Mercury cycling during acid rain recovery at the forested Lesní potok catchment,Czech Republic

From 2011 to 2019, mercury (Hg) stores and fluxes were studied in the small forested catchment Lesní potok (LES) in the central Czech Republic using the watershed mass balance approach together with internal measurements. Mean input fluxes of Hg via open bulk deposition, beech throughfall and spruce throughfall during the periodwere 2.9, 3.9 and 7.6 μg m⁻² year⁻¹, respectively. These values were considerably lower than corresponding deposition Hg fluxes reported in the early years of the 21st century from catchments in Germany. Current bulk precipitation inputs at unimpacted Czech mountainous sites were lower than those in Germany. The largest Hg inputs to the catchment were via litterfall, averaging 22.6 and 17.8 μg m⁻² year⁻¹ for beech and spruce stands. The average Hg input, based on the sum of mean litterfall and throughfall deposition, was 23.0 μg m⁻² year⁻¹, compared to the estimated Hg output in runoff of 0.5 μg m⁻² year⁻¹, which is low compared to other reported values. Thus, only ~2% of Hg input is exported in stream runoff. Stream water Hg was only weakly related to dissolved organic carbon (DOC) but both concentrations were positively correlated with water temperature. The estimated total soil Hg pool averaged 47.5 mg m⁻², only 4% of which was in the O-horizon. Thus Hg in the O-horizon pool represents 72 years of deposition at the current input flux and 3800 years of export at the current runoff flux. Age-dating by ¹⁴C suggested that organic soil contains Hg from recent deposition, while mineral soil at 40–80 cm depth contained 4400-year old carbon, suggesting the soil had accumulated atmospheric Hg inputs through millennia to reach the highest soil Hg pool of the soil profile. These findings suggest that industrial era intensification of the Hg cycle is superimposed on a slower-paced Hg cycle during most of the Holocene.     

长江冲淡水的扩展及其营养盐的输运

本文根据长江口及其邻近海域硝酸盐和硅酸盐的平面分布特征,研究得出,除冬季外,长江冲淡水中的营养盐同时向两个方向输送,一、向北或东北输入南黄海西南部;二、向南或东南输入东海。据此提出“长江冲淡水双向扩展”的观点,即长江冲淡水先顺河口走向朝东南方向流动,到达口门处分成两部分（冬季除外）,一部分穿过杭州湾口及舟山群岛一带沿岸南下,或自长江口向东南方向扩展;另一部分则左转向北或东北,进入南黄海西南部。南、北两股冲淡水的水量大小及其比例,因不同季节而异。     

Seasonal variation in the biogeochemical cycling of seston in Grand Traverse Bay, Lake Michigan

This study describes the biogeochemical cycling of seston in Grand Traverse Bay, Lake Michigan. Seston was characterized by carbon and nitrogen elemental and isotopic abundances. Fluorescence, temperature, light transmittance, and concentrations of dissolved inorganic nitrogen were also determined. PCBs were analyzed from surface (10 m) seston and ΣPCB was calculated by summing all of the congeners quantified in each sample. The vertical and seasonal trends in the δ¹³C values of seston exhibited a broad range from −30.7 to −23.9‰. Low δ¹³C values that occur concurrently with a peak in fluorescence below the thermocline reflect uptake of ¹³C depleted respiratory CO₂ and/or the accumulation of ¹³C depleted lipids by phytoplankton. High δ¹³C values late in the season likely result from a reduction in photosynthetic fractionation associated with a decrease in the CO₂ pool. Seasonal δ¹⁵N values of seston were high in the spring and declined through August. The δ¹⁵N values of seston reflect a balance between fractionation during assimilation of NH₄⁺ or NO₃⁻ and degradative processes. The seston ΣPCB and fluorescence were both high in the spring and subsequently declined, suggesting that the concentrations of PCBs in seston were associated with labile material derived from primary productivity. The strong seasonal trends in the organic geochemical characteristics of seston and concentrations of PCBs emphasize the complex nature of particle cycling in aquatic environments.     

