深埋顶管顶力理论计算与实测分析

针对管幕预筑法中深埋顶管顶力进行理论和实测分析。顶管顶力与垂直土压力密切相关。参照隧道开挖中垂直土压力的计算方法,常用的垂直土压力计算理论有：普氏理论和太沙基理论。在详细分析了这两种垂直土压力计算理论的适用性和缺陷之后,结合普氏理论和太沙基理论,提出了改进的垂直土压力计算理论公式,并编写MATLAB程序计算改进理论公式的数值解。改进理论既考虑了土拱效应,又考虑了拱下土体的挟持力,更符合实际土体变形情况。将普氏理论、太沙基理论和改进的理论应用于沈阳地铁新乐遗址站管幕预筑法顶管工程中,计算不同深度的两根大埋深管道顶力,并把计算与实测结果进行比较,发现普氏理论和太沙基理论计算结果都远大于实测值,改进理论计算结果稍大于实测值,更适合于深埋顶管顶力估算。     

新疆巴音沟蛇绿混杂岩带中硅质岩及硅质泥岩的元素地球化学特征及其形成环境

巴音沟蛇绿混杂岩带中成薄层状产出的硅质岩、硅质泥岩的Si02：55．37％～91．19％,Al2O3含量较高,变化在3．07～17．66,TiO2=0．12～0．8,Al2O3与TiO2具有较好的正相关关系,表明它们含有较高比例的陆源泥质沉积物质。样品经北美页岩标准化的稀土模式呈现无Ce负异常（Ce／Ce^＊=1．03～1．45）的平坦稀土谱型,球粒陨石标准化稀土模式为轻稀土富集,Eu具明显负异常的右倾谱型。均显示与大陆边缘沉积硅质岩、硅质泥岩相似的稀土配分模式。它们的（La／Ce）N=0．62～0．92,V／Y=0．32～8．87,Th／U=2．99～6．45,表明这些硅质岩、硅质泥岩形成于与陆源物质输入密切相关的大陆边缘环境,综合大地构造背景、蛇绿岩带中超基性、基性岩元素地球化学以及年代学分析认为,蛇绿岩就位于早石炭世晚期,形成在大陆裂谷向大洋裂谷转换并形成小洋盆的环境。     

陕北奥陶纪盐盆马五6时期东、西部盐坳沉积环境对比研究

陕北奥陶纪盐盆位于鄂尔多斯盆地伊陕斜坡东部。研究表明:马五6亚期,盐盆存在"两坳一隆"的构造格局,即东、西部盐坳和中部隆起,东、西部盐坳在钾矿化情况、溴氯系数反映的水体咸化趋势方面初步显示了陕北盐盆东、西部沉积环境的差异。本文通过东、西部盐坳典型钻井马五6层位沉积学分析,揭示了马五6时期东、西部盐坳在水体深度变化、浓缩趋势、含钾量、淡化层段厚度、陆源物质输入方面均存在差异。其中,西部盐坳受海水影响大,水体变浅且持续淡化,泥质分布反映陆源物质贡献少,对钾盐的沉积与保存均十分不利。而东部盐坳受海水影响小,与西部盐坳水体联通性差,在马五6时期环境更为封闭,具体表现为淡化夹层分布数量少、厚度薄的特征;水体持续变深并浓缩咸化;泥质夹层较多,反映了相较于西部,陆源物质对其影响更大,上述特点为钾盐沉积提供了有利的地球化学条件及可容空间。东、西部盐坳沉积环境对比表明东部盐坳对成钾更为有利。     

频率测探正演滤波算法及算例

通过对频率测深理论的研究，提出了水平电偶极场视电阻率改进滤波算法，并编制了正演计算的实用程序。理论模型计算表明，改进滤波算法 效果好，计算速度快。     

碲的泡塑预分离M17树脂富集原子荧光测定法

采用王水溶样，泡沫塑料预分离金等干扰组分，以Ｍ１７树脂富集Ｔｅ并使之与大部分共存的干扰元素分离，建立了原子荧光含金地质样品中碲的方法，用地矿部标准参考样品和含金地质试样分析考察，结果满意。方法检测下限为０．００９×１０＾－６。     

High temperature dehydroxylation of muscovite-2M1: a kinetic study by in situ XRPD

