敞开酸溶和偏硼酸锂碱熔ICP-MS法测定多金属矿中的稀土元素及铌钽锆铪

用电感耦合等离子体质谱法(ICP-MS)测定地质样品中的稀土及难熔元素,混合酸敞开酸溶法和碱熔融法是两种主要的溶样方法。但地质样品组分复杂,元素之间存在相互共生的现象,对于特殊元素、特殊样品用传统酸溶法会造成部分元素消解不完全,使测定结果不准确;而碱熔法的操作过程繁琐,且溶液盐度高,易产生基体干扰和堵塞仪器进样系统。本文改进了传统四酸和五酸体系,采用氢氟酸-硝酸-硫酸敞开酸溶体系,用国家一级标准物质制作标准曲线测定15种稀土元素,方法准确度(ΔlgC)为0.001～0.027。同时改进了偏硼酸锂碱熔法,样品用偏硼酸锂碱熔提取,加入氢氧化钠调节溶液至碱性条件,所测元素与偏硼酸锂共沉淀后过滤分离熔剂,再用硝酸复溶测定15种稀土元素及铌钽锆铪。两种溶样方法的测定值与认定值的相对误差为1.09%～9.30%。将混合酸敞开酸溶法测定稀土元素、偏硼酸锂碱熔法测定铌钽锆铪的结果与其他实验室密闭酸溶法相比,两组数据的相对偏差为0.13%～15.32%。本实验表明,混合酸敞开酸溶法适用于测定地质样品中的稀土元素,偏硼酸锂碱熔法不仅适用于测定地质样品中的稀土元素及铌钽锆铪,也适用于测定如古老高压变质岩石及铝含量高的样品中的铌钽锆铪。     

长江中下游六省大气甲烷柱浓度时空分布

甲烷(CH₄)是造成气候变暖的主要温室气体之一。为了了解长江中下游水稻种植区CH₄浓度的分布情况,本次研究基于温室气体观测卫星(greenhousegasesobservingsatellite,GOSAT)和大气红外探测仪(atmospheric infraredsounder,AIRS)卫星反演的数据产品,对我国长江中下游六省大气CH₄柱浓度的时空分布特征进行了研究。研究结果表明,由GOSAT反演的长江中下游六省大气CH₄浓度呈逐年增长趋势,其年均浓度由2011年的1817×10^-9增长至2018年的1875×10^-9,高于东三省、华北平原和全国平均水平。区域平均年增长量为8.2×10^-9 a^-1。各省年际增长幅度略有差异,纬度偏低的江西、湖南和浙江三省大气CH₄浓度高且增长量偏大,纬度偏高的湖北、安徽和江苏三省大气CH₄浓度略低且增长量偏小。长江中下游六省大气CH...     

Kurzzeit-Toxizitätstests zur Messung der Toxizität von Chemikalien gegenüber Belebtschlamm

Short-term Toxicity Tests for the Measurement of Toxicity of Chemicals Towards Activated Sludge. To avoid severe damage to the activated sludge of a wastewater treatment plant it is necessary to control the sludge activity by means of biological test systems. Especially the short-term respiration assay and the dehydrogenase assay with resazurin as a redox-dye seem to be appropriate for this monitoring program. The practical performance of both test systems was optimized in some essential points. With the help of several reference substances both monitoring systems were tested for practical use as short-term toxicity tests. The results of the investigations showed that the inhibitory concentrations measured in both test systems were partially very different. In monitoring experiments with laboratory-scale wastewater treatment plants it could be shown that a positive correlation between respiration activity and dehydrogenase activity is not always given. Furthermore, a pH-dependent toxicity could be demonstrated for several substituted phenols.     

Application of Spectral Decomposition to Detection of Fracture-Cavity Carbonate Reservoir Beds in the Tahe Oiifieid, Tarim Basin, NW China

Ordovician fracture-cavity carbonate reservoir beds are the major type of producing formations in the Tahe oilfield, Tarim Basin. The seismic responses of these beds clearly changes depending on the different distance of the fracture-cavity reservoir bed from the top of the section. The seismic reflection becomes weak or is absent when the fracture-cavity reservoir beds are less than 20 ms below the top Ordovician. The effect on top Ordovician reflection became weaker with deeper burial of fracture-cavity reservoir beds but the developed deep fracture-cavity reservoir beds caused stronger reflection in the interior of the Ordovician. This interior reflection can be divided into strong long-axis, irregular and bead string reflections, and was present 80 ms below the top Ordovician. Aimed at understanding reflection characteristics, the spectral decomposition technique, which uses frequency to ＂tune-in＂ bed thickness, was used to predict Ordovician fracture-cavity carbonate formations in the Tahe oilfield. Through finely adjusting the processing parameters of spectral decomposition, it was found that the slice at 30 Hz of the tuned data cube can best represent reservoir bed development. Two large N-S-trending strong reflection belts in the mid-western part of the study area along wells TK440- TK427-TK417B and in the eastern part along wells TK404-TK409 were observed distinctly on the 30 Hz slice and 4-D time-frequency data cube carving. A small N-S trending reflection belt in the southern part along wells T403-TK446B was also clearly identified. The predicted reservoir bed development area coincides with the fracture-cavities connection area confirmed by drilling pressure testing results. Deep karst cavities occur basically in three reservoir bed-development belts identified by the Ordovician interior strong reflection. Spectral decomposition proved to be a useful technique in identifying fracture-cavity reservoir beds.     

