Selenium concentration in food and blood of residents of Abeokuta Metropolis,Southwestern Nigeria

Selenium like any other element can both be essential and toxic depending upon the concentration at which it occurs in human diet. This paper assessed the level of this trace element in twenty different (20) types of locally produced food items around Abeokuta town and the blood obtained from the antecubital fossa vein of eighty-eight (88) healthy adults resident in Abeokuta.     

Measurements of net all-wave radiation at a tropical location,Ile-Ife,Nigeria

Hourly averaged net all-wave radiation data spanning a complete three-year period (2010-2012) at a meteorological station located inside the Obafemi Awolowo University campus in Ile-Ife (7.52° N, 4.52° E), Nigeria is presented in this study to investigate its diurnal and seasonal variations. Using a high-sensitivity four-component net radiometer, the data represents so far the most consistent and detailed information available for a tropical location in West Africa. From the dataset, hourly maxima of the net radiation occurred at 14:00 LT (GMT + 1), whose values increased considerably from 337.6 ± 146.4 Wm⁻² in July, which is the peak of the wet season, to 441.7 ± 82.4 Wm⁻² in March, the end of the dry season. April and October, both of which mark the beginning and end of the raining season at Ile-Ife have recorded the highest values of 584.7 and 612.2 Wm⁻², respectively. There was strong intra/inter-seasonal variation observed in the monthly mean values of the net radiation due mainly to the fluctuations in cloudiness and humidity. In the study area, the data indicated a net radiative heating taking place at the surface, whose annual trend follows a bimodal distribution. The present data supports the results published in earlier studies by other authors.     

尼日利亚巴古多(Bagudo)锰矿地质特征及找矿标志

尼日利亚的巴古多(Bagudo)锰矿是近年新发现的具有找矿潜力的沉积变质型锰矿床,位于马如—安卡费金铜铁成矿带的西北缘附近。矿区共圈定了3个锰矿区,锰矿体出露于地表,整体呈NW向或近SN向延伸。矿体中的条纹状锰矿石和块状锰矿石均属低磷中铁中品位的氧化锰-硅酸锰混合矿石,且块状锰矿石锰品位低于条纹状锰矿石。目前矿区的勘查深度主要为-50m以上的浅表部分,深部的勘查工作尚未进行。由于锰矿石具弱磁性,故而高精度磁异常的部位具有找锰意义。     

Contamination risk assessment of fresh groundwater using the distribution and chemical speciation of some potentially toxic elements in Calabar (southern Nigeria)

The computer program PHREEQC was used to determined the distribution, chemical speciation and mineral saturation indices in a fresh groundwater environment with limited mining activities in the adjoining areas. The aim was mainly to determine the potential risk of a coastal plain aquifer contamination by some potentially toxic elements. The results show that the elements Ba, Cd, Cu, Fe, Mn, Ni, Rb, Sr, and Zn are distributed as free metal ions. Arsenic is in the neutral form of H₃AsO₃ ^o, while three species of aluminium [Al³⁺, AlOH₂, Al(OH)₂ ⁺] dominate. The major species of uranium include UO₂CO₃, UO₂²⁺+, UO₂⁺, and UO₂OH⁺, respectively, in order of abundance. The groundwater is saturated with respect to alunite [KAl₃ (SO₄)₂ (OH)₆], basaluminite [Al₄ (OH)₁₀ SO₄], boehmite [Al(OH)], Cu metal (Cu), cuprous ferrite (CuFeO₂), diaspore [AlO(OH)], gibbsite [Al(OH)₃], goethite (FeOOH), hematite (Fe₂O₃), magnetite (Fe₃O₄) and uraninite (UO₂). Most of the species are not mobile under the prevailing pH (3.3 to 5.9) and Eh (7 to 158 mV) conditions. The mobile ones are very low in concentration and will be immobilized by precipitation of mineral phases. The study concludes that presently these species do not pose any risk to the aquifer.     

‘Borehole Race’ and the Dilemma of Governing the ‘Ungoverned’: Understanding the Urban Political Ecology of Groundwater Exploitation in Nigeria

Groundwater exploitation is an essential aspect of the numerous processes of transforming the urban natural environment for human gains. We use the political ecology of borehole exploitation in Nigeria’s urban environment to understand the micro-and macro-level processes mediating the transformation and changes in urban “groundwater scape”. The fieldwork processes depend on field counting of borehole distribution, in-depth and semi-structured interviews, and a review of secondary literatures. We argue that the social and environmental changes arising from the exploitation of groundwater bespeak the active and continual manifestation of the interplay of combustible interests and power friction among institutional agents within the permissible range of the natural environment. Such dynamic power relations engender a pattern of socio-natural transformation consistent with Swyngedouw’s notion of urban metabolism- “a series of interconnected heterogeneous and dynamic but contested and contestable processes of continuous quantitative and qualitative transformations that re-arranges humans and non-humans in new and often unexpected ways”.     

