安徽滁州和管店早白垩世高镁埃达克质侵入岩的成因:锆石U-Pb年代学和Sr-Nd-Hf同位素的制约

本文以华北陆块东部早白垩世滁州闪长玢岩和管店石英闪长岩为研究对象,报道了新的全岩地球化学（主量元素、微量元素以及Sr-Nd同位素）以及锆石U-Pb年代学和Hf同位素的综合研究结果,进而约束其岩石成因和构造意义。滁州闪长玢岩中锆石发育振荡环带,管店石英闪长岩中锆石具条痕状吸收的特点,它们均为岩浆成因。锆石LA-ICP-MS U-Pb定年结果显示,滁州和管店闪长质锆石年龄分别为128±1Ma和130±2Ma,表明二者均形成于早白垩世。地球化学特征显示,滁州和管店闪长质岩石具有类似的主量元素和微量元素组成,整体具中等的SiO₂含量（58.55%~60.12%）和富MgO（4.43%~5.10%,Mg^#=57~61）的特征,Na₂O/K₂O比值为1.20~1.47,属于高钾钙碱性系列岩石;富集轻稀土元素和大离子亲石元素（如Rb、Ba）,亏损重稀土元素和高场强元素（如Nb、Ta、Zr、Hf）,并具不同程度的Eu负异常（δEu=0.85~0.93）。它们具高的Sr（575×10^-6~1035×10^-6）和低的Y含量（10.2×10^-6~15.3×10^-6）以及高的Sr/Y比值（57~69）,属于埃达克质岩石。此外,滁州和管店闪长质岩石具有类似的Sr-Nd以及锆石Hf同位素的特征,滁州闪长玢岩的⁸⁷Sr/⁸⁶Sr初始比值介于0.7061~0.7066之间,ε_Nd（t）值为-17.7~-16.9,锆石ε_Hf（t）值变化于-23.1~-19.1之间,而管店石英闪长岩的⁸⁷Sr/⁸⁶Sr初始比值为0.7046~0.7059,ε_Nd（t）值为-18.7~-15.8,锆石ε_Hf（t）值为-25.6~-20.0。综合上述,滁州和管店闪长质岩石均属于高镁埃达克质岩石,起源于拆沉的加厚下地壳部分熔融的熔体与地幔橄榄岩反应的产物,形成于早白垩世华北东部陆块拆沉作用下的伸展背景。     

松嫩盆地北部林甸地热田供暖尾水处理试验

将混入污染物和杂质的地热尾水直接排向地表水体,会造成水、土环境污染,也会造成水资源的浪费。为高效减少地热尾水中污染物,实现供暖地热尾水的无害化排放,以林甸县花园镇供暖地热尾水为例,通过混凝沉淀、超滤、纳滤工艺开展供暖尾水处理的室内实验和中试试验研究,连续监测获取地热尾水各处理工艺运行参数,组合工艺稳定运行期间监测到溶解性总固体浓度由5 824.7 mg/L降为432.40 mg/L、氯化物浓度由3 010.13 mg/L降为194.16 mg/L、氟化物浓度由1.57 mg/L降为0.31 mg/L、硼浓度由4.04 mg/L降为1.62 mg/L。确定该区地热尾水处理的最佳组合工艺为采用超滤运行压力为0.1 MPa,纳滤膜为陶氏NF90,操作压力为0.60 MPa,进水量为0.8 m3/h。室内实验溶解性总固体去除率90.21%～92.49%,氯化物去除率91.63%～93.02%,氟化物去除率96.81%,硼去除率55.20%～55.69%。中试试验溶解性总固体去除率为92.62%;氯化物浓度200 mg/L,氯化物去除率为92.57%;硼浓度1.77 mg/L,硼去除率为55.7%,以上实验结果均达到相关规范标准。试验证明本工艺处理松嫩盆地北部林甸地热田供暖尾水是可行的,解决了供暖尾水处理中资源浪费和尾水回收利用的技术性问题,为地热资源可持续利用提供了新的途径。     

