柱撑蛭石吸附去除废水中重金属离子的实验研究

分别利用有机柱化剂十二烷基磺酸钠(SDS)和无机柱化剂聚羟基铝(HA)对蛭石进行柱撑制得十二烷基磺酸钠柱撑蛭石(SDS-V erm icu lite)和聚羟基铝柱撑蛭石(HA-V erm icu lite),并通过XRD、红外光谱、ZETA电位等表征手段对柱撑蛭石进行表征,同时针对柱撑蛭石对Cu2 ,Cd2 ,C r3 3种重金属离子的吸附进行研究,结果表明:吸附去除率受反应时间、重金属离子的初始浓度、pH值等因素的影响,经柱撑后的蛭石对重金属离子吸附的吸附性能比蛭石原矿要强。柱撑蛭石吸附3种重金属离子的动力学吸附过程可用E lov icb方程和双常数方程进行较好的拟合。     

含部分晶须的钛酸锂的制备及其性能表征

L i4T i5O12是一种循环性能好、有很好的充放电平台、理论比容量较大、不与电解液反应的新型负极材料,研究探索以偏钛酸和碳酸锂为主要原料制备含部分晶须的尖晶石型晶型L i4T i5O12的一种方法。通过此工艺在1 000℃煅烧8 h后在样品中约20%的晶须出现,晶须的直径≤0.5μm,晶须的长度约为7μm。     

胶东乳山金矿蚀变岩中绢云母40Ar/39Ar年龄及其对金成矿事件的制约

胶东乳山金矿是我国单脉金储量最大的矿床,金的成矿具有多期多阶段的特点。为了研究早期矿化的时代,利用绢云母40Ar/39Ar法测定了乳山金矿含矿脉体旁围岩蚀变带中的绢英岩年龄。结果表明,围岩花岗岩的强烈绢英岩化蚀变年龄为129 Ma,比金发生大规模沉淀的成矿时间早约10 Ma,表明乳山金矿是多期热液成矿事件的产物,但这一事件也发生于120±10 Ma,从而证明乳山金矿与胶东其他地区金矿一样都是在中生代构造机制转折、岩石圈强烈减薄的构造背景下集中成矿的,这为进一步认识乳山金矿的成因机制和成矿动力学背景提供了新的证据。     

有机地球化学指标的分析

有机地球化学的指标经过近几十年的研究,已能较好地指导油气勘探工作。通过对未熟—低熟烃源岩及原油与成熟烃源岩及原油的有机地球化学指标的比较,着重论述了未熟—低熟油、源中可用的指标系列及内涵,指出成熟度方面甾烷C2920Rββ/(αα ββ)、αααC2920S/(20S 20R)及βα-莫烷/αβ-藿烷和ββ-藿烷等是比较可靠的地球化学参数;在生源方面非环状类异戊二烯化合物、三环萜烷和四环萜烷系列等是可靠的标志物;形成环境方面β-胡萝卜烷及重排甾烷/规则甾烷等都是重要的指标。     

1961-2018年西南地区夏季干旱变化特征及其与环流异常的联系

利用1961—2018年中国西南地区312站降水观测资料、NCEP/NCAR再分析资料及海表温度资料,采用夏季SPI(Standardized Precipitation Index)指数作为干旱指数,研究了西南地区夏季干旱变化特征及其与环流异常的联系。结果表明:西南地区夏季总体呈现变干趋势,尤其在云南、四川东南部干旱化趋势显著。当西南地区夏季显著干旱时,该地区对流层低层辐散、上层辐合,且向该地区的水汽输送偏少。造成西南地区干旱维持的原因可归结为大气波动活动异常和海温异常强迫。前者通过西风带扰动向下游的能量频散,为西南地区低层辐散、上层辐合的环流异常的形成和维持提供了必要的扰动能量积聚;后者通过热带西北太平洋异常热源对大气的强迫,使得该地区对流层低层(上层)形成异常辐合(辐散),在西南地区和热带西北太平洋形成了斜向垂直环流,使西南地区受下沉气流控制,从而形成了利于降水显著偏少和干旱发生并维持的条件。     

