重庆喀斯特山地典型表层岩溶泉水化学分析

表层岩溶泉是储存于表层岩溶带的地下水,为近地面的表层地下水系统,它的普遍分布是西南岩溶峰丛区居民聚集和繁衍的重要条件。本文选取重庆市南川区典型的岩溶峰丛区6个较有代表性的表层岩溶常流泉点,分析表层岩溶泉水化学特征。研究发现：①6个泉点泉水化学类型以HCO3.SO4-Ca型为主,其次为HCO3.SO4-Ca.Mg型,个别为HCO3-Ca型;②常规水化学指标中,受人类活动的影响,各泉点泉水HCO3-含量较高,SO42-和NO3-含量偏高。③各泉点微量金属元素除As和Ba未达地下水质量标准GB/T 14848-1993Ⅰ类水体标准,其余测试指标均符合Ⅰ类水体标准。     

基于谱分析法的深水半潜式平台疲劳强度分析

以某新型深水半潜式钻井平台为分析对象,依据三维绕射理论计算单位波幅下波浪诱导载荷,通过建立三维有限元模型计算完成了热点应力响应。运用热点应力的谱分析法计算得到危险节点的疲劳寿命,并进一步分析了各个短期海况和不同浪向对节点总的疲劳损伤度的贡献。研究结果表明,危险节点的疲劳寿命都满足设计寿命要求;在各种中低海况下,疲劳损伤主要来自于平均跨零周期在6 s附近,有义波高转大的短期海况;平台关键连接部位的疲劳损伤主要是在横浪和斜浪状态下产生的,并且对某单一方向的波浪非常敏感。此研究对该类型平台的连接处结构设计和疲劳分析方法有参考意义。     

Definition of catchment area in karst: case of the rivers Krčić and Krka,Croatia

Abstract

The study area consists of the spring zones of the Kr?i?, Krka and Cetina river catchments located in the Dinaric karst, Croatia. Classical hydrological approaches and some newer time and frequency domain methods are used in order to validate the existing hypotheses both qualitatively and quantitatively, and these contribute to factual information about the hydrological behaviour of the catchments. The groundwater recharge rates are calculated by a mathematical model based on Palmer's soil-moisture balance method. The values of parameters of the groundwater recharge model are estimated by the spectral method. The calculated monthly and annual groundwater recharge rates form the basis for estimating the hydrological catchment areas of the spring zones and also for the determina-tion of quantitative relationships between the catchments.     

Monthly and annual effective infiltration coefficients in Dinaric karst: example of the Gradole karst spring catchment

Abstract

The method of “historic event” is used to generate synthetic hyetographs based on statistical analysis of precipitation data. A synthetic triangular model was developed based on rainfall data of Zioud watershed (central Tunisia) with a standard time step of one hour. A database of 2799 observed rainfall events was used to provide statistical parameters for a simple triangular-shaped hyetograph model. The developed model provides a synthetic hyetograph in dimensionless form for different storm durations (2, 3 and 4 hours). For a given season and location, the variation of the first dimensionless moment with duration was relatively small, with an average range of 13% for all the stations. The resulting dimensionless hyetographs were found to be nearly identical when they were non-dimensionalized using the rainfall depth and duration, showing some seasonal effect and insignificant effects of the rainfall duration. A good agreement between simulated and observed hyetographs was achieved based on not only visual impressions, but also statistical numerical and graphical tests.     

Seismic tests on reinforced concrete and steel frames retrofitted with dissipative braces

Seismic tests have been conducted on two 3‐storey structures protected with pressurized fluid‐viscous spring damper devices. One of the structures was a reinforced concrete frame with clay elements in the slabs, while the other one was a steel frame with steel/concrete composite slabs. The spring dampers were installed through K bracing in between the floors. The tests were performed by means of the pseudodynamic method, which allowed the use of large and full‐size specimens, and by implementing a specific compensation strategy for the strain‐rate effect at the devices. The test results allowed the verification of the adequacy of the attachment system as well as the comparison of the behaviour of the unprotected buildings with several protected configurations, showing the benefits of the application of the devices and the characteristics of their performance. The response of the protected structures was always safer than that of the unprotected ones mainly due to a significant increase of equivalent damping. The increase in the damping ratio depends on the level of deformation. Copyright © 2004 John Wiley & Sons, Ltd.     

天星河、文峰河流域岩溶水化学及影响因素

重庆东北部地区巫溪天星河、文峰河的岩溶流域水化学特征研究结果表明:研究区泉水样品的p H值为6.47~8.28,平均值为7.79;流域河水饱和指数(SIc)的平均值为0.14,表明其变化受到流域碳酸盐岩分布的控制。水化学类型以HCO3-Ca型水为主,Ca2+和HCO-3平均分别占阳、阴离子的75%和82%。通过分析Gibbs图,发现泉水的主要组分属于"岩石风化类型",主要反映了岩石的溶解作用对泉水水化学的影响。流域内部分水样NO-3和SO2-4较高,可能是受工农业生产等人类活动的影响引起,此外硫酸也参与了碳酸盐矿物的溶解。     

A novel strategy using biodegradable EDDS for the chemically enhanced phytoextraction of soils contaminated with heavy metals

For the sake of cost and potential environmental risk, it is necessary to minimize the amount of chelates used in chemically-enhanced phytoextraction. In the present study, a biodegradable chelating agent, EDDS was added in a hot solution at 90℃ to the soil in which garland chrysanthemum （Chrysanthemum coronarium L.） and beans （Phaseolus vulgaris L., white bean） were growing. The application of hot chelate solutions was much more efficient than the application of normal chelate solutions （25℃） in improving the uptake of heavy metals by plants. When 1 mmol kg1 of EDDS as a hot solution was applied to soil, the concentrations ofCu, Zn and Cd and the total phytoextraction by the shoots of the two plant species exceeded or approximated those in the shoots of plants treated with 5 mmol kg^-1 of normal EDTA solution. The concentrations of metals in the shoots of beans were significantly correlated with the relative electrolyte leakage rate of root cells, indicating that the root damage resulting from the hot solution might play an important role in the process of chelate-enhanced metal uptake. The soil leaching study demonstrated that decreasing the dosage of chelate resulted in decreased concentrations of soluble metals in soils. On the 28th day following the application of chelate, the concentrations of soluble metals in the EDDS treated soil were not significantly different from the concentrations in the control soil to which chelates had not been applied.     

喜马拉雅造山带南北向裂谷的冷缩成因模型

长期以来,学者们普遍认为垂直于喜马拉雅造山带的南北向裂谷是东西向伸展的构造形迹。现代GPS观测数据却显示,喜马拉雅造山带东西位移(分)量很小,甚至为零。综合前人资料,喜马拉雅造山过程可划分为热造山(25~13Ma)及造山后(< 13Ma)冷却两个时期,热造山期具有受热膨胀,物质向外运移的特点,高喜马拉雅热隆挤出并触发各主要断裂(MCT、STD、GCT)活动,印度板块向北汇聚速率下降。造山后则表现为冷却收缩,前期构造-热活动停止或减弱,印度板块向北汇聚加速。研究认为,南北向裂谷与高喜马拉雅等冷却过程的东西向收缩。且被局限于东、西两个构造结之间有关。并据此建立了裂谷的冷缩成因模型,模型估值与地质事实很吻合。     

Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.     

Thermal bidirectional gap probability model for row crop canopies and validation

Land surface temperature is a key parameter in monitoring the status of crop water stress by remote sensing, and studying the water and energy balance in cropland ecosystem. The component temperatures of crop and soil are especially significant in remote …