鄂尔多斯盆地南部马莲河流域地下水中锶富集特征及成因分析

马莲河流域地处鄂尔多斯盆地南部黄土高原区,按储水介质和埋藏条件可将地下水分为黄土潜水、基岩潜水和基岩承压水三类,利用2015—2018年流域的295组地下水水化学数据,分析了地下水中锶(Sr²⁺)的质量浓度水平、垂向分布及沿流向分布的特征,并采用因子相关性研究地下水中Sr²⁺的来源和富集成因。结果表明:马莲河流域地下水富锶现象显著,黄土潜水、基岩潜水和基岩承压水中锶的平均质量浓度分别为1.14 mg/l、1.39 mg/l和5.24 mg/l;地下水中锶富集成因主要是含锶矿物天然状态下的水-岩作用,黄土潜水、基岩潜水和基岩承压水三类地下水中Sr²⁺的主要来源分别为碳酸盐岩与铝硅酸盐岩、碳酸盐岩与硫酸盐和碳酸盐矿物的溶滤作用;地下水中Sr²⁺的质量浓度沿流向呈逐渐增大的趋势,在不同区域中随深度变化的趋势不一致。     

A Comparative Study of the Coal‐forming Characteristics of Marginal Sea Basins and Epicontinental Sea Basins

The coal-forming characteristics,as well as the similarities and differences between epicontinental sea basins and continental marginal sea basins developed during different time periods,were analyzed in this study by adopting comparative analysis thoughts and methods.The results obtained in this study revealed that epicontinental basins and marginal sea basins are both characterized by the main development of thin coal seams or extremely thin coal seams.In addition,changes in sea levels were determined to be the main controlling factors for coal formation,and there were similarities in the continent-sea interactions and coal-forming sedimentary systems of the different basins.However,there were also significant differences observed in the sea level change events,basin basement structural characteristics,coal seam stability levels,accumulation and aggregation characteristics,and the migration patterns of coal-forming materials.For example,the marginal sea basins in the South China Sea were found to be characterized by strong tectonic activities,diversity and complexity.The basin structures showed complex patterns of depressions,uplifts and concave or sag uplifts,which tended to lead to greater complexity in the paleogeographic patterns of the coal formations.This had subsequently resulted in complex coal-forming processes and paleogeographic characteristics,in which the coal-forming zones displayed bead-like distributions,and the enrichment areas and centers were scattered.The practical significance of studying the similarities and differences of the coal-forming characteristics between epicontinental basins and marginal sea basins is that the results can potentially be used to guide the predictions of coal-measure coal seam distributions in South China Sea,as well as provide valuable guidance for future explorations of natural gas reservoirs related to coal measures in the South China Sea area.     

羌塘盆地热觉茶卡-藏夏河地区泉水水化学特征及其地质意义

泉水的水化学特征可以反映氧化-还原环境和水动力条件,近年来被广泛地用于石油、天然气以及天然气水合物的找矿工作中。本文对羌塘盆地热觉茶卡—藏夏河地区37处泉水和13件地表水进行了水化学特征、水溶性烃类气体特征和水中氢氧同位素特征分析,结果表明,羌塘盆地热觉茶卡—藏夏河地区的水型主要为Na₂SO₄型和MgCl₂型,其次为NaHCO₃型和CaCl₂型。矿化度普遍较高,说明该区具有较好的保存条件。铵根离子的平均含量为0.895 g/g,在藏夏河地区高达7.381 g/g,表明在藏夏河东部地区有机质相对较为丰富,这与区域上发育的富有机质页岩结果一致。氢氧同位素结果显示,该区水体的氢氧同位素落在了大气降水线附近,表明水体的来源主要受大气降水的补给。另外,采集的9个泉水样品中均检测出一定含量的水溶甲烷,在白云湖地区的甲烷含量相对较高,显示出较好的油气潜力。综合研究表明,藏夏河东和白云湖地区具有良好的油气烃源岩条件,保存条件较好,显示出良好的油气和天然气水合物资源前景。     

Dissolution characteristics of deep?buried dolostone in the Member 5 of Ordovician Majiagou Formation in southern Ordos Basin

The different types of deep-buried dissolution process in the Member 5 of Ordovician Majiagou Formation in the southern Ordos Basin and its influence on the reservoir properties are studied in this paper. It shows that three types of mechanisms include organic acid fluid, hydrothermal fluid and TSR are identified through studies of core observation, thin section analysis, inclusion temperature, trace elements and rare earth elements. It is found that the dissolution of organic acid fluid causes the stratified dissolution pores, film-like asphaltene and ring-like asphaltene, while hydrothermal fluid causes the non-selective dissolution pores without petrofabric, veins of pyrites, massive pyrites and the association of hypothermal minerals. Four occurrence models of dissolution include, (1) the deep-buried dissolution of low-temperature hydrothermal fluid occurs in Zhiluo Period of Middle Jurassic; (2) the deep-buried dissolution of organic acid fluid started from the late Middle Jurassic followed by the first hydrocarbon injection; (3) the deep-buried dissolution of middle-high temperature hydrothermal fluid occurred in the Dongsheng Period of Early Cretaceous; (4) TSR occurred at the end of Early Cretaceous with the second larger hydrocarbon injection. Both organic acid fluid and hydrothermal fluid can improve the porosity and permeability of reservoir, but the hydrothermal fluid is more effective than that of organic acid fluid.     

