库车坳陷克拉2气田异常流体压力演化史

根据克拉2气田现今实测地层压力分析了异常高压发育的特征,并通过流体包裹体测试求取包裹体形成时期的古压力。计算结果表明:下白垩统和古近系库姆格列木群砂岩储层在距今8～6Ma(康村组沉积期末)时,古压力系数大致为1.09～1.18,发育过剩压力为4.6～9.6MPa的异常高压。在此基础上,以古、今压力数据为约束条件,利用数值模拟技术定量恢复出下白垩统与侏罗系异常流体压力的演化历史。研究发现:下白垩统储层流体压力经历了沉积型异常流体压力形成发展(白垩纪-库车组沉积期末)和沉积型异常流体压力萎缩—构造挤压型异常流体压力孕育(库车组沉积期末至今)两个阶段。康村组沉积早期沉积型超压开始出现,库车组沉积期末达到顶峰,过剩压力达40～50MPa;此后,在沉积型超压萎缩—构造挤压型超压孕育过程的耦合下,过剩压力曾降至25～30MPa,更新世起超压略有升高。侏罗系流体压力演化较为简单,吉迪克组沉积期开始出现超压,至库车组沉积期末达到高峰,此后异常高压逐渐萎缩。在克拉2气田的主要成藏时期(距今3～1Ma),烃源岩较储层具有更高的异常压力,源—储压力差为10～30MPa。     

济阳坳陷奥陶系碳酸盐岩及缝洞充填方解石C、O同位素特征及其意义

对济阳坳陷奥陶系碳酸盐原岩及孔洞缝中充填方解石进行了C、O同位素测定,结果表明孔洞缝充填方解石的δ¹³C和δ¹⁸O值比原岩偏负。奥陶系三山子组和马家沟组孔缝中充填的方解石C、O同位素演化有很大区别,前者的δ¹³C和δ¹⁸O值均为负值,δ¹³C向较高负值偏移,δ¹⁸O值向较低负值偏移;马家沟组八陡段孔缝充填方解石的δ¹³C和δ¹⁸O值也多为负值,δ¹³C向较正值方向偏移,δ¹⁸O值向较高负值偏移。奥陶系碳酸盐岩孔缝充填方解石形成于大气淡水环境和埋藏成岩环境,次生孔洞可能主要形成于早期表生阶段,裂缝形成于中-新生代的构造运动,方解石主要充填于埋藏环境中。次生孔缝的主要形成时期早于油气大量运移期,对古潜山油藏的形成有利。     

铵(氮)在岩石和矿物中地球化学行为研究进展

地壳中的氮大都以NH4 储存在矿物中.由于成岩时含氮有机物质的分解作用,氮广泛分布在沉积岩和低级变质岩中;在岩浆岩和变质岩中,氮主要以NH4 存在于含钾硅酸盐(长石和云母类)中;岩浆岩的δ(15N)值和氮浓度明显地不同于沉积物和变沉积岩,主要是由于有机物的缺乏.具有明显铵含量的火成岩主要是含钾矿物的深成岩.因而NH4 可以作为一个"示踪元素"而用于成矿作用等方面的研究.文章还提出了未来的研究方向.     

Quantitative Analysis of Paleoatmospheric CO2 Level Based on Stomatal Characters of Fossil Ginkgo from Jurassic to Cretaceous in China

A better theoretical and practical understanding of the linkage between paleo-CO2 and climate during geological history is important to enhance the sustainable development of modern human society. Development in plant physiology since the 1980s has led to the realization that fossil plants can serve as a proxy for paleoatmosphere and paleobiosphere. As a relict gymnosperm with evolutionary stasis, Ginkgo is well suited for paleoenvironmental reconstruction. This paper analyzes fossil Ginkgo species from integrated strata in the north of China using anatomic data of plant physiology. Using stomatal parameters, a trend for the paleo-CO2 level during the Early-Middle Jurassic and the Early Cretaceous was obtained, which is consistent with the estimates by GEOCARB. The trend is also similar to that of Mean Global Surface Temperature in geological time. Compared with three other atmospheric CO2 concentration parameters, the trend of paleo-CO2 level based on the stomatal parameter of the fossil Ginkgo specimens from three contiguous strata is more exact.     

