Development of a reactive zone technology for simultaneous in situ immobilisation of radium and uranium

Simultaneous in situ immobilisation of uranium (U) and radium (²²⁶Ra) by injectible amounts of grey cast iron (gcFe), nano-scale iron (naFe) and a gcFe/MnO₂ mixture (1:1) was studied in batch and column tests. Both 0.5 g/L naFe and gcFe are effective in ²²⁶Ra and U removal from mine water, whereas MnO₂ addition clearly increased the efficiency of gcFe for ²²⁶Ra and U immobilisation. In a column test with 0.6 wt% gcFe/MnO₂ mixture (1:1), neither ²²⁶Ra nor U was detected in the effluent after replacement of 45 pore volumes. A sequential extraction under flow condition revealed ²²⁶Ra to be mostly occluded in manganese oxides. Uranium was mostly sorbed onto poorly crystalline iron hydroxides, but a significant part was found to be occluded in manganese oxides also. The results of this study suggest that MnO₂ promotes iron hydroxide formation under slightly reducing environmental conditions resulting in an increased pollutant retention capacity.     

珠江口盆地白云凹陷新生代构造演化动力学

白云凹陷构造演化史的研究对在白云凹陷开展油气勘探和深水沉积研究具有重要的意义。通过对断裂与沉积结构平面和剖面特点的分析,结合岩浆活动特点,文中提出白云凹陷是一个复式地堑,推测这种结构特点与凹陷下地壳的强烈韧性减薄和颈缩变形有关,表现为热岩石圈的伸展。其发育机制推测与白云凹陷位于构造转换带上有关,特殊的构造位置使白云凹陷成为强烈构造变形区,岩石圈地壳强烈减薄,伴随伸展过程和地幔上涌,脆性地壳或上地幔中部分熔融物质的出现导致岩石圈强度的急剧降低,在区域伸展应力场下以韧性流变方式减薄。岩浆在构造转换带下聚集并发育主岩浆房,由于白云凹陷南北边缘没有发育正断裂系统,岩浆主要沿垂直伸展的方向运移,因此在珠琼运动一幕和二幕南南东向伸展应力作用下,岩浆向白云凹陷的东部和西部运移至北西向基底深大断裂处,那里由于北西向断裂表现为左行张剪性质而成为压力较低的地区,从而成为岩浆上涌和侵位的地方。在岩浆聚集的地区,活动岩浆体附近的脆性变形被分散的韧性变形所取代,因此在凹陷的东北和西南两个角上,发育了张性和张剪性小断裂群,由于热岩石圈弹性较差,白云凹陷长期持续沉降。白云凹陷的断裂活动和沉积演化史还受到南海海盆扩张活动的影响。     

海底地下水排放:重要的海岸带陆海相互作用过程

沿海地区海底地下水排放在北美和欧洲等发达地区受到了越来越多的重视,被认为是一个重要的海岸带陆海相互作用过程。但这一过程在我国尚未引起足够认识,有关研究极少见。海底地下水排放的研究历史不长,只是近十多年才有了快速的发展,有了越来越多的定量研究成果。其研究方法主要有水文计算法、现场实测法和地球化学示踪法,各种方法之间的对比实验是目前的热点问题。沿海地下水排放具有重要的环境意义,它可以是陆地营养物质和污染物质的一个重要排放通道,可以对海岸带环境产生一定影响。我国沿海地区应该加强有关的研究工作,为海岸带环境管理作出贡献。     

Late Pleistocene and Holocene paleoseismology of an intraplate seismic zone in a large alluvial valley, the New Madrid seismic zone, Central USA

