水体中NH3-N对建鲤非特异性免疫功能的影响

用 0 .1、0 .5、1.0、2 .0和 5.0 mg/ L NH3- N分别刺激建鲤 10 d和 2 0 d后 ,测定了建鲤非特异性免疫指标 ,估测不同浓度的 NH3- N对建鲤非特异性免疫指标的影响。 0 .1、0 .5mg/ L的 NH3- N对建鲤NBT阳性细胞、溶菌酶活性无影响 ,1.0 mg/ L的 NH3- N可使 NBT阳性细胞数和溶菌酶活性降低 ,而2 .0和 5.0 mg/ L则使 NBT阳性细胞数和溶菌酶活性显著下降 ( P<0 .0 5)。这些结果表明水体中 0 .1、0 .5mg/ L的 NH3- N对建鲤非特异性免疫功能无影响 ,1.0 mg/ L的 NH3- N略有影响 ,而 2 .0和 5.0mg/ L的 NH3- N则明显降低了建鲤的非特异性免疫功能     

TOXIC EFFECTS OF Zn~(2+), Cu~(2+), Cd~(2+)and NH_3 ON CfflNESE PRAWN

This study deals with the toxic effects of Zn2+, Cu2+, Cd2+ and NH3 on Chinese prawn (Penaeus orientalis). The median lethal concentrations of the toxic matters on Chinese prawn were determined. Cd2+>Cu2+>Zn2+>NH3-Nm is the toxic order of these chemicals to Chinese prawn. The toxic order of concentrated Zn2+ and Cd2+ in tissues and organs of Chinese prawn is in the order gill > shell + appendage>viscera > muscle..     

The release behavior of inorganic nitrogen and phosphorus in sediment during disturbance

Sediments and surface water were sampled in a tide flat in the Huiquan Bay, Qingdao, China in January 2004 to simulate the exchange of NH4-N/NO3-N/ PO 43- between sediments and surface water. A working system was designed with which samples were shaken at 60, 120 and 150 revolutions per minute (r/min). Experiment results show that NH4-N concentration in water at shaking rate of 60r/min decreased gradually, while at 120r/min increased gradually. In resuspension, fine-grained sediments contributed most NH4-N to the seawater, followed by medium-grained and coarse-grained sediments. The NO3-N concentration in water had a negative relation with the shaking rate; the medium-grained sediments contributed more NO3-N to seawater than the coarse-and fine-grained sediments. The PO 43- concentration is positively related with the shaking rate, the fine-grained sediments were the main N and P contributor to the seawater, followed by medium-and coarse-grained sediments.     

Local and regional differences in the chemical potential of water in amphibolite facies pelitic schists

Abstract Mineral assemblages in different samples of amphibolite facies pelitic schists collected from two separate outcrops in the Moosilauke area, NH, record differences in the chemical potential of water during metamorphism. Mineralogical, petrological, and field relations indicate that mineral assemblages at both outcrops equilibrated at 520°C and 3.5–4.0 kbar. Thermodynamic analysis of the mineral assemblages demonstrates that maximum chemical potential differences at each outcrop were of the order of 150 calories, over distances of 10–20 m.
The differences in the chemical potential of water recorded in both bed-to-bed and outcrop-to-outcrop relations are consistent with the following conclusions: (1) mineral assemblages on a specific outcrop did not equilibrate with an external reservoir of fluid of fixed composition, (2) the relatively small magnitude of the chemical potential differences suggests little or no infiltration of externally derived fluid, (3) these differences on the outcrop scale are probably related to initial compositional variations and the buffer capacity of the mineral assemblage, and (4) the different values of the chemical potential of water exhibited by the various mineral assemblages permits an understanding of the effects of variable μ_H2O for amphibolite facies pelitic schists.     

改性红辉沸石去除水溶液中氨氮的初步研究

文章研究了采用酸、碱、盐改性红辉沸石和加热活化红辉沸石对改性红辉沸石去除水溶液中氨氮的影响效果。实验结果表明：（1）用红辉沸石去除溶液中氨氮的实验条件选择如下：1搅拌时间为30min;2沸石粒度为40～60目;3沸石用量为2g;4氯化氨溶液浓度为40mg/L;5氯化氨溶液用量为80ml。（2）采用高温活化对提高红辉沸石去除氨氮效率的作用不明显。（3）酸和碱改性对提高红辉沸石去除氨氮的效率有一定的作用,其中盐酸改性的红辉沸石去除氨氮效率为16.2%,硫酸改性的红辉沸石去除氨氮效率为13.1%,碱改性的红辉沸石去除氨氮效率为25.6%。（4）盐改性对红辉沸石去除水溶液中氨氮的影响效果巨大：经盐改性后,去除率由9.6%升高至72.6%。     