海岸水边线提取方法在GF-2卫星影像中的适应性研究

准确提取海岸水边线是海岸线变迁研究中必不可少的基本工作。本文以海南省陵水黎族自治县2016年的GF-2影像为数据源,在大气校正和正射校正等预处理的基础上,结合数学形态学处理等方法,采用NDWI (Normalized Difference Water Index)阈值法、ISOADTA (Iterative Self-Organizing Data Analysis Technique Algorithm)、SVM (Support Vector Machine)和面向对象法（Object-Oriented Classification,OOC）等4种不同方法来对海岸水边线进行提取,并对其提取结果进行定性和定量评估,进而分析比较了这4种方法在提取人工海岸、砂质海岸和基岩海岸等3种不同海岸类型的水边线时的提取效果和提取精度。结果表明,SVM方法在3种海岸水边线上的总体提取效果最好,总体提取精度最高。     

中国海洋生态效率时空格局演变及影响要素分析

随着海洋环境问题的日益凸显,海洋经济与海洋生态保护如何协调发展已成为学术界的研究热点。本文使用C2NLS方法对2003-2016年中国沿海11个省区市海洋生态效率进行测度,使用SDE方法对海洋生态效率的时空演进特征进行分析,最后对影响海洋生态效率的因素进行实证探索。结果表明：(1)海洋生态效率整体呈上升趋势,但地区差距并未显著缩小,海洋生态效率的地区分布出现极化趋势。(2)海洋生态效率重心表现出西南向移动特征,东北-西南向的空间格局更加明显。(3)环境规制、海洋科技和对外开放可以有效提高海洋生态效率水平;产业结构效应不显著,可能是由于高污染行业同时具有高产出与高排放的特征导致;区位因素效应不显著,海洋生态效率与地区发展水平之间没有明显的二次型关系,与中国海洋经济整体发展仍处于“倒U”型曲线的上升通道情况相符,部分印证了“环境的库兹涅茨”曲线理论。     

Microbial photosynthesis in coral reef sediments (Heron Reef, Australia)

We investigated microphytobenthic photosynthesis at four stations in the coral reef sediments at Heron Reef, Australia. The microphytobenthos was dominated by diatoms, dinoflagellates and cyanobacteria, as indicated by biomarker pigment analysis. Conspicuous algae firmly attached to the sand grains (ca. 100 μm in diameter, surrounded by a hard transparent wall) were rich in peridinin, a marker pigment for dinoflagellates, but also showed a high diversity based on cyanobacterial 16S rDNA gene sequence analysis. Specimens of these algae that were buried below the photic zone exhibited an unexpected stimulation of respiration by light, resulting in an increase of local oxygen concentrations upon darkening. Net photosynthesis of the sediments varied between 1.9 and 8.5 mmol O₂ m⁻² h⁻¹ and was strongly correlated with Chl a content, which lay between 31 and 84 mg m⁻². An estimate based on our spatially limited dataset indicates that the microphytobenthic production for the entire reef is in the order of magnitude of the production estimated for corals. Photosynthesis stimulated calcification at all investigated sites (0.2–1.0 mmol Ca²⁺ m⁻² h⁻¹). The sediments of at least three stations were net calcifying. Sedimentary N₂-fixation rates (measured by acetylene reduction assays at two sites) ranged between 0.9 to 3.9 mmol N₂ m⁻² h⁻¹ and were highest in the light, indicating the importance of heterocystous cyanobacteria. In coral fingers no N₂-fixation was measurable, which stresses the importance of the sediment compartment for reef nitrogen cycling.     