对IPCC第六次评估报告中有关干旱变化的解读

政府间气候变化专门委员会（IPCC）于2021年8月发布了第六次评估报告（AR6）自然科学基础卷的决策者摘要,主要对自2013年第五次评估报告（AR5）以来的气候变化科学研究进展进行了系统的评估,并使用新一代气候模式在新的共享社会经济路径情景下对未来气候变化进行了预估。本文基于AR5和AR6相关章节素材,解读了干旱变化的评估结论。     

振动测量用叉指式硅微加速度计性能研究

硅MEMS加速度仪可以用于地震以及各种工程振动的测量,目前其精度较低,温度灵敏度较高,为了掌握MEMS加速度计的特性,提高其实用性能,本文介绍了一种叉指式硅微机械加速度计(FMSA)表头微结构和系统的工作原理,推导了微结构梁的刚度,利用ANSYS有限元软件分析了FM-SA加速度计的静态特性、动态特性和温度特性,验证了推导的正确性,说明微结构参数是决定FMSA加速度计性能的主要因素,为改进加速度计性能提供了依据,并对其在振动观测领域实际应用提供了理论指导。     

Pushover analysis procedure for systems considering SSI effects based on capacity spectrum method

This paper presents a new procedure to transform an SSI system into an equivalent SDOF system using twice equivalence. A pushover analysis procedure based on the capacity spectrum method for buildings with SSI effects （PASSI） is then established based on the equivalent SDOF system, and the modified response spectrum and equivalent capacity spectrum are obtained. Furthermore, the approximate formulas to obtain the dynamic stiffness of foundations are suggested. Three steel buildings with different story heights （3, 9 and 20） including SSI effects are analyzed under two far-field and two near-field historical records and an artificial seismic time history using the two PASSI procedures and the nonlinear response history analysis （NLhRHA） method. The results are compared and discussed. Finally, combined with seismic design response spectrum, the nonlinear seismic response of a 9-story building with SSI effects is analyzed using the PASSI procedures, and its seismic performance is evaluated according to the Chinese ＇Code for Seismic Design of Buildings. The feasibility of the proposed procedure is verified.     

Joint probability density function of the stochastic responses of nonlinear structures

The joint probability density fimction （PDF） of different structural responses is a very important topic in the stochastic response analysis of nonlinear structures. In this paper, the probability density evolution method, which is successfully developed to capture the instantaneous PDF of an arbitrary single response of interest, is extended to evaluate the joint PDF of any two responses. A two-dimensional partial differential equation in terms of the joint PDF is established. The strategy of selecting representative points via the number theoretical method and sieved by a hyper-ellipsoid is outlined. A two-dimensional difference scheme is developed. The free vibration of an SDOF system is examined to verify the proposed method, and a flame structure exhibiting hysteresis subjected to stochastic ground motion is investigated. It is pointed out that the correlation of different responses results from the fact that randomness of different responses comes from the same set of basic random parameters involved. In other words, the essence of the probabilistic correlation is a physical correlation.     

Reconstruction of earthquake hazard in regions of sparse seismic monitoring

Studying strong motion records and the spatial distribution of ground shaking is of great importance in understanding the underlying causes of damage in earthquakes. Many regions in the world are either not instrumented or are sparsely instrumented. As such, significant opportunities for motion-damage correlations are lost. Two recent and damaging earthquakes belong to the class of lost opportunities, namely the Kashmir (Pakistan) earthquake of October 2005 and the Yogyakarta (Indonesia) earthquake of May 2006. In this paper, an overview of the importance of supply and demand studies in earthquake-stricken regions is given, followed by two examples of investigative engineering seismology aimed at reconstructing the hazard from sparse data. The paper closes with a plea for responsible authorities to invest in seismic monitoring networks in the very near future.