砾石在分析盆地物源区迁移与湖岸线演化中的作用*

中国中西部盆地的盆山结合部位,勘探程度较低、钻井少、地震成像复杂,致使利用传统的地震相、测井相、岩心资料等研究原型盆地岩相古地理特征较为困难。基于露头中巨厚砾岩发育层段对应盆地内储集层平面展布范围最广这一认识,运用“将今论古”方法,建立南天山前现代冲积扇、扇三角洲平原、河流等沉积体系中砾石与搬运距离关系,以及不同沉积相类型中砾石发育产状与湖岸线远近关系,定量计算了准噶尔盆地多条重点剖面侏罗系—白垩系现今位置与沉积物源区和湖岸线演化的距离,恢复了侏罗纪—白垩纪物源区范围与湖岸线演化过程。认为侏罗纪—早白垩世砂砾岩储集体向盆地内延伸范围最大时期的湖岸线,明显与现今盆地边缘线有一向西北方向敞开的夹角,该认识对在编制岩相古地理图过程中以盆地边缘线即为湖岸线的观念提出了不同见解,为恢复准南等低勘探程度区原型盆地的岩相古地理特征、预测有利储集体的展布提供参数依据。建立的刻画物源区变化和湖岸线迁移的定量评价方法与参数,是对传统沉积学研究的有益补充。     

鱼粪化石特征对早侏罗世托阿尔期湖泊生态系统的启示:以川东大安寨段为例*

早侏罗世托阿尔期早期大洋缺氧事件(Toarcian Oceanic Anoxic Event,~183.8 Ma)是一次全球性的多幕式生物—环境事件,其在四川盆地下侏罗统自流井组大安寨段亦有显示。对采集自川东北地区大安寨段的鱼粪化石进行形态学描述和内含物分析,发现鱼粪化石中含有大量的磷质成分,多为未经消化的鱼骨化石,另有大量介壳类化石与有机质混杂在一起。据露头岩性和显微薄片特征认为: (1)粪化石呈螺旋状,生产该粪化石的鱼类为大型肉食性鱼类,其喜食小型鱼类和软体动物等,推测可能是肺鱼类(角齿鱼);(2)鱼粪化石形成于开放型淡水湖泊中的半深湖—深湖区,其中湖泊表层含氧量丰富,主要由生产者、消费者构成了研究区早侏罗世托阿尔期大型湖泊生态系统,食物链较为复杂,而湖底为水动力条件较弱的还原环境。该研究成果可为早侏罗世托阿尔期大洋缺氧事件在湖泊中的沉积响应及生态影响研究提供依据。     

四川盆地开江地区WT1井震旦系陡山沱组物源分析及构造背景判断*

为厘清四川盆地开江地区WT1井震旦系陡山沱组地层发育的构造背景,重塑其原型沉积盆地,为重建古地理及油气进一步勘探部署工作提供科学依据,利用岩石学、岩石地球化学及碎屑锆石U-Pb年代学手段对该井陡山沱组物源进行了分析。岩石地化结果表明WT1井陡山沱组沉积物源岩为中基性火山岩类且经历了中等程度化学风化作用;碎屑锆石U-Pb年龄主要记录了915~850Ma、794~714.5Ma以及622~700Ma 3个阶段的构造岩浆活动,与扬子克拉通北缘及邻区Rodinia超大陆的裂解演化过程有关,该构造活动背景下的中基性火山岩是WT1井陡山沱组沉积的主要物质来源。结果表明四川盆地开江地区的陡山沱组发育于拉张伸展构造背景,属克拉通内裂陷盆地沉积,有利于烃源岩层的发育;同时为Rodinia超大陆的裂解演化过程提供了重要的年代学演化证据。该成果对深入认识四川盆地的地质结构、沉积-构造演化以及油气勘探的战略部署等具有极为重要的科学意义。