A ‘superoutburst’ in XTEJ1118+480

I propose that the properties of the two outbursts observed in the X‐ray transient XTEJ1118+480 in 2000 are akin to superoutbursts of SU UMa stars. In these systems a ‘normal’ outburst immediately precedes a 5–10 times longer (‘super’) outburst. The optical light curve of the outbursts of XTEJ1118+480 is remarkably similar to that seen in some SU UMa stars, such as UVPer and TLeo, where the precursor outburst is distinct from the superoutburst, but the time scales are a factor of ∼15 different. The first outburst of XTEJ1118+480 was relatively short (∼1 month) while the second outburst was ∼5 times longer. During the second outburst superhumps were seen, a feature characteristic for superoutbursts. The gap of about a month between the two outbursts is longer in X‐rays with respect to the optical, a feature not previously recognized for X‐ray transients. Also in SU UMa stars the precursor outburst becomes more distinct at shorter wavelengths. Finally, I show that the time of appearance of the superhumps in XTEJ1118+480 is consistent with the expected superhump growth time, if the superhump mechanism was triggered during the first outburst. I conclude that the similarity in outburst behaviour in the two types of systems provides further support that a common mechanism is at work to start the long (‘super’) outbursts.     

Spectroscopic Characterization of Organic Structures and Organic‐Inorganic Interactions in Paper Mill Sludge

The organic composition and organic‐inorganic interaction in paper mill sludge (PS) solvent extracts (hexane, ethyl acetate, acetone and ethanol) and humic fractions, humic acid (HA) and humin (HU) were studied by electron paramagnetic resonance spectroscopy (EPR), proton and carbon‐13 nuclear magnetic resonance spectroscopy (¹H NMR; ¹³C NMR), Fourier‐transformed infrared spectroscopy (FTIR), and ultraviolet‐visible spectroscopy (UV‐vis). The strategy of fractionating the PS, sequentially, with organic solvents of increasing polarity is a reliable analytical procedure for humic substance sample separation because it results in more purified fractions. FTIR, ¹H NMR and ¹³C NMR results showed that hexane extract consisted mainly of aliphatic hydrocarbon structures. Their contents in the extracts decreased as the polarity of the extracting solvent increased and the content of oxygen functional groups increased. Carboxylic and carboxylate functional groups were found in the acetone extract, and ester and ether functions were predominantly found in the ethanol extract. EPR spectra revealed some Fe³⁺ complexes with rhombic structure (g₁ = 4.3; g₂ = 9.0) in the humic fractions and in all solvent extracts, except hexane. Quasi‐octahedral Fe³⁺ complexes (g = 2.3; ΔH_pp ≤ 400 G) were found in the HU fraction and in the acetone extract. The organic free radical content in the HA fraction was higher than the non‐fractionated PS sample and HU fraction.     

Characterisation of Fulvic Acids and Glycyrrhizic Acid by Time‐of‐Flight Secondary Ion Mass Spectrometry

Fulvic acids of different origin, spray deposited on polished silicon after dissolution in high‐purity water without any additives, were analysed by time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS) in combination with oblique 24...36 keV SF₅⁺ ion bombardment. The observed, highly reproducible mass spectra cover more than five orders of magnitude in dynamic range, without background subtraction. Apart from lines due to atomic ions and low‐mass ion fragments, the mass spectra exhibit broad maxima between m/z 200...350, mainly due to a beat‐like superposition of lines at every single mass number, up to at least m/z 400. In the negative ion spectra the beats have a spacing of m/z 14, corresponding to a CH₂‐unit. The high‐mass tails of the spectra extend well beyond m/z 5000, with similar slopes in the positive and the negative ion mass spectra. The negative spectra appear to be less affected by fragmentation products than the positive spectra. Fulvic acids (FAs) of different origin show distinctly different spectra, with mean masses ranging between m/z ≈ 450 and 580 (for a low‐mass cut‐off m/z 150). To further verify the ability of TOF‐SIMS to detect molecules and clusters with masses significantly above the maxima of the FA spectra, samples of glycyrrhizic acid (GA, as GA ammonium salt with molecular weight 840) were also analysed. Parent ions as well as multimers (GA)_n were observed as positive and negative ions, up to n = 4 (m/z 3320). The results are compared with spectra recently obtained by other mass spectrometric techniques.     

