Laboratory kinetics of C2H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.     

对青藏东北缘现今块体划分、运动及变形的初步研究

利用2维非连续变形分析方法（DDA），以位移代替围压作为边界约束力，研究青藏东北缘现今块体划分及其运动变形。根据该地区地质构造及地震活动，以GPS点测量位移作为模拟结果约束点，得出了较合理的块体划分模型和随时间演化的主应变分布图，并把应变高值区与近几年来发生的5级以上地震作对比，得出了研究区内地震危险性可能较大的区域。另外，对模拟的甘青块体与阿拉善块体的边缘带断裂左旋运动做了大概计算。     

抽油机悬点投影测量仪

油田抽油机的抽油杆幌动幅度过大，是引起抽油杆断裂的一个重要因素，检测这种幌动幅度是防止抽油杆断裂的一种有效手段。设计了一种基于面阵CCD和普通半导体激光器（LD）测量这种幌动的悬点投影测量方法，通过数字卷积滤波，达到了范围为0－40mm，误差＜0.2mm的技术检测指标。     

初轨计算中的病态分析

本文对现有初轨计算方法进行病态性分析与误差分析；研究结果表明：病态对现有初轨算法的影响，主要来源于法方程系数中包含观测误差．系数行列式愈大，定轨精度的损失愈多，当■被随机误差项△μ淹盖时，现有初轨算法将失效．此外，仿真结果还显示：■与△μ的大小还极大地依赖观测弧段的空间位置，当观测弧段包含近站点作为中点时，■最大，而■小，此时定轨精度较高；当观测弧段位于近站点的某一侧时，■小，而■大，此时定轨精度较低，观测弧段愈偏离近站点，病态影响愈大；因而在观测时，应尽量使观测弧段与近站点对称（此时μ值较大），这是提高短弧定轨的一种有效途径．     

Canonical theory of perturbations using eccentric anomaly as independent variable

It is shown in this paper how to build a canonical transformation of variables, so that the eccentric anomaly becomes the new independent variable. In the case of eccentric elliptical orbits it changes the equations of motion so, that they can be integrated analytically to any order of approximation comparatively easy.