Tar ball frequency data and analytical results from a long-term beach monitoring program

Following the spill of fuel oils from the New Carissa in February 1999, approximately 300 km of beaches on the Pacific coast of North America were surveyed. A long-term observation program focused on the documentation of stranded tar balls in the vicinity of the spill site. Systematic beach surveys which were conducted over the period March 1999 to April 2001 and semi-logarithmic scale, time-series plots proved the most useful format for identifying trends. Beach monitoring continued through to August 2001. by which time 212 tar balls had been analyzed by GC/MS for their chemical characteristics. The samples of tar balls collected between February 1999 and August 2001 were qualitatively compared with New Carissa source oils (NCSO) and 101 (48%) were not consistent with NSCO. The presence of tar balls that are not related to an incident can confound attempts to define cleanup or endpoint criteria and to assess possible injury to natural resources.     

Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.     

Synthesis, Characterization and Antibacterial Activity of New Ln（Ⅲ ） Complexes with an Unsymmetrical Schiff Base Ligand

1Introduction SomeSchiffbasecomplexesderivedfromaminoacidsareparticularlyactiveinbiologycatalysisandmaterial.Thestudyofthemisfocusofthestudyof coordinationchemistry.Recently,studiesofsuchmetalcomplexesofmono Schiffbaseshavebeenre ported(Fanetal.,2003a,b;L…     

POSSIBLE INFLUENCE OF FEBRUARY-APRIL ARCTIC OSCILLATION ON THE ITCZ ACTIVITY OF WESTERN-CENTRAL PACIFIC

The daily patterns and activity of Intertropical Convergence Zone(ITCZ) in the Western-Central Pacific Ocean are analyzed using NOAA interpolated Outgoing Longwave Radiation dataset during the period from 1979 to 2008, and the relationships between ITCZ patterns and Arctic Oscillation(AO) is investigated in this paper. In accordance with the central activity region the daily ITCZ can be divided into six patterns—north, south, equator, double, full and weak pattern, respectively. The statistic result shows that the north(accounting for 30.98% of the total observations), south(31.11%) and weak(24.05%) ITCZ patterns are the most active daily patterns within a 30-year period, while the other three ITCZ patterns occur infrequently. Results show that the February-April AO index has a significant positive(negative) correlation with the frequency of the north(weak) ITCZ pattern from March-May to August-October, with the strongest correlation in April-June(March-May). At the same time, the lower tropospheric atmosphere circulation(850-hPa wind field) and SST anomalies corresponding to the AO change significantly in the tropical Pacific. When AO is in the positive phase, there is an anomalous westerly from the equator to 15°N and warmer SST in the critical north ITCZ active region, while there is an anomalous easterly and insignificant change of SST from the equator to 15°S. The wind and SST anomalies share the same characteristics of the equatorial asymmetry and thus enlarge the gradient between the south and north of equator, which would help reinforce convection in the north of equator and result in more frequent occurrence of the northern type of ITCZ.     

Quantitative characterization of connectivity and conductivity of sandstone carriers during secondary petroleum migration,applied to the Third Member of Eocene Shahejie Formation,Dongying Depression,Eastern China

Studies on migration pathways remain qualitative, albeit extensive quantification of migration forcing. In this study, hydrocarbon carriers are defined as carrier units and their corresponding carrier beds for the Third Member of Eocene Shahejie Formation in the Dongying Depression, Bohai Bay Basin, eastern China, on the basis of their lithofacies and physical properties, spatial relationships, and data availability; secondary migration conduits are then quantified. A carrier unit is defined as a stratigraphic unit that contains microscopically porous and permeable carrier beds and is covered by regional seals. The carrier beds are macroscopically and physically connected to each other within a carrier unit and are hydrodynamically connected during secondary migration. A method of quantifying sandstone carrier units using common physical properties is developed. First, a carrier unit containing potential carrier beds is identified on the basis of lithofacies and their lateral changes. Second, physical connectivity of sandstone carrier beds is assessed on the basis of percolation theory. Third, the hydrodynamic connectivity of a sandstone carrier unit is analyzed using effective parameters that may reflect the hydraulic circulation in the carrier unit. Last, the conductivity of a sandstone carrier bed is quantitatively characterized using appropriate physical property parameters. The results for sandstone carrier units in the Third Member of the Shahejie Formation are used in numerical models addressing Pleistocene secondary migration. The model results explain the discovered accumulation and hydrocarbon shows well; and the model predictions on exploration targets have been confirmed by drilling.     

三塘湖盆地二叠系干酪根热模拟气体产物的地球化学特征

针对三塘湖盆地的主力烃源岩二叠系芦草沟组泥质烃源岩开展封闭体系和半开放体系热模拟实验,前者将干酪根密封在金管中开展实验、后者直接对烃源岩样品进行压机半开放体系热解模拟,对实验中生成气体的组分和稳定碳同位素进行分析。实验结果显示,两种热解方法以无机气体生成为主,包括CO2、H2、H2S 和 N2等,其中 CO2含量最丰富,这与样品干酪根中丰富的氧含量一致。半开放体系模拟实验温度达到480℃时,气态烃的含量达40.64%,其中甲烷含量达到26.10%,封闭体系中随着模拟温度升高烃类气体产物的碳同位素呈现先变轻后变重的趋势,但同位素分馏程度不大, CH4气体的δ13C 值分布在-40.2‰~-46.6‰之间, C2H6分布在-34.3‰~-38.0‰之间, C3H8分布在-33.6‰~-36.0‰之间,而CO2气体δ13C值分布在-32.8‰~-28.8‰之间。三塘湖盆地针对气藏的勘探已经有所发现,但有关气藏的地球化学特征报道较少,该工作中的模拟实验结果可为三塘湖盆地深入的气藏地球化学勘探提供基础数据。     

Hydromechanical behavior of Tournemire argillites: Measurement of the poroelastic parameters and estimation of the intrinsic permeability by œdometric tests

Knowledge of shale poromechanical behavior is proven to be essential for various environmental issues such as deep geological storage of CO₂, high level radioactive waste storage, oil field abandonment and so forth… This paper sets out the key points of shale experimental characterization within the framework of Biot's mechanics of fluid saturated porous solids. Shales are well known to present a more or less transverse isotropy. This paper describes a full methodology for ?dometric tests on such sensitive and weakly permeable material. To illustrate this methodology, measurements carried out on Tournemire argillite are proposed. A transverse isotropic poroelastic model is also used to give a more in depth understanding of the hydromechanical coupling. Copyright © 2010 John Wiley & Sons, Ltd.     