东海赤潮高发区营养盐时空分布特征及其控制要素

东海长江口、舟山渔场附近海域是我国近海赤潮爆发严重的区域之一。在影响该海域营养盐分布的水团中 ,长江冲淡水向表层输入了大量的氮、磷、硅营养盐 ,台湾暖流主要对底层和长江口外上升流区有贡献 ,苏北沿岸水、闽浙沿岸水主要影响近岸区域。同时 ,营养盐在海水 -沉积物界面的交换作用 ,大气湿沉降作用等也影响着该海域营养盐的时空分布。结合2002年4月～2003年3月对29°00′～32°00′N、122°00′～124°00′E海域四季航次调查的营养盐分布规律 ,该海域可分为三片区域 ,由岸边向外海分别为高营养盐、低浮游植物区 ,较高营养盐、高浮游植物区和较低营养盐、低浮游植物区。随着近年来营养盐输入通量的增加 ,富营养化程度加大 ,受化学、物理、生物等因素综合作用 ,高浮游植物区赤潮爆发频率和规模逐年增加 ,已为中国近海典型的赤潮高发区     

Water and nutrient fluxes in a cool temperate rainforest at the Cordillera de la Costa in southern Chile

Water and nutrient fluxes were studied during a 12-month period in an alerce (Fitzroya cupressoides) forest, located in a remote site at the Cordillera de la Costa (40°05′S) in southern Chile. Measurements of precipitation, throughfall, stemflow, effective precipitation, soil infiltration and stream flow were carried out in an experimental, small watershed. Simultaneously, monthly water samples were collected to determine the concentrations and transport of organic-N, NO₃-N, total-P, K⁺, Ca²⁺, Na⁺ and Mg²⁺ in all levels of forest. Concentration of organic-N, NO₃-N, total-P and K⁺ showed a clear pattern of enrichment in the throughfall, stemflow, effective precipitation and soil infiltration. For Ca²⁺ and Mg²⁺, enrichment was observed in the effective precipitation, soil infiltration and stream flow. Annual transport of K⁺, Na⁺, Ca²⁺ and Mg²⁺ showed that the amounts exported from the forest via stream flow (K⁺=0·95, Na⁺=32·44, Ca²⁺=8·76 and Mg²⁺=7·16 kg ha⁻¹ yr⁻¹) are less than the inputs via precipitation (K⁺=6·39, Na⁺=40·99, Ca²⁺=15·13 and Mg²⁺=7·61 kg ha⁻¹ yr⁻¹). The amounts of organic-N and NO₃-N exported via stream flow (organic-N=1·04 and No₃-N=3·06 kg ha⁻¹ yr⁻¹) were relatively small; however, they represented greater amounts than the inputs via precipitation (organic-N=0·74 and NO₃-N=0·97 kg ha⁻¹ yr⁻¹), because of the great contribution of this element in the superficial soil horizon, where the processes of decomposition of organic material, mineralization and immobilization of the nutrients occurs. © 1998 John Wiley & Sons, Ltd.     

Geomorphological controls on fluvial carbon storage in headwater peatlands

Geomorphological controls and catchment sediment characteristics control the formation of floodplains and affect their capacity to sequester carbon. Organic carbon stored in floodplains is typically a product of pedogenic development between periods of mineral sediment deposition. However, in organically-dominated upland catchments with a high sediment load, eroded particulate organics may also be fluvially deposited with potential for storage and/or oxidation. Understanding the redistribution of terrestrial carbon laterally, beyond the bounds of river channels is important, especially in eroding peatland systems where fluvial particulate organic carbon exports are often assumed to be oxidised. Floodplains have the potential to be both carbon cycling hotspots and areas of sequestration. Understanding of the interaction of carbon cycling and the sediment cascade through floodplain systems is limited. This paper examines the formation of highly organic floodplains downstream of heavily eroded peatlands in the Peak District, UK. Reconstruction of the history of the floodplains suggests that they have formed in response to periods of erosion of organic soils upstream. We present a novel approach to calculating a carbon stock within a floodplain, using XRF and radiograph data recorded during Itrax core scanning of sediment cores. This carbon stock is extrapolated to the catchment scale, to assess the importance of these floodplains in the storage and cycling of organic carbon in this area. The carbon stock estimate for the floodplains across the contributing catchments is between 3482-13460 tonnes, equating on an annualised basis to 0.8-4.5% of the modern-day POC flux. Radiocarbon analyses of bulk organic matter in floodplain sediments revealed that a substantial proportion of organic carbon was associated with re-deposited peat and has been used as a tool for organic matter source determination. The average age of these samples (3010 years BP) is substantially older than Infrared Stimulated Luminesence dating which demonstrated that the floodplains formed between 430 and 1060 years ago. Our data suggest that floodplains are an integral part of eroding peatland systems, acting as both significant stores of aged and eroded organic carbon and as hotspots of carbon turnover. © 2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

[专稿] 生态文明的自然本原

何为生态文明的自然本原?它就是良性的生态循环.生态文明的自然基础是一系列生态系统的良性循环——森林生态系统、草地生态系统、农业生态系统、湖泊生态系统、河流生态系统、海洋生态系统……等等,而良性循环的标志有二:1)为人类提供清洁的水源、新鲜的空气、优质的农-牧-渔产品、舒心的休闲景观等,这些是我们身心健康的前提,没有它们的支撑,人类文明的大厦将难以为继;2)为珍稀濒危以及土著物种提供良好的栖息之地,维持良好的生态平衡关系,增加生态系统对外界干扰的可塑性.     