Sorption and Chemical Reactions of PAHs with Dissolved Humic Substances and Related Model Polymers

Sorption coefficients measured for PAHs on dissolved humic substances by SPME and FQT were found to be inevitably different and method‐dependent – SPME provides activity‐based and FQT concentration‐based sorption coefficients. Poly(acrylic acid) esters as well‐defined model polymers were used in sorption experiments, leading to the conclusion that short aliphatic chains are more effective in binding PAHs than aromatic moieties. FQT was inappropriate to measure sorption coefficients for the interaction of pyrene with poly(acrylic acid) esters but the experiments revealed a characteristic shift in the fluorescence spectrum. Using pyrene as a probe for the molecular environment in the sorbed state, the observed spectral shift indicated a highly hydrophobic microenvironment. The empirical relationships between lg K_DOC and lg K_OW were generalized on the basis of a modified Flory‐Huggins concept. Introducing only one sorbent‐specific parameter, the solubility parameter δ_DOM, the calculation of sorption coefficients became possible for a wide range of HOCs using fundamental data readily available from the literature. Long‐term experiments showed that reactive PAHs (such as acenaphthylene and 9‐methylanthracene) are able to react with HAs under strictly abiotic and anoxic conditions, whereas less reactive PAHs (such as naphthalene and dihydroanthracene) do not form bound residues. The HA reveals two functions in the interaction, behaving as a reaction partner and as a protecting ligand.     

Lagoon–tidal flat sedimentation in an epeiric sea: Proterozoic Bhander Group,Son Valley,India

The Bhander Group, the uppermost stratigraphic unit of the Proterozoic Vindhyan Supergroup in Son Valley, exhibits in its upper part a 550 m thick, muddy siliciclastic succession characterized by features indicative of deposition in a wave‐affected coastal, lagoon–tidal flat environment suffering repeated submergence and emergence. The basic architecture of the deposit is alternation of centimetre‐ to decimetre‐thick sheet‐like interbeds of coarser clastics (mainly sandstone) and decimetre‐thick mudstones. The coarser interlayers are dominated by a variety of ripple‐formed laminations. The preserved ripple forms on bed‐top surfaces and their internal lamination style suggest both oscillatory and combined flows for their formation. Interference, superimposed, ladder‐back and flat‐topped ripples are also common. Synsedimentary cracks, wrinkle marks, features resembling rain prints and adhesion structures occur in profusion on bed‐top surfaces. Salt pseudomorphs are also present at the bases of beds. The mudstone intervals represent suspension settlement and show partings with interfaces characterized by synsedimentary cracks. It is inferred that the sediments were deposited on a coastal plain characterized by a peritidal (supratidal–intertidal) flat and evaporative lagoon suffering repeated submergence and emergence due to storm‐induced coastal setup and setdown in addition to tidal fluctuations. The 550 m thick coastal flat succession is surprisingly devoid of any barrier bar deposits and also lacks shoreface and shelfal strata. The large areal extent of the coastal flat succession (c. 100,000 km²) and its great thickness indicate an extremely low‐gradient epeiric basin characterized by an extensive coastal flat sheltered from the deeper marine domain. It is inferred that the Bhander coastal flat was protected from the open sea by the Bundelkhand basement arch to the north of the Vindhyan basin, instead of barrier bars. Such a setting favoured accumulation of a high proportion of terrigenous mud in the coastal plain, in contrast to many described examples from the Proterozoic. Copyright © 2001 John Wiley & Sons, Ltd.     

Pseudo‐dynamic testing with substructuring at the ELSA Laboratory

The paper describes the distinctive features of the pseudo‐dynamic test method as implemented at the ELSA reaction‐wall facility. Both hardware and software aspects are considered. Particular attention is devoted to the digital control system and to a coupled numerical–experimental substructuring technique allowing realistic earthquake testing of very large structures. Mathematical and implementation details corresponding to this testing technique are given for both synchronous and asynchronous input motion. Selected test results illustrate the advantages of the presented features. Copyright © 2000 John Wiley & Sons, Ltd.     