EH4电磁系统在云南红河地区地下水勘查中的应用

本文介绍了EH4电磁成像系统的基本原理、技术特点和适用范围,结合该系统在云南红河地区不同类型地下水勘查中的应用实例,证明该系统能够查清厚覆盖层下的地质构造、地下河形态及含水岩溶带。利用该系统确定的井位已成功地打出地下水,有效地解决了当地的供水问题。     

新显色剂四-(3-磺基-4-氯苯基)卟啉分光光度法测定微量铜

研究了新显色剂四-(3-磺基-4-氯苯基)卟啉在微酸性介质中,表面活性剂OP与CPC存在下测定微量铜的显色反应。络合物在波长420 nm处有最大吸收峰,摩尔吸光度系数为3.44×105L·mol-1cm-1,用双峰双波长光度法测定摩尔吸光系数为6.72×105L·mol-1·cm-1,铜含量在0.5~4.5μg/25 m L范围内符合比耳定律。方法应用于矿样中微量铜的测定,结果令人满意。     

准中4区块侏罗系头屯河组滩坝及风暴沉积特征

在准噶尔盆地中部(简称准中)4区块侏罗系岩心观察的基础上,考虑粒度分析、薄片镜下观察及古气候恢复成果,认为该区头屯河组沉积时期发育滨浅湖滩坝沉积;以典型风暴沉积构造的识别为基础,提出一种与滩坝相伴生出现的新的风暴岩类型——滨浅湖风暴岩,并建立理想垂向序列模型,自下至上依次为:递变、块状层段(Sa),平行层段、冲洗交错层段(Sb),波状层段(Sc);断续纹层段(Sd)和滨浅湖泥岩段(Se).该类风暴岩发育在正常浪基面之上的滨浅湖地区,与半深湖风暴岩相比,更易遭受后期波浪改造而难以完整保存;因其发育的平面位置不同,滨浅湖风暴岩序列顶底的沉积物可以是氧化色调的滨浅湖泥坪沉积物或是正常的滨浅湖滩坝沉积物.滨浅湖风暴岩的提出完善了滨浅湖滩坝沉积体系,为研究区古地理、古气候特征的恢复提供线索,为滩坝的成因和沉积环境研究提供思路,对准噶尔盆地隐蔽油气藏的勘探具有一定指导意义.     

“SZ-4”飞船高度计天线指向角反演方法

利用2003年2月7到8日“SZ-4”高度计的波形数据,经过波形数据预处理(波形为1 s的平均、去除热噪声和波形归一化)后,对海面回波波形后沿进行拟合,计算出了高度计天线的指向角,结果表明,“SZ-4”飞船高度计天线的指向角几乎全部在0.024°以内,天线指向在计算时间内比较稳定.     

铜藻(Sargassum horneri)在营养限制胁迫后对NH4-N的超补偿吸收研究

以经济马尾藻铜藻(Sargassum horneri)为研究材料,研究了其在营养限制胁迫后对NH_4-N的超补偿吸收情况。实验分营养限制和恢复营养两个阶段进行,每个阶段均设置饥饿处理组、饱和处理组和正常对照组。铜藻在低营养限制胁迫(饥饿)下培养10天后,恢复营养盐培养3天,分别采用次溴酸盐氧化法和锌镉还原法测定培养液中的NH_4-N和NO_3-N的浓度。本文研究发现,饥饿处理组中铜藻吸收氨氮的速率远高于正常对照组和饱和处理组,在恢复培养第一天时,饥饿处理组对NH_4-N的吸收速率最高为14.94μmol/(g·h),与正常对照组及饱和处理组间差异显著。在恢复培养的后两天,三个处理组中铜藻对NH_4-N的吸收速率差异慢慢变小,直至最后几乎相同。三组对NO_3-N没有表现出较高的吸收,最高仅为6.15μmol/(g·h),结果表明:氮源包括NH_4-N和NO_3-N时,铜藻优先选择吸收NH_4-N。实验后称重测定生长速率:对照组、饥饿处理组和饱和组生长率(SGR)分别为8.48%、8.86%、8.01%,ANOVA方差分析表明,三者存在显著差异(P=0.0320.05),从而证实了铜藻也存在超补偿生长的现象。