非点源污染研究中土壤溶解性无机氮的提取方法选择

用2M KCl溶液(5:1)、饱和CaSO4溶液(5:1)、0.01M CaCl₂溶液(20:1,100:1) 和去离子水(20:1,100:1)4种提取液、6种提取方式,采用Auto-analyzerⅢColorimeter (Bran Luebbe),水杨酸-次氯酸盐法和Griess-Ilosvay法测定并对比了北京地区4种天然土样的溶解性氨氮和硝态氮的含量。研究结果表明:溶解性硝态氮的测定结果不受提取液和水土比(小于100:1)的影响,而溶解性氨氮测定结果受影响较大。在非点源污染研究中,对于土壤中可向水体迁移的溶解性无机氮含量的测定,应根据来水水源特征和研究目的选择适宜的浸提剂和水土比。     

准动态箱法测定农田NH3挥发初探

提出了能够原位测定农田土壤-植物体系NH3排放的准动态箱法,并开展了一系列实验对其进行评估。该方法的回收率为89.0%±4.9%,与风洞法一致;对农田裸地施肥后的NH3挥发测定结果与有限流通密闭室法具有显著一致性(r<0.05);休闲裸地1日内的NH3挥发与气温呈显著指数相关(r<0.05)。根据NH3挥发的日变化和逐日动态规律,准动态箱法测定农田日NH3挥发的最佳时间为9时(北京时间,下同)左右或16时左右,对单次施肥引起的NH3挥发最佳观测周期为施肥后1～2星期。且实验表明,山西冬小麦拔节期追施(撒施)尿素后,采用准动态箱法测定的NH3挥发N损失率为3%～5%。     

云南老王寨金矿煌斑岩固定铵（NH4^＋）地球化学特征

云南老王寨金矿与金矿化时空密切共生的煌斑岩可分为新鲜（弱蚀变）、蚀变和矿化3种。固定铵（NH4^ ）含量测定结果表明，新鲜煌斑岩固定铵含量明显高于其他幔源岩石、低于矿区碳质围岩的固定铵含量。笔者认为该特征可能不是地壳混染的结果，从新鲜煌斑岩→蚀变煌斑岩→矿化煌斑岩，固定铵含量递增，且与金含量具较好的正相关，表明矿区煌斑岩蚀变流体和矿化流体中均可能存在铵，铵在金矿化流体中对金的迁移起了作用。     

(NH_4)_2SO_4浸取EDTA-Zn测定试样中RE_2O_3

稀土元素的分析主要采用有机试剂萃取。偶氮试剂做为显色剂的比色分析,分析手续繁琐,也不易得到满意的分析结果,本文在EDTA容量法的基础上,采用较为简便的(NH4)2SO4浸取EDTA-Zn滴定法直接测定新型稀土总量,大大简化了试样的分析过程和操作手续。     

Characterization of NH4-phlogopite (NH4) (Mg3) [AlSi3O10] (OH)2 and ND4-phlogopite (ND4) (Mg3) [AlSi3O10] (OD)2 using IR spectroscopy and Rietveld refinement of XRD spectra

 A synthesis technique is described which results in >99% pure NH₄-phlogopite (NH₄) (Mg₃) [AlSi₃O₁₀] (OH)₂ and its deuterium analogue ND₄-phlogopite (ND₄) (Mg₃) [AlSi₃O₁₀] (OD)₂. Both phases are characterised using both IR spectroscopy at 298 and 77 K as well as Rietveld refinement of their X-ray powder diffraction pattern. Both NH₄ ⁺ and ND₄ ⁺ are found to occupy the interlayer site in the phlogopite structure. Absorption bands in the IR caused by either NH₄ ⁺ or ND₄ ⁺ can be explained to a good approximation using T_d symmetry as a basis. Rietveld refinement indicates that either phlogopite synthesis contains several mica polytypes. The principle polytype is the one-layer monoclinic polytype (1M), which possesses the space group symmetry C2/m. The next most common polytype is the two-layer polytype (2M ₁ ) with space group symmetry C2/c. Minor amounts of the trigonal polytype 3T with the space group symmetry P3₁12 were found only in the synthesis run for the ND₄-phlogopite. Electron microprobe analyses indicate that NH₄-phlogopite deviates from the ideal phlogopite composition with respect to variable Si/Al and Mg/Al on both the tetrahedral and octahedral sites, respectively, due to the Tschermaks substitution ^VIMg²⁺+^IVSi⁴⁺↔^VIAl³⁺+^IVAl³⁺ and with respect to vacancies on the interlayer site due to the exchange vector ^XII(NH₄)⁺+^IVAl³⁺↔^XII□+^IVSi⁴⁺. Received: 30 August 1999 / Accepted: 2 October 2000