A response spectrum approach for seismic performance evaluation of actively controlled structures

To evaluate and measure the effectiveness of active control schemes in reducing the response of structures subjected to earthquake excitations, it is common to use recorded or artificially generated earthquakes as input motions. This paper introduces the response spectrum analysis to evaluate linear control systems for seismic inputs defined by code‐prescribed or site‐specific ground response spectra. Using such a method one can evaluate a control system in a single analysis for the ensemble of time histories that are represented by the input response spectra. The response spectrum analysis can also facilitate the implementation of comprehensive parametric studies. A generalized response spectrum method is used to analyse systems with non‐symmetrical matrices that are caused by the general nature of the control actions imposed on the structure. The application of the method is demonstrated on several numerical examples of a building structure where the control force is applied through an active tuned‐mass damper. Copyright © 2000 John Wiley & Sons, Ltd.     

Extending the known distribution of the Younger Dryas Vedde Ash into northwestern Russia

The known distribution of wind‐blown Vedde Ash (ca. 10.3 ka BP) has been extended to the Karelian Isthmus in northwestern Russia. This has been possible as the result of a density separation technique that separates the rhyolitic Vedde Ash shards from the minerogenic host sediment. The Vedde Ash occurs in the middle of a pollen zone with high percentages of, for example, Artemisia and Chenopodiaceae, suggesting that the Younger Dryas (or GS‐I in the GRIP ice‐core event stratigraphy) was cold and dry throughout its duration. This is in agreement with sites in south Sweden where the Vedde Ash also occurs in the middle of a pollen zone dominated by Artemisia, Chenopodiaceae and Cyperaceae. Copyright © 2000 John Wiley & Sons, Ltd.     

The use of caesium‐137 to estimate agricultural erosion on steep slopes in a tropical watershed

The estimation of erosion and sediment delivery rates in tropical mountain watersheds is difficult and most of the methods widely used for estimating soil erosion over large areas have serious limitations. The ¹³⁷Cs approach has potential for quantifying soil erosion because it can provide retrospective estimates of long‐term (since 1963) net sediment redistribution relatively quickly. Despite its great potential, ¹³⁷Cs has not yet been used in an extensive, reconnaissance level survey of erosion in complex tropical mountain environments. The objective of this study was to examine the applicability of the ¹³⁷Cs method to estimate erosion on steep tropical agricultural lands (23 to 80% slopes) in the Nizao watershed, a humid, tropical mountain area of the Dominican Republic. In this study we (i) examine the variation of ¹³⁷Cs in ten reference sites—eight coffee groves and two forested sites—and (ii) estimate erosion from 14 cultivated fields. The soil pool of ¹³⁷Cs ranged from to 150 to 192 mBq cm⁻² on reference sites with minimal erosion. Variability among reference sites was less than expected for such complex mountain terrain. The variability within coffee and forested reference (average CV=28%) sites was similar to the variability found on grassland and forested reference sites in the temperate zone. The estimated annual soil loss from 14 sampled fields ranged from 6 to 61 t ha⁻¹ year⁻¹ with an overall mean of 26 t ha⁻¹ year⁻¹. Overall, the soil erosion estimates found using the ¹³⁷Cs method were much lower than those often assumed for such steep tropical hillsides. These erosion estimates account for soil loss since 1963 only and it seems likely that soil losses may have been much higher in earlier decades immediately after initial forest clearing earlier in the 20th century. Copyright © 2000 John Wiley & Sons, Ltd.     

A data‐based mechanistic modelling (DBM) approach to understanding dynamic sediment transmission through Wyresdale Park Reservoir,Lancashire, UK

This paper outlines the application of a new data‐based mechanistic (DBM) modelling methodology to the characterization of the sediment transmission dynamics in a small upland reservoir, Wyresdale Park, Lancashire. The DBM modelling strategy exploits advanced statistical procedures to infer the dynamic model structure and its associated parameters directly from the instrumented data, producing a parametrically efficient, continuous time, transfer function model which relates suspended sediment load at the reservoir inflow to the outflow at the event scale. The associated differential equation model parameters have physical attributes which can be interpreted in terms of sediment transmission processes and associated reservoir trap efficiency. Sedigraph analysis suggests that wind‐induced resuspension episodically supplies an additional load to the reservoir outlet. The stochastic nature of the DBM model makes it ideal for evaluating the effects of uncertainty through Monte Carlo simulations (MCS) for discharge and sediment transmission. Copyright © 2000 John Wiley & Sons, Ltd.