Seasonal variations in the origin of lead in snow at Dye 3, Greenland

The isotopic composition and concentration of lead has been measured in fresh and slightly aged snow collected at Dye 3 in southern Greenland during one full year. The lead concentration displayed large variations ranging from 14–3016 pg/g in April (spring) to 3–6 pg/g in September (summer) while the isotopic ratios changed in regular manner during the year. The ²⁰⁶Pb/²⁰⁷Pb ratios were 1.15 from spring to mid-summer snow, and increased in late summer to early autumn, reaching 1.20 in winter. These isotopic data indicate that the lead in the autumn to winter snow originated in North America, while that in spring to mid-summer snow is from Eurasia.     

A new approach to the Nd residence time in the ocean: the role of atmospheric inputs

Concentrations of rare earth elements (REE) and Nd isotopic ratios were analyzed for seawater, filtered suspension and sediment trap samples collected in the tropical Atlantic Ocean (EUMELI program, EUtrophic, MEsotrophic and oLIgotrophic sites, 20°N, 18°–21°W). This is the first REE/Nd dataset on solution and different-sized particles collected at the same site. We present direct evidence of the Nd isotopic exchange between particulate lithogenic fraction and seawater without significant mass transfer. This exchange is probably one of the main factors that simultaneously constrains the Nd concentration and isotopic ratio budget. We propose a new approach to estimate the residence time of Nd in the ocean (τ_Nd) based on isotopic exchange: 200 yr < τ_Nd< 1000 yr. The exchange requires a partial dissolution of lithogenic Nd. We estimate that the fraction of soluble Nd proportion in atmospheric dust is of the order of 20% based on the isotopic ratios. We suggest that the partial dissolution of atmospheric fallout is probably one of the main REE sources of the ocean.     

Characteristics of metals in atmosphere over the western Taiwan Strait Ⅱ. Sources and fluxes

I~IOWDuceetal.(1980)calculatedthattheair-seaexchangeprocesscouldsupply80%--90%ofthediforedironinputtothephotcrzoneoftheSargassoAsfromairand16%--76%tothecentralNorthPacific.CuisessentialtotheTnarineorganisms,butexcessiveCuistoxictOtheOrganisms.CdandPh...     

A review of diagnostic emission line ratios in the Narrow Line Region of Active Galactic Nuclei

The availability of new observing facilities both from ground and space such as the Keck 10m telescope and the Hubble Space Telescope is casting new light on the spectroscopic investigation of emission line galaxies. In particular, it is now possible to detect spectra with a significantly improved signal to noise ratio in a very wide wavelength range, from the ultraviolet to the near infrared (HST, Keck) and beyond (ISO is unveiling the far infrared domain). As we move to high redshifts, however, it is more likely that the observed spectra are given by the contribution of different components in the galaxy: in particular, this may be the case if an Active Galactic Nucleus (AGN hereafter) emitting a power-law continuum is surrounded by regions with strong star formation activity. The identification of the source which ionizes the line emitting regions is then complicated by the fact that we are observing the integrated spectrum from regions which are ionized by different sources. In this paper we wish to review which line ratios may be used in order to discriminate between photoionization by young stars and power-law continuum in the wavelength range from 1200 Å to 100 μm. To this aim we used the photoionization code Cloudy (Ferland 1996) to present a series of diagnostic diagrams showing the dependence of emission line ratios on the main input parameters of photoionization models in the case of one component models with gaseous clouds ionized by (1) a stellar continuum typical of an HII region and (2) a power-law continuum typical of an AGN: these line ratios are plotted as isoratio maps for different values of the hydrogen density, ionization parameter and slope of the power-law continuum. We then show how the results may be affected by more realistic assumptions about the environment of the ionized gas: to this aim, we show the effects on selected line ratios of (a) the presence of two populations of clouds with different densities and (b) an AGN surrounded by regions with strong star formation activity.     