Comparison of ecophysiological characteristics between introduced and indigenous mangrove species in China

Due to its rapid growth, the introduced mangrove species Sonneratia apetala from Bangladesh has been widely used in mangrove restoration in southeastern China since 1985. As an indigenous mangrove species in Hainan, China, Sonneratia caseolaris was also planted in Guangdong Province for afforestation purposes. Both species have developed well in their new habitats, but their ecophysiological differences with the native mangrove species have not been studied. In this study, leaf gas exchange, water and nitrogen use efficiencies of two Sonneratia species were compared with those of selected native mangrove species (Avicennia marina, Aegiceras corniculatum, Kandelia candel, and Excoecaria agallocha) in Hainan and Shenzhen. The introduced S. apetala maintained lower carbon assimilation rate (A) and photosynthetic nitrogen use efficiency (PNUE) than the indigenous S. caseolaris. In Shenzhen, the two introduced Sonneratia had comparable photosynthetic rates and water use efficiency (WUE) with the native mangrove species, except that PNUE in S. caseolaris was significantly higher than in the native mangrove species. The two Sonneratia species showed significant overlap in PNUE and long-term WUE. Photosynthetic parameters derived from leaf photosynthetic light–response curves and A–C_i curves also suggested lower carbon assimilation capacities for the introduced Sonneratia than for the native mangrove species in both study sites. The lower light compensation point (LCP) of two introduced Sonneratia in both study sites also indicated a better adaptation to a low light regime than the native mangrove species. The results of photosynthetic capacities indicated that the introduced mangrove species have little competitive advantage over local native mangrove species in their respective new habitats.     

Spatiotemporal aspects of silica buffering in restored tidal marshes

Losses of pelagic diatom production resulting from silica limitation have not only been blamed for toxic algal blooms, but for the reduction in ability of coastal food webs to support higher trophic levels. Recent research has shown the importance of advective seepage water fluxes of dissolved silica (DSi) from freshwater marshes to pelagic waters during moments of riverine Si-limitation. In this study, we investigated the potential impact of recently installed new tidal areas along the Schelde estuary, located in former polder areas and characterized by so-called controlled reduced tidal regimes (CRT). Nine mass-balance studies were conducted in a newly constructed CRT in the freshwater Schelde estuary. During complete tidal cycles both DSi and amorphous silica (ASi) concentrations were monitored at the entrance culverts and in different habitats in the marsh. A swift DSi-delivery capacity was observed despite the shifted spatiotemporal frame of exchange processes compared to reference marshes. As silica-accumulating vegetation is not yet present, and difference with reference marshes’ deliveries is surprisingly small, we indicate diatomaceous debris and phytoliths to be the main silica source. Although further research is necessary on the driving forces of the different processes involved, restoration of former agricultural areas under CRT-regime provide the potential to buffer silica in the estuary.     

Isotopic,trace element and nutrient characterization of coastal waters from Ubatuba inner shelf area,south-eastern Brazil

Stable isotopes, tritium, radium isotopes, radon, trace elements and nutrients data were collected during two sampling campaigns in the Ubatuba coastal area (south-eastern Brazil) with the aim of investigating submarine groundwater discharge (SGD) in the region. The isotopic composition (δD, δ¹⁸O, ³H) of submarine waters was characterised by significant variability and heavy isotope enrichment. The stable isotopes and tritium data showed good separation of groundwater and seawater groups. The contribution of groundwater in submarine waters varied from a few % to 17%. Spatial distribution of ²²²Rn activity concentration in surface seawater revealed changes between 50 and 200 Bq m⁻³ which were in opposite relationship with observed salinities. Time series measurements of ²²²Rn activity concentration in Flamengo Bay (from 1 to 5 kBq m⁻³), obtained by in situ underwater gamma-spectrometry showed a negative correlation between the ²²²Rn activity concentration and tide/salinity. This may be caused by sea level changes as tide effects induce variations of hydraulic gradients, which increase ²²²Rn concentration during lower sea level, and opposite, during high tides where the ²²²Rn activity concentration is smaller. The estimated SGD fluxes varied during 22–26 November between 8 and 40 cm d⁻¹, with an average value of 21 cm d⁻¹ (the unit is cm³/cm² per day). The radium isotopes and nutrient data showed scattered distributions with offshore distance and salinity, which implies that in a complex coast with many small bays and islands, the area has been influenced by local currents and groundwater–seawater mixing. SGD in the Ubatuba area is fed by coastal contaminated groundwater and re-circulated seawater (with small admixtures of groundwater), which claims for potential environmental concern with implications on the management of freshwater resources in the region.