Depth dependency of stress ratios during the sedimentation of NW Gyeongsang Basin (Cretaceous), southeast Korea: Estimate of stress parameters and timing of tectonic episodes

The natural stress state in the lithosphere consists of the vertical load and Poisson ratio, and then additional horizontal compression and extension (denoted by Δσ_H and Δσ_T, respectively) are assumed to be superimposed upon this gravitational stress field. The resulting stress state is composed of the maximum, medium and minimum stresses denoted by σ₁, σ₂, and σ₃, respectively. The stress ratio is given as Φ = (σ₂ − σ₃)/(σ₁ − σ₃). A linear relation is found between Φ or 1/Φ and the vertical load in wrench-faulting and extensional stress regimes, respectively. The slope and intercept of the linear relation result in the additional horizontal stresses and level of (average) paleo-surface, respectively. Stress ratio is also determinable by the stress tensor inversion of fault-slip data. The earliest tectonic event (T_1 Event) in the Cretaceous Gyeongsang Basin consists of coexisting E–W compression and N–S extensional faulting episodes. Plots of Φ or 1/Φ against the burial depth (or vertical load) display several linear trends: two clusters in extensional episodes, and two or three clusters in wrench-faulting episodes. Because Δσ_H is assumed to be null or negligible in the extensional regime, Δσ_T is determinable from the slopes of two linear clusters as being −2.5 to −4.0 MPa. In wrench-faulting episodes, the values of Δσ_H are given to be 61.6–101.4 MPa by applying determined additional horizontal extensions. Determined levels of average paleo-surfaces and those of syndepostional structures illustrate that more than five wrench-faulting or extensional episodes have occurred during the T_1 Event, whose active age, consequently, ranges from the Barremian to the Coniacian. This supports that the coexisting coaxial faulting episodes with the same extension may correspond to the alternation of wrench-faulting and extensional episodes.     

The application of lead isotope ratios in the Antarctic macroalga Iridaea cordata as a contaminant monitoring tool

Lead (Pb) isotope ratios were measured in the marine macroalga Iridaea cordata collected from four locations in the Windmill Islands, East Antarctica. Based on the masses of thalli collected, samples analysed in this study were likely to be a mixture of one and two year old thalli. For a sample of thalli of various ages (<12 months to 2 years old) from the same site there was no apparent variation in Pb concentration or Pb isotope ratio with thallus mass/age, indicating that contaminant sources had been constant over the lifetime of the thalli sampled. I.cordata samples close to the Thala Valley waste disposal site (Brown Bay Inner) near the Australian Station, Casey, displayed isotopic signatures (²⁰⁸Pb/²⁰⁴Pb 35.99; ²⁰⁶Pb/²⁰⁷Pb 1.066; n = 3; average values shown) trending towards that possessed by major Australian Pb sources (Broken Hill and Mt Isa, ²⁰⁸Pb/²⁰⁴Pb 35.60; ²⁰⁶Pb/²⁰⁷Pb 1.041) suggesting that these samples had been exposed to anthropogenic Pb originating from the Thala Valley waste disposal site. Material collected hundreds of metres from the tip location at Brown Bay Outer had isotopic values (²⁰⁸Pb/²⁰⁴Pb 36.32; ²⁰⁶Pb/²⁰⁷Pb 1.088; n = 10) intermediate between Brown Bay Inner and sites further from the contaminant source at Sparkes Bay and Wilkes (²⁰⁸Pb/²⁰⁴Pb 36.46; ²⁰⁶Pb/²⁰⁷Pb 1.094; n = 4) showing that contaminant transport was predominantly restricted to Brown Bay Inner. This study demonstrates that the isotope ratios of Pb in marine macroalgae can provide valuable information as to the origin and extent of heavy metal flux in a marine environment.     

Removal of Copper,Nickel and Zinc Ions from Aqueous Solution by Chitosan‐8‐Hydroxyquinoline Beads

In this work, 8‐hydroxyquinoline is used as the active sites in cross‐linked chitosan beads with epichlorohydrin (CT‐8HQ). The CT‐8HQ material was shaped in bead form and used for heavy metal removal from aqueous solution. The study was carried out at pH 5.0 with both batch and column methods and the maximum adsorption capacity of metal ions by the CT‐8HQ was attained in 4 h in the batch experiment. The adsorption capacity order was: Cu²⁺ > Ni²⁺ > Zn²⁺ for both mono‐ and multi‐component systems with batch conditions. From breakthrough curves with column conditions, the adsorption capacity followed the order Cu²⁺ > Zn²⁺ > Ni²⁺ for both mono‐ and multi‐component systems. The CT‐8HQ beads maintained good metal adsorption capacity for all five cycles with absorbent restoration achieved with the use of 1.0 mol L^–1 HCl solution, with 90% regeneration.     

Broadband frequency-dependent amplification of seismic waves across Bucharest, Romania

The determination of seismic amplitude amplification is a fundamental contribution to seismic hazard assessment. While often only high-frequency amplitude variations (>1 Hz) are taken into account, we analyse broadband waveforms from 0.14 to 8.6 Hz using a temporary network of 32 stations in and around the earthquake-prone city of Bucharest. Spectral amplitudes are calculated with an adaptive multiple-taper approach. Across our network (aperture 25 km × 25 km), we find a systematic northwest/southeast-oriented structural influence on teleseismic P-wave amplitudes from 0.14 to 0.86 Hz that can be explained by constructive interference in the dipping Cenozoic sedimentary layers. For higher frequencies (1.4–8.75 Hz), more local site effects prevail and can be correlated partly among neighbouring stations. The transition between systematic and localised amplitude variations occurs at about 1 Hz.     