Estimate of shallow groundwater recharge in the Hadejia–Nguru Wetlands, semi-arid northeastern Nigeria

 The Hadejia–Nguru Wetlands are annually inundated flood plains in semi-arid northeastern Nigeria. The area has a unique ecosystem that forms a natural barrier against the encroachment of the Sahara desert. Both the rich wetland vegetation and local farmers using shallow tube wells depend on a groundwater mound (with a water table less than 6 m below the surface) that is present in the unconfined aquifer under the flood-plain area. Using well records (1991–97) and a hydrogeologic profile based on piezometers that were monitored for two years, it is shown that recharge through the annually inundated flood plains is the source of the groundwater mound. Maintenance of the groundwater-recharge function of the flood plains depends on wet-season releases from two large upstream dams. On the basis of a water-budget method, the mean (1991–97) wet-season unconfined groundwater recharge in the flood-plain area between Hadejia and Nguru and in the immediate vicinity (1250 km²) is estimated to be 132 mm (range, 73–197 mm). Outflow from the unconfined flood-plain aquifer to the unconfined upland aquifer is approximately 10% of the wet-season flood-plain recharge. The unconfined groundwater outflow from the flood-plain area can provide a significant contribution to the present-day rural water supply in the surrounding uplands, but it does not offer much potential for additional groundwater abstraction. In addition to outflow to the upland aquifer (∼14 mm), the distribution of the annually recharged water volume of the shallow flood-plain aquifer is (1) domestic uses (3 mm), (2) small-scale irrigation (∼15 mm), and (3) evapotranspiration ( 1 100 mm). Along the hydrogeologic profile, the recharge in the upland (i.e., outflow from the unconfined flood-plain aquifer and possibly diffuse rain-fed recharge) is in balance with the water uses (i.e., domestic uses, groundwater outflow, and evapotranspiration). The absence of a seasonal water-level trend in the two piezometers in the upland indicates that no rain-fed recharge occurs through preferential path-way (macropore) flow. Received, June 1998 / Revised, November 1998, January 1999 / Accepted, January 1999     

Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence

Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin, Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry. The bulk carbon isotopic values of the whole rock extracts, saturate and aromatic fractions range from –28.7‰ to –26.8‰, –29.2‰ to –27.2 ‰ and –28.5 ‰ to –26.7 ‰, respectively while the bulk carbon isotopic values of the whole oils, saturate and aromatic fractions range from –25.4 ‰ to –27.8 ‰, –25.9 ‰ to –28.4 ‰ and –23.5 ‰ to –26.9 ‰, respectively. The average carbon isotopic compositions of individual alkanes (nC₁₂-nC₃₃) in the rock samples range from –34.9‰ to –28.2‰ whereas the average isotopic values of individual n-alkanes in the oils range from –31.1‰ to –23.8‰. The δ¹³C isotope ratios of pristane and phytane in the rock samples range from –29.2 ‰ to –28.2 ‰ and –30.2 ‰ to –27.4 ‰ respectively while the pristane and phytane isotopic values range from –32.1‰ to –21.9‰ and –30.5‰ to –26.9‰, respectively. The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments. The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.     

Delineation of saltwater intrusion into the freshwater aquifer of Lekki Peninsula,Lagos, Nigeria

Recently, the deterioration of water quality in the coastal zones of Lekki Peninsula area of Lagos due to saltwater infiltration into the freshwater aquifer has become a major concern. With the aim of providing valuable information on the hydrogeologic system of the aquifers, the subsurface lithology and delineating the groundwater salinity, vertical electrical resistivity (VES) sounding survey was carried out utilizing surface Schlumberger electrode arrays, and electrode spacing varying between 1 and 150 m. The DC resistivity surveys revealed significant variations in subsurface resistivity. Also, the VES resistivity curves showed a dominant trend of decreasing resistivity with depth (thus increasing salinity). In general, the presence of four distinct resistivity zones were delineated viz.: the unconsolidated dry sand (A) having resistivity values ranging between 125 and 1,028 Ωm represent the first layer; the fresh water-saturated soil (zone B) having resistivity values which correspond to 32–256 Ωm is the second layer; the third layer (zone C) is interpreted as the mixing (transition) zone of fresh with brackish groundwater. The resistivity of this layer ranges from 4 to 32 Ωm; while layer four (zone D) is characterized with resistivities values generally below 4 Ωm reflecting an aquifer possibly containing brine. The rock matrix, salinity and water saturation are the major factors controlling the resistivity of the formation. Moreover, this investigation shows that saline water intrusion into the aquifers can be accurately mapped using surface DC resistivity method.     

Species composition and gear characteristics of the <Emphasis Type="Italic">Macrobrachium</Emphasis> fishery of the Cross River Estuary,Nigeria

The Cross River Estuary, Nigeria, is an important shrimping area for artisanal fishermen of the coastal communities. The multi-species Macrobrachium fishery is exploited with three main gears, namely beach seine, push net and trap. Studies on species composition of this fishery recorded thirteen shrimp species, one swimming crab (Callinectes amnicola) and two fish species (Eleotris sp. and Pellonula leonensis). The shrimp species identified included Macrobrachium macrobrachion (83.39% and 55.69% by number and weight, respectively), M. vollenhovenii (9.66% and 37.18%), M. equidens (3.8% and 2.87%), juveniles-sub-adults of Penaeus notialis (1.11% and 1.3%), M. dux, M. felicinum, Palaemonetes africanus, Palaemon maculatus, Palaemon elegans, Desmocaris sp., Leander sp., Nematopalaemon hastatus and Alpheus pontederiae. While the selectivity index for trap was 0.25, beach seine and push net had a lower index of 0.063. The results present the first comprehensive and representative report for the Estuary shrimp fishery and will assist in the management of the biodiversity of this ecosystem.