The New Madrid seismic zone (NMSZ) is an intraplate right-lateral strike-slip and thrust fault system contained mostly within the Mississippi Alluvial Valley. The most recent earthquake sequence in the zone occurred in 1811–1812 and had estimated moment magnitudes of 7–8 (e.g., [Johnston, A.C., 1996. Seismic moment assessment of stable continental earthquakes, Part 3: 1811–1812 New Madrid, 1886 Charleston, and 1755 Lisbon. Geophysical Journal International 126, 314–344; Johnston, A.C., Schweig III, E.S, 1996. The enigma of the New Madrid earthquakes of 1811–1812. Annual Reviews of Earth and Planetary Sciences 24, 339–384; Hough, S.E., Armbruster, J.G., Seeber, L., Hough, J.F., 2000. On the modified Mercalli intensities and magnitudes of the New Madrid earthquakes. Journal of Geophysical Research 105 (B10), 23,839–23,864; Tuttle, M.P., 2001. The use of liquefaction features in paleoseismology: Lessons learned in the New Madrid seismic zone, central United States. Journal of Seismology 5, 361–380]). Four earlier prehistoric earthquakes or earthquake sequences have been dated A.D. 1450 ± 150, 900 ± 100, 300 ± 200, and 2350 B.C. ± 200 years using paleoliquefaction features, particularly those associated with native American artifacts, and in some cases surface deformation ([Craven, J. A. 1995. Paleoseismology study in the New Madrid seismic zone using geological and archeological features to constrain ages of liquefaction deposits. M.S thesis, University of Memphis, Memphis, TN, U.S.A.; Tuttle, M.P., Lafferty III, R.H., Guccione, M.J., Schweig III, E.S., Lopinot, N., Cande, R., Dyer-Williams, K., Haynes, M., 1996. Use of archaeology to date liquefaction features and seismic events in the New Madrid seismic zone, central United States. Geoarchaeology 11, 451–480; Guccione, M.J., Mueller, K., Champion, J., Shepherd, S., Odhiambo, B., 2002b. Stream response to repeated co-seismic folding, Tiptonville dome, western Tennessee. Geomorphology 43(2002), 313–349; Tuttle, M.P., Schweig, E.S., Sims, J.D., Lafferty, R.H., Wolf, L.W., Haynes, M.L., 2002. The earthquake potential of the New Madrid seismic zone, Bulletin of the Seismological Society of America, v 92, n. 6, p. 2080–2089; Tuttle, M.P., Schweig III, E.S., Campbell, J., Thomas, P.M., Sims, J.D., Lafferty III, R.H., 2005. Evidence for New Madrid earthquakes in A.D. 300 and 2350 B.C. Seismological Research Letters 76, 489–501]). The two most recent prehistoric and the 2350 B.C. events were probably also earthquake sequences with approximately the same magnitude as the historic sequence.Surface deformation (faulting and folding) in an alluvial setting provides many examples of stream response to gradient changes that can also be used to date past earthquake events. Stream responses include changes in channel morphology, deviations in the channel path from the regional gradient, changes in the direction of flow, anomalous longitudinal profiles, and aggradation or incision of the channel ([Merritts, D., Hesterberg, T, 1994. Stream networks and long-term surface uplift in the New Madrid seismic zone. Science 265, 1081–1084.; Guccione, M.J., Mueller, K., Champion, J., Shepherd, S., Odhiambo, B., 2002b. Stream response to repeated co-seismic folding, Tiptonville dome, western Tennessee. Geomorphology 43 (2002), 313–349]). Uplift or depression of the floodplain affects the frequency of flooding and thus the thickness and style of vertical accretion or drowning of a meander scar to form a lake. Vegetation may experience trauma, mortality, and in some cases growth enhancement due to ground failure during the earthquake and hydrologic changes after the earthquake ([VanArdale, R.B., Stahle, D.W., Cleaveland, M.K., Guccione, M.J., 1998. Earthquake signals in tree-ring data from the New Madrid seismic zone and implications for paleoseismicity. Geology 26, 515–518]). Identification and dating these physical and biologic responses allows source areas to be identified and seismic events to be dated.Seven fault segments are recognized by microseismicity and geomorphology. Surface faulting has been recognized at three of these segments, Reelfoot fault, New Madrid North fault, and Bootheel fault. The Reelfoot fault is a compressive stepover along the strike-slip fault and has up to 11 m of surface relief ([Carlson, S.D., 2000. Formation and geomorphic history of Reelfoot Lake: insight into the New Madrid seismic zone. M.S. Thesis, University of Arkansas, Fayetteville, Arkansas, U.S.A]) deforming abandoned and active Mississippi River channels ([Guccione, M.J., Mueller, K., Champion, J., Shepherd, S., Odhiambo, B., 2002b. Stream response to repeated co-seismic folding, Tiptonville dome, western Tennessee. Geomorphology 43 (2002), 313–349]). The New Madrid North fault apparently has only strike-slip motion and is recognized by modern microseismicity, geomorphic anomalies, and sand cataclasis ([Baldwin, J.N., Barron A.D., Kelson, K.I., Harris, J.B., Cashman, S., 2002. Preliminary paleoseismic and geophysical investigation of the North Farrenburg lineament: primary tectonic deformation associated with the New Madrid North Fault?. Seismological Research Letters 73, 393–413]). The Bootheel fault, which is not identified by the modern microseismicity, is associated with extensive liquefaction and offset channels ([Guccione, M.J., Marple, R., Autin, W.J., 2005, Evidence for Holocene displacements on the Bootheel fault (lineament) in southeastern Missouri: Seismotectonic implications for the New Madrid region. Geological Society of America Bulletin 117, 319–333]). The fault has dominantly strike-slip motion but also has a vertical component of slip. Other recognized surface deformation includes relatively low-relief folding at Big Lake/Manila high ([Guccione, M.J., VanArdale, R.B., Hehr, L.H., 2000. Origin and age of the Manila high and associated Big Lake “Sunklands”, New Madrid seismic zone, northeastern Arkansas. Geological Society of America Bulletin 112, 579–590]) and Lake St. Francis/Marked Tree high ([Guccione, M.J., VanArsdale, R.B., 1995. Origin and age of the St. Francis Sunklands using drainage patterns and sedimentology. Final report submitted to the U. S. Geological Survey, Award Number 1434-93-G-2354, Washington D.C.]), both along the subsurface Blytheville arch. Deformation at each of the fault segments does not occur during each earthquake event, indicating that earthquake sources have varied throughout the Holocene.     