半干旱区沼泽沉积剖面特征元素比值及其物源、氧化还原变化信息

沼泽发育过程中堆积的各类沉积物真实地记录了区域环境演变与沼泽发育过程。以霍林河下游漫流区--向海沼泽湿地为研究对象,由¹³⁷Cs、²¹⁰Pb法定年实现沉积层深度坐标向年代坐标的转换,对其典型沉积剖面特征元素比值进行了综合剖析。结果表明：稳定元素对比值Ti/Al是判断不同沉积物来源是否一致的较好指标。剖面上下Ti/Al比值在一定层序的波动变化表明物源的波动性,洪水成因可能性较大。综合比较,V/(V+Ni)比值用于沼泽湿地缺氧沉积环境的判别标准可靠性较好。贫氧环境是向海沼泽湿地主要特征之一,其次是缺氧或含氧环境,各环境之间频繁振荡,体现了内流河下游半干旱区沼泽地表水周期和干湿环境转换频繁的特征。     

Assessment of generation temperatures of crude oils

Biological marker maturity parameters were used to estimate the minimum HC generation temperatures of crude oils from Eastern Hungary. More than 50 oils and oil shows were analysed. Molecular- and homologous-ratios of biological marker compounds (triterpanes, steranes, mono- and triaromatic steroid hydrocarbons) were used as maturation parameters. The oils have at least five maturity stages, i.e. they have been generated under different thermal conditions. The highest reservoir temperature in each group was chosen as the best estimate of the groups' temperature just below the generation temperature, i.e. reservoirs of the group might be expected to be at shallower depths (lower temperatures) than those of the generation zone due to vertical migration into pools. For each maturation level, a threshold temperature range for genesis was inferred from reservoir temperatures; they are from 130–135°C for the least mature oils to 210–215°C for the most mature oils. In the least mature oils cracking was not observed, hence carbon–carbon cracking reactions had not taken place during their genesis. The most mature oils are intensively cracked oils; they are almost condensates. Two major genetic groups (families) of oils were found in the area. Both are present in each maturation level. The effects of migration were checked, and no influence on maturation was found. A number of the oils are in overpressured reservoirs within, or just above, the zone of the present-day active oil generation, hence the present-day temperatures of the pools must have been maximum temperatures. Contrary to the traditionally accepted temperature range for petroleum generation–maturation reactions (50–150°C), there is strong evidence from this study that the onset of oil generation requires temperatures higher than 130°C and is still proceeding above 215°C.     

Error propagation in equations for geochemical modeling of radiogenic isotopes in two-component mixing

This paper presents error propagation equations for modeling of radiogenic isotopes during mixing of two components or end-members. These equations can be used to estimate errors on an isotopic ratio in the mixture of two components, as a function of the analytical errors or the total errors of geological field sampling and analytical errors. Two typical cases (“Small errors” and “Large errors”) are illustrated for mixing of Sr isotopes. Similar examples can be formulated for the other radiogenic isotopic ratios. Actual isotopic data for sediment and basalt samples from the Cocos plate are also included to further illustrate the use of these equations. The isotopic compositions of the predicted mixtures can be used to constrain the origin of magmas in the central part of the Mexican Volcanic Belt. These examples show the need of high quality experimental data for them to be useful in geochemical modeling of magmatic processes.     

A time-domain viscous damping model based on frequency-dependent damping ratios

This paper introduces the mathematics and procedures used in developing a time-dependent damping model for integration analyses of structural response. To establish the time-dependent viscous damping model, frequency-dependent damping ratios of the structure under a series of steady-state unit impulses corresponding to actual loads are first calculated. For simplicity, the ratios can be incorporated with the static stiffness of the structure to model approximately the impulse induced damping spectrum. According to the nature of the problem, these ratios can be calculated from the theoretical impedance functions and experimental observations. With the computed damping spectrum, the damping coefficient in the time domain can be obtained with the Fourier transform technique. Adopting the impulse–response method, the damping can be modeled rationally through integration with changing loads. Numerical examples are presented to show the feasibility of this model while the transform criterion is satisfied.     

Rb and Sr Geochemical Characterization of the Chinese Loess Stratigraphy and Its Implications for Palaeomonsoon Climate

Concentrations and distributions of Rb and Sr in loess and palaeosol samples from the Luochuan profile have been studied, in grain-size fractions and chemical forms. Results show that Rb is quite rich in the fraction of less than 2μm, and exits only in the residual phase, while Sr is distributed in sand and silt fractions, occurring in the residual and carbonate phases. Therefore, variations of the concentrations of Rb and Sr in loess and palaeosols are closely related not only to dustfall compositions depending on winter monsoon wind strength but also to summer monsoon-induced pedogenic intensity. This indicates that variations of Rb/Sr ratio in Chinese loess sequences represent cyclic alternations of East Asian summer and winter monsoon climates on the orbital time-scale. Variations in Sr concentrations along the sequence bear a high similarity to the oxygen isotope record of the deep sea sediments over the past 2.5 Ma, whereas variations in Rb concentrations are in good agreement with the record of     

论矿山经济技术指标对企业效益的影响

从矿山生产经营的主要指标分析入手,建立以效益为目标函数的经济分析模型,全面进行矿产经济评价,探讨生产成本、出矿品位、贫化率、矿石产量等对矿山经营效果的影响,从而找出影响矿山经济效益的主要因素,进行指导矿山生产。