The influence of light intensity,SO2, NOx and C3H6 on sulfate aerosol formation

The photochemical oxidation of SO₂ in the presence of NO and C₃H₆ was studied in a 18.2 liter pyrex reactor. When light intensity, irradiation time and SO₂ concentration were constant, SO₄ ^2- concentration, derived from the total volume of aerosol produced, peaked when [C₃H₆]/[NO] was approximately 6.0. Another increase im SO₄ ^2- formation was reached at very high ratios (>50). The experimental observations are consistent with the two SO₂ oxidation mechanisms. At low [C₃H₆]/[NO] ratios, the processes proceed via the HO–SO₂ reaction, while at high ratios the O₃–C₃H₆ adduct is assumed to oxidize SO₂ to produce SO₄ ^2- aerosols.     

地震作用下横断层地质金属成矿带电法找矿成果研究

深部矿产资源勘探是未来勘探的必然趋势.地震作用下的横断层地质构造对金属矿、 能源矿等矿产资源的分布具有重要影响,拥有较大的找矿潜力.对于地震作用下横断层地质等条件复杂的场合,采用高密度电阻率法、 激发极化法和可控源音频大地电磁法等单一电法勘探可能存在找矿效果不佳的问题,有必要研究更为有效的找矿技术方法.首先阐述了激发极化法、CSAMT法等电法勘探的基本内容和各自优缺点;然后,在分析地震作用下横断层地质特征的基础上,研究并提出了基于激发极化法和CSAMT的综合找矿法.基于激发极化法和CSAMT的综合找矿法能有效反映地下地电差异,在大深度范围有效反应地电断面电阻、 极化率参数,互相校正验证;结合已有地质物探资料,推断地下异常,提高横断层的金属矿产勘探效率和效果.将本文的研究成果应用于某横断层地质区域的金属矿勘探实践,取得了良好的勘探效果.实践表明本文所提方法有效、 可行.     

高氮磷比与酸化共同作用对微小亚历山大藻生长和产毒的影响

通过实验室构建不同氮磷比条件下的酸化海水环境,培养麻痹性贝毒(paralytic shellfish toxin,PST)产毒藻微小亚历山大藻(Alexandrium minutum),采用藻细胞计数法、分光光度法、高效液相色谱-质谱法等分析方法,探讨了不同氮磷比条件下的酸化海水对微小亚历山大藻的生长、氮磷营养盐吸收、产毒等参数的影响。结果表明,在一定程度上,酸化环境对A.minutum的生长、PST的胞内累积和胞外释放有促进作用,且胞外培养液中PST含量增加的程度更高;同时,酸化海水促进胞内毒性较低的N-H类膝沟藻毒素(GTX2和GTX3)被氧化成毒性较高的N-OH类膝沟藻毒素(GTX1和GTX4),导致A.minutum的细胞毒性和培养液毒性增加。而海水中氮磷比的进一步升高,在一定程度上促进了微小亚历山大藻细胞毒素含量和毒性的增加,但并未促进其生长,且降低了藻细胞内的磷储量。     

Isolation of plane shear wave using water saturated trench barrier

The article presents a theoretical investigation of the propagation of normally and obliquely incident plane shear waves past a rectangular trench filled up with water saturated soil sandwiched between anisotropic elastic media. The motivation for this work is due to the effectiveness of the isolation of waves by the in-filled rectangular trench. Unlike the most of the previous researchers, this model considers the soil–structure interaction effects and directly determines the influence of barrier in the form of in-filled trench on the mode of wave propagation. It is of interest to determine the reflection and transmission coefficients, and the energy partition distribution of shear waves in the in-filled rectangular trench showing the influence of barrier on the propagation of waves. An extensive parametric study through numerical computation is carried out to investigate the influence of the material properties of the in-filled trench and the amplitude ratios on shear waves. The in-filled trench barrier directly declines the intensity of waves significantly in such a way that the waves do not create any hazards to the nearby structures, if exists at all.