Petrological and mineralogical studies of Pan-African serpentinites at Bir Al-Edeid area, central Eastern Desert, Egypt

The studied serpentinites occur as isolated masses, imbricate slices of variable thicknesses and as small blocks or lenses incorporated in the sedimentary matrix of the mélange. They are thrusted over the associated island arc calc-alkaline metavolcanics and replaced by talc-carbonates along shear zones. Lack of thermal effect of the serpentinites upon the enveloping country rocks, as well as their association with thrust faults indicates their tectonic emplacement as solid bodies. Petrographically, they are composed essentially of antigorite, chrysotile and lizardite with subordinate amounts of carbonates, chromite, magnetite, magnesite, talc, tremolite and chlorite. Chrysotile occurs as cross-fiber veinlets traversing the antigorite matrix, which indicate a late crystallization under static conditions. The predominance of antigorite over other serpentine minerals indicates that the serpentinites have undergone prograde metamorphism or the parent ultramafic rocks were serpentinized under higher pressure. The parent rocks of the studied serpentinites are mainly harzburgite and less commonly dunite and wehrlite due to the prevalence of mesh and bastite textures. The serpentinites have suffered regional metamorphism up to the greenschist facies, which occurred during the collisional stage or back-arc basin closure, followed by thrusting over a continental margin. The microprobe analyses of the serpentine minerals show wide variation in SiO₂, MgO, Al₂O₃, FeO and Cr₂O₃ due to different generations of serpentinization. The clinopyroxene relicts, from the partly serpentinized peridotite, are augite and similar to clinopyroxene in mantle-derived peridotites. The chromitite lenses associated with the serpentinites show common textures and structures typical of magmatic crystallization and podiform chromitites. The present data suggest that the serpentinites and associated chromitite lenses represent an ophiolitic mantle sequence from a supra-subduction zone, which were thrust over the continental margins during the collisional stage of back-arc basin.     

Discussion on influence of cavern’s span on surrounding rock classification

The influence of cavern’s span on surrounding rock classification is getting more and more recognition along with large span underground working’s increasingly coming forth. The authors analyse the timbering expense of cavern in jointed rock mass, the radius of plastic loosened zone and the size effect of macroscopical mechanical parameters of rock mass. Based on the complexion of depressing of surrounding rock’s stability due to increment of cavern’s span, the authors pinpoint attaching importance to the influence of cavern’s span on surrounding rock classification; and suggest reckoning the factor of cavern’s span in surrounding rock classification scientifically by studying the size effect of rock mass’s physico-mechanical parameters.     