Credit stacking in nutrient trading markets for the Baltic Sea

Heavy loads of the nutrients nitrogen and phosphorus cause severe damage in many waters in the world. Nutrient trading markets where capped firms can buy and sell nutrient load credits have been established in several countries in order to achieve certain nutrient reduction targets at minimum costs for society. The availability of multifunctional nutrient abatement measures that simultaneously reduce loads of both nutrients, such as wetland construction, raises the issue of credit stacking, i.e. whether a firm constructing the wetland should earn credits for both nutrients. This article examines theoretically and empirically the implications of establishing alternative nutrient trading market designs (markets with and without credit stacking, a market for a bundled payment of nutrients, and separate markets for either nutrient) for total costs and achievement of stipulated nutrient reduction targets for the Baltic Sea. The results show that the total abatement cost of achieving reduction targets of both nutrients is always lowest if a market design with credit stacking is established, that markets without credit stacking result in higher abatement cost and nutrient abatement in excess of the reduction targets, and that none of the single nutrient market systems is able to generate the required abatement of both nutrients. The application to the Baltic Sea shows that the total abatement cost can be 20% higher when credit stacking is not allowed than when it is allowed.     

Nitrate dynamics in a rural headwater catchment: measurements and modelling

This study was designed to improve our understanding of, and mechanistically simulate, nitrate (NO₃) dynamics in a steep 9.8 ha rural headwater catchment, including its production in soil and delivery to a stream via surface and subsurface processes. A two‐dimensional modelling approach was evaluated for (1) integrating these processes at a hillslope scale annually and within storms, (2) estimating denitrification, and (3) running virtual experiments to generate insights and hypotheses about using trees in streamside management zones (SMZs) to mitigate NO₃ delivery to streams. Total flow was mathematically separated into quick‐ and slow‐flow components; the latter was routed through the HYDRUS software with a nitrogen module designed for constructed wetlands. Flow was monitored for two years. High surface‐soil NO₃ concentrations started to be delivered to the stream via preferential subsurface flow within two days of the storm commencing. Groundwater NO₃‐N concentrations decreased from 1.0 to less than 0.1 mg l^?1 from up‐slope to down‐slope water tables, respectively, which was attributed to denitrification. Measurements were consistent with the flushing of NO₃ mainly laterally from surface soil during and following each storm. The model accurately accounted for NO₃ turnover, leading to the hypotheses that denitrification was a minor flux (<3 kg N ha^?1) compared to uptake (98^?127 kg N ha^?1), and that SMZ trees would reduce denitrification if they lowered the water table. This research provides an example of the measurement and modelling of NO₃ dynamics at a small‐catchment scale with high spatial and temporal resolution. Copyright © 2013 John Wiley & Sons, Ltd.     

Spatial–temporal variability in water quality and macro-invertebrate assemblages in the Upper Mara River basin,Kenya

Tropical rivers display profound temporal and spatial heterogeneity in terms of environmental conditions. This aspect needs to be considered when designing a monitoring program for water quality in rivers. Therefore, the physico-chemical composition and the nutrient loading of the Upper Mara River and its two main tributaries, the Amala and Nyangores were monitored. Initial daily, and later a weekly monitoring schedule for 4 months spanning through the wet and dry seasons was adopted. Benthic macro-invertebrates were also collected during the initial sampling to be used as indicators of water quality. The aim of the current study was to investigate the physico-chemical status and biological integrity of the Upper Mara River basin. This was achieved by examining trends in nutrient concentrations and analyzing the structure, diversity and abundance of benthic macro-invertebrates in relation to varying land use patterns. Sampling sites were selected based on catchment land use and the level of human disturbance, and using historical records of previous water quality studies. River water pH, dissolved oxygen, electrical conductivity (EC), temperature, and turbidity were determined in situ. All investigated parameters except iron and manganese had concentration values within allowable limits according to Kenyan and international standards for drinking water. The Amala tributary is more mineralized and also shows higher levels of pH and EC than water from the Nyangores tributary. The latter, however, has a higher variability in both the total phosphorus (TP) and total nitrogen (TN) concentrations. The variability in TP and TN concentrations increases downstream for both tributaries and is more pronounced for TN than for TP. Macro-invertebrate assemblages responded to the changes in land use and water quality in terms of community composition and diversity. The study recommends detailed continuous monitoring of the water quality at shorter time intervals and to identify key macro-invertebrate taxa that can be used to monitor changes of the water quality in rivers of the Mara basin as a result of anthropogenic changes.