Muscovite-2M₁ shows a major phase transition at about 800°C, which is generally attributed in the literature to the structural dehydroxylation process, although a number of structural models have been proposed for the dehydroxylated phase, and different transformation mechanisms have also been put forward. The observed first order transformation involves an increase in the cell volume, and it is not clear to date how the cell expansion is related to the loss of hydroxyl groups. The phase change has been re-investigated here by in situ high temperature powder diffraction, both in non-isothermal and isothermal modes, to combine for the first time the structural and the kinetic interpretation of the transformation. The results unequivocally confirm that the reaction taking place in the temperature range 700–1000°C is truly a dehydroxylation process, involving the nucleation and growth of the high temperature dehydroxylated phase, having Al in 5-fold coordination. Structural simulations of the basal peaks of the powder diffraction patterns indicate that the model originally proposed by Udagawa et al. (1974) for the dehydroxylated phase correctly describes the high temperature phase. The kinetic analysis of the isothermal data using an Avrami-type model yields values for the reaction order compatible with a reaction mechanism limited by a monodimensional diffusion step. Apparent activation energy of the process in vacuum is about 251 kJ/mol. Experiments carried out at temperatures much higher than the onset temperature of the reaction show that the dehydroxylation reaction overlaps with the reaction of formation of mullite, the final product in the reaction pathway. Received: 24 April 1998 / Revised, accepted: 12 October 1998     

57Fe Mössbauer spectroscopy of tektites

Tektite glasses are investigated using ⁵⁷Fe Mössbauer spectroscopy. Room temperature spectra analysis is performed using two complementary analytical methods based on two-dimensional distributions of both isomer shift and quadrupole splitting. No a priori correlation between the two hyperfine parameters is considered. The first method, based on a shape independent distribution, provides the justification for the Gaussian distribution shape used in the second method. No ferric iron contribution is evidenced by Mössbauer spectra analysis in these samples, although several criteria are used. Ferrous iron sites are shown to be continuously distributed between four- and five-fold co-ordinated sites.     

Analysis of DNAPL infiltration in a medium with a low-permeable lens

In this paper we study the infiltration of DNAPL in a porous medium containing a single low-permeable lens. Our aim is to determine whether or not DNAPL infiltrates into the lens. A key role is played by the capillary pressure: DNAPL cannot infiltrate into the lens unless the capillary pressure exceeds the entry pressure of the lens. In the model this is reflected by an interface condition, the extended capillary pressure condition. To derive analytical approximations we first consider a steady-state DNAPL plume in a homogeneous medium. This results in an estimate of the DNAPL plume width as a function of depth, and an asymptotic solution for small saturations. Assuming that the extent of the lens is much larger than the width of the unperturbed DNAPL plume in the homogeneous medium, we derive an explicit criterion for DNAPL infiltration into the lens in terms of a critical inflow rate. A numerical algorithm is presented in which the extended capillary pressure condition is incorporated. The numerical and analytical results show good qualitative agreement. This revised version was published online in August 2006 with corrections to the Cover Date.     

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.     

Characterization of a chalcopyrite from Brazil by Mössbauer spectroscopy and other physicochemical techniques

We studied a chalcopyrite from a Cu ore deposit in Rio Grande do Sul, Brazil, by Mössbauer spectroscopy at room temperature and 110 K. Supporting methods to check for sample purity and to characterize further sample properties were slow-scanning X-ray powder diffraction and optical and microprobe analyses of polished sections of selected grains. Chemical analyses obtained using a scanning electron microscope equipped with an energy-dispersive X-ray spectrometer showed the sample to consist of homogeneous and essentially stoichiometric chalcopyrite (CuFeS₂). Mössbauer spectra taken at both the above temperatures consist of asymmetric magnetically ordered patterns with unequal intensities of the line pairs 1–6 and 2–5, pointing to the existence of non-equivalent or multiple Fe sites. Least-squares fittings evidenced that the resonance intensity ratio of subspectrum with lower quadrupole shift (indicative of a more symmetric environment) to that with higher shift is 69:31, at room temperature, and 68:32, at 110 K. Rietveld refinement of the XRD data indicates the existence of tetragonal [a = 0.52855(1) and c = 1.0412(1) nm] and cubic [a ₀ = 0.5273(2) nm] modifications in a proportion of 74:26, in good agreement with the Mössbauer data. The saturation magnetization of the sample was 32.7 J/(T kg), confirming the oxidation state of Fe as trivalent and pointing to little to no spin canting.