基于高密度电阻率法的土体干缩裂隙动态发育过程精细监测研究

土体在气候作用下发育干缩裂隙是一种常见的自然现象,裂隙的存在会极大弱化土体的工程性质,诱发许多岩土与地质工程问题。为了实时掌握黏性土中干缩裂隙网络的发展状态,提出了一套基于高密度电阻率层析成像技术（ERT）的土体干缩裂隙动态发展过程精细监测方法。分别开展模型试验及原位试验,利用自行研制的测定系统持续采集电流-电位差数据,随后利用自行开发的有限元法电阻率层析成像（FemERT）系统进行数据处理,获取了裂隙网络在不同发育阶段的空间分布特征。结果表明：（1）ERT可以实现土体裂隙发育过程的精细监测,具备监测三维裂隙网络几何形态的能力,裂隙宽度的识别精度达到毫米级,裂隙深度的识别精度达到厘米级;（2）ERT的感度分布特征解释了裂隙发育对于土体电阻率的影响规律,测定电阻值时程曲线因裂隙产生位置的不同而呈现不同的变化规律;（3）反演电阻率及其相对变化率（Rev）可以直观表征裂隙网络在不同阶段的空间几何形态,凸显裂隙动态发育过程对于土体导电性的影响。     

南海北部琼东南盆地第四系陆架边缘轨迹迁移及深水沉积模式

陆架边缘迁移轨迹综合受控于构造、物源、海平面和气候等多种因素,其迁移演化与深水沉积体系发育关系密切。陆架边缘迁移规律及沉积物输送体制与深水砂体预测是当前国际地学领域的热点议题。本文通过基于琼东南盆地新采集的高精度地震资料,定量表征了第四系陆架边缘轨迹,识别了低角度缓慢上升型、中等角度上升型和高角度急剧上升型等3类陆架边缘轨迹类型。2.4 Ma以来,陆架边缘轨迹时空演化可分为3个阶段且具有侧向差异性:2.4~1.9 Ma以低角度缓慢上升型为主,1.9~0.8 Ma西北部以低角度缓慢上升型为主,东北部则以中等角度上升型为主,0.8 Ma至今西北部以中等角度上升型为主,东北部以高角度急剧上升型为主。琼东南盆地第四系陆架边缘迁移轨迹研究表明:当陆架边缘轨迹角0°<α<4°时,陆坡区峡谷规模较小且下切浅,深海平原区发育多期大型海底扇沉积,块体搬运沉积(MTDs)较少;当4°<α<35°时,陆坡区峡谷规模有所增加,深海平原区海底扇沉积与块体搬运沉积均有出现;当35°<α<90°时,陆坡区峡谷发育较少但下切深,深水平原区沉积以大型块体搬运沉积为主,海底扇几乎不发育。琼东南盆地更新世以来气温不断下降,以及东亚冬季风的显著增强,物源供给增强加之海平面的下降进而导致了西北部陆架边缘表现为进积特征;研究区东北部的断裂活动频繁以及物源供给弱,导致了研究区东北部陆坡推进距离远远小于研究区西北部且发育多期次块体搬运沉积物。以上认识对南海北部陆架边缘体系及深水扇预测具有一定的理论意义。     

内蒙古河套灌区浅层地下水化学特征和灌溉适宜性分析

随着黄河流域水资源供需矛盾加剧,我国特大型灌区——内蒙古河套灌区开始采用黄河水与地下水相结合的方式进行农业灌溉。本研究采集河套灌区内499组地下水样品和1组黄河水样品,在分析地下水和黄河水样品的水化学特征基础上,运用钠吸附比(SAR)、渗透指数(PI)、钠含量(SC)和残余碳酸钠(RSC)以及《农田灌溉水质标准(GB 5084—2021)》对地下水和黄河水的灌溉适宜性进行对比分析。结果表明,地下水与黄河水均为弱碱性水,Ca²⁺和HC0₃^-为优势离子,Gibbs图显示地下水受到岩石风化淋溶和蒸发浓缩的双重影响,对灌溉适宜性影响较大的钠盐主要来自岩盐溶解。灌溉适宜性分析结果表明,从SAR、PI和RSC指标来看,地下水的灌溉适宜性较好,从SC指标来看,不适宜灌溉的地下水主要分布在灌区北部总排干和灌区南部黄河沿岸;根据农田灌溉水质标准分析,除总砷和氯化物两项指标外,其余指标适宜灌溉样品占比均高于90%,综合评价全区共231组地下水样品适宜灌溉。地下水与黄河水灌溉适宜性对比表明,黄河水的SAR和SC指标灌溉适宜性分析结果较好,地下水的PI和RSC指标灌溉适宜性分析结果较好,根据灌溉水质标准显示黄河水所有指标均适宜灌溉。本研究为日后内蒙古河套灌区合理选用灌溉水源提供数据支撑,为该区域地下水的治理与防控提供科学依据。