北方农牧交错带退耕还林还草经济政策优化调控

退耕还林还草作为北方农牧交错带生态重建的切入点,在实际操作中也不可避免地存在一定的问题。文章对当前退耕还林还草的社会经济特征、政策安排、协调机制及制约因素进行了分析。提出:区域粮食适度自给定位、部门协调机制创新、产权制度改革、区域产业专业化分工、适度生态移民及建立生态补偿机制为进行政策优化调控的主要途径。     

An alternative Boussinesq equation considering the effect of hysteresis on coastal groundwater waves

This paper presents an alternative Boussinesq equation considering hysteresis effect via a third‐order derivative term. By introducing an improved moisture–pressure retention function, this equation describes, with reasonable precision, groundwater propagation in coastal aquifers subject to Dirichlet boundary condition of different oscillation frequencies. Test results confirmed that it is necessary to consider horizontal and vertical flows in unsaturated zone, because of their variable influences on hysteresis. Hysteresis in unsaturated zone can affect the water table wave number of groundwater wave motion, such as wave damping rate and phase lag. Oscillations with different periods exert different hysteresis effect on wave propagation. Truncation/shrinkage of unsaturated zones also affects the strength of hysteresis. These impacts can be reflected in the alternative Boussinesq equation by adjusting the parameter representing the variation rate of moisture associated with pressure change, as opposed to traditional computationally expensive hysteresis algorithms. The present Boussinesq equation is simple to use and can provide feasible basis for future coupling of groundwater and surface water models. Copyright © 2016 John Wiley & Sons, Ltd.     

Mixing of event and pre‐event water in a shallow Entisol in sloping farmland based on isotopic and hydrometric measurements,SW China

Water percolation and flow processes in subsurface geologic media play an important role in determining the water source for plants and the transport of contaminants or nutrients, which is essential for water resource management and the development of measures for pollution mitigation. During June 2013, the dynamics of the rainwater, soil water, subsurface flows and groundwater in a shallow Entisol on sloping farmland were monitored using a hydrometric and isotopic approach. The results showed that effective mixing of rainwater and soil water occurred in hours. The rebound phenomenon of δD profiles in soils showed that most isotope‐depleted rainwater largely bypassed the soil matrix when the water saturation in the soil was high. Preferential‐flow, which was the dominant water movement pattern in the vadose zone, occurred through the whole soil profile, and infrequent piston‐flow was mainly found at 20–40 cm in depth. The interflow in the soil layer, composed of 75.2% rainwater, was only generated when the soil profile had been saturated. Underflow in the fractured mudrock was the dominant flow type in this hillslope, and outflow was dominated by base flow (groundwater flow) with a mean contribution of 76.7%. The generation mechanism of underflow was groundwater ridging, which was superimposed upon preferential‐flow composed mainly of rainwater. The quick mixing process of rainwater and soil water and the rapid movement of the mixture through preferential channels in the study soil, which shows a typical bimodal pore size distribution, can explain the prompt release of pre‐event water in subsurface flow. Water sources of subsurface flows at peak discharge could be affected by the antecedent soil water content, rain characteristics and antecedent groundwater levels. Copyright © 2016 John Wiley & Sons, Ltd.     

An Eocene/Oligocene blueschist‐/greenschist facies P–T loop from the Cycladic Blueschist Unit on Naxos Island,Greece: Deformation‐related re‐equilibration vs. thermal relaxation

Geothermobarometric and geochronological work indicates a complete Eocene/early Oligocene blueschist/greenschist facies metamorphic cycle of the Cycladic Blueschist Unit on Naxos Island in the Aegean Sea region. Using the average pressure–temperature (P–T) method of thermocalc coupled with detailed textural work, we separate an early blueschist facies event at 576 ± 16 to 619 ± 32°C and 15.5 ± 0.5 to 16.3 ± 0.9 kbar from a subsequent greenschist facies overprint at 384 ± 30°C and 3.8 ± 1.1 kbar. Multi‐mineral Rb–Sr isochron dating yields crystallization ages for near peak‐pressure blueschist facies assemblages between 40.5 ± 1.0 and 38.3 ± 0.5 Ma. The greenschist facies overprint commonly did not result in complete resetting of age signatures. Maximum ages for the end of greenschist facies reworking, obtained from disequilibrium patterns, cluster near c. 32 Ma, with one sample showing rejuvenation at c. 27 Ma. We conclude that the high‐P rocks from south Naxos were exhumed to upper mid‐crustal levels in the late Eocene and early Oligocene at rates of 7.4 ± 4.6 km/Ma, completing a full blueschist‐/greenschist facies metamorphic cycle soon after subduction within c. 8 Ma. The greenschist facies overprint of the blueschist facies rocks from south Naxos resulted from rapid exhumation and associated deformation/fluid‐controlled metamorphic re‐equilibration, and is unrelated to the strong high‐T metamorphism associated with the Miocene formation of the Naxos migmatite dome. It follows that the Miocene thermal overprint had no impact on rock textures or Sr isotopic signatures, and that the rocks of south Naxos underwent three metamorphic events, one more than hitherto envisaged.