GÜEPAJÉ-3D project

We applied analysis AVO with partial stacking to an onshore gas field in order to detect gas at the top of the Ciénaga de Oro formation (FCO), by using seismic gathers of the Güepajé-3D project. The technique was supported by petrophysical analysis of the Ayombe-1 well.The sensitivity of seismic response to changes in the saturating fluid was evaluated by fluid substitution technique in an interval of the Ayombe-1 well. As a result, a class I AVO anomaly at the top of the FCO was observed, even though the gas and water responses were similar. After applying AVO with partial stack technique at the top of FCO, AVO class I anomalies were observed in the Ayombe-1 and Güepajé-1 gas wells and none in the dry Güepajé-3 well. In spite of being reported with gas, the results in the Güepajé-2 well indicated any to an incipient class I anomaly related to a weak seismic response associated to gas.When the technique was applied to the seismic volume of the Güepajé-3D Project, a map of the direct gas indicator was obtained. The map shows a high correlation with the structural surface at top of FCO. Lithic factors such as compaction, cementation and carbonate overlaying the FCO and variable thickness of partial and full saturated layers, may cause anomalies in zones unlikely to contain gas.     

The November 2002 eruption at Piton de la Fournaise volcano,La Réunion Island: ground deformation,seismicity, and pit crater collapse

An eruption on the eastern flank of Piton de la Fournaise volcano started on 16 November, 2002 after 10 months of quiescence. After a relatively constant level of activity during the first 13 days of the eruption, lava discharge, volcanic tremor and seismicity increased from 29 November to 3 December. Lava effusion suddenly ceased on 3 December while shallow earthquakes beneath the Dolomieu summit crater were still recorded at a rate of about one per minute. This unusual activity continued and increased in intensity over the next three weeks, ending with the formation of a pit crater within Dolomieu. Based on ground deformation, measured by rapid-static and continuous GPS and an extensometer, seismic data, and lava effusion patterns, the eruptive period is divided into five stages: 1) slow summit inflation and sporadic seismicity; 2) rapid summit inflation and a short seismic crisis; 3) rapid flank inflation, onset of summit deflation, sporadic seismicity, accompanied by stable effusion; 4) flank inflation, coupled with summit deflation, intense seismicity, and increased lava effusion; and finally 5) little deflation, intense shallow seismicity, and the end of lava effusion. We propose a model in which the pre-intrusive inflation of Stage 1 in the months preceding the eruption was caused by a magma body located near sea level. The magma reservoir was the source of an intrusion rising under the summit during Stage 2. In Stage 3, the magma ponded at a shallow level in the edifice while the lateral injection of a radial dike reached the surface on the eastern flank of the basaltic volcano, causing lava effusion. Pressure decrease in the magmatic plumbing system followed, resulting in upward migration of a collapse front, forming a subterranean column of debris by faulting and stoping. This caused intense shallow seismicity, increase in discharge of lava and volcanic tremor at the lateral vent in Stage 4 and, eventually the formation of a pit crater in Stage 5.     

Occurrence,durée et intensité des précipitations simulées par deux modèles régionaux canadiens du climat sur la région du Maghreb

[Translated by the editorial staff] Simulating the precipitation regime of Northern Africa is challenging for regional climate models, particularly because of the strong spatial and temporal variability of rain events in the region. In this study we evaluate simulations conducted with two recent versions of regional climate models (RCM) developed in Canada: the CRCM5 and CanRCM4. Both are also used in the COordinated Regional Climate Downscaling EXperiment (CORDEX)-Africa. The assessment is based on the occurrence, duration, and intensity indices of daily precipitation in Maghreb during the fall and spring seasons from 1998 to 2008. We also examine the links between the North-Atlantic Oscillation (NAO) index, weather systems, and the precipitation regime over the region. During the rainy season (September to February), the CRCM5 reproduces the frequency and intensity of extreme precipitation adequately, as well as the occurrence of days with rain, while the CanRCM4 underestimates precipitation extremes. The study of links between weather systems and the precipitation regime shows that, along the Atlantic coast, precipitation (occurrence, intensity, and wet sequences) increases significantly with storm frequency in the fall. In winter, these links grow stronger going east, from the Atlantic coast to the Mediterranean coast. The negative phases of the NAO index are statistically associated with the increase in rain intensity, extremes, and accumulation along the Atlantic coast in the fall. However, the link weakens in winter over these regions and strengthens along the Mediterranean coast as the precipitation frequency rises during negative phases of the NAO. Both RCMs generally reproduce the links between the NAO and the precipitation regime well, regardless of location.     

A buoyant plume adjacent to a headland—Observations of the Elwha River plume

Small rivers commonly discharge into coastal settings with topographic complexities - such as headlands and islands - but these settings are underrepresented in river plume studies compared to more simplified, straight coasts. The Elwha River provides a unique opportunity to study the effects of coastal topography on a buoyant plume, because it discharges into the Strait of Juan de Fuca on the western side of its deltaic headland. Here we show that this headland induces flow separation and transient eddies in the tidally dominated currents (O(100 cm/s)), consistent with other headlands in oscillatory flow. These flow conditions are observed to strongly influence the buoyant river plume, as predicted by the “small-scale” or “narrow” dynamical classification using Garvine's (1995) system. Because of the transient eddies and the location of the river mouth on the headland, flow immediately offshore of the river mouth is directed eastward twice as frequently as it is westward. This results in a buoyant plume that is much more frequently “bent over” toward the east than the west. During bent over plume conditions, the plume was attached to the eastern shoreline while having a distinct, cuspate front along its westernmost boundary. The location of the front was found to be related to the magnitude and direction of local flow during the preceding O(1 h), and increases in alongshore flow resulted in deeper freshwater mixing, stronger baroclinic anomalies, and stronger hugging of the coast. During bent over plume conditions, we observed significant convergence of river plume water toward the frontal boundary within 1 km of the river mouth. These results show how coastal topography can strongly influence buoyant plume behavior, and they should assist with understanding of initial coastal sediment dispersal pathways from the Elwha River during a pending dam removal project.