湖南仁里稀有金属矿田地质特征、成矿时代 及其找矿意义

仁里稀有金属矿田位于幕阜山岩体西南缘,是华南地区重要的稀有金属矿产地之一。文章旨在通过对区域成矿条件、矿田地质特征、地球化学特征、成岩成矿时代与稀有金属成矿作用的综合分析,为矿田勘查设计乃至华南地区稀有金属找矿与研究提供理论依据。在矿田范围内对燕山期、武陵期花岗岩及每个矿区代表性伟晶岩进行了系统采样,开展了岩石化学成分分析,同时对矿田内二云母二长花岗岩及锂辉石伟晶岩分别进行了锆石U-Pb、白云母Ar-Ar同位素定年。研究表明:①多期造山与燕山期陆内活化是成矿的有利地质背景,多阶段伸展作用导致幕阜山地区多期大规模的多金属成矿作用发生;②矿田构造主要以NE(或NNE)向构造为主,复合改造NW向及近EW向构造,NE(或NNE)向和NW(或近EW)向构造呈现立交桥式的构造格局,控制了花岗岩和伟晶岩分布;③矿田内伟晶岩属极高分异、富硅、过铝质花岗质岩石,燕山期花岗岩属陆壳改造"S型"花岗岩;④幕阜山岩体由岩体内接触带往岩体外接触带(10 km),由黑云母伟晶岩→二云母伟晶岩→白云母伟晶岩→锂云母伟晶岩→锂辉石白云母伟晶岩过渡,形成了较完整的稀有金属演化序列:无矿化→Be→Be+Nb+Ta→Be+Nb+Ta+Li→Be+Nb+Ta+Li+Cs;⑤稀有金属成矿与构造岩浆时空演化、构造组合、特别是岩浆的分异程度密切相关,矿田内燕山期花岗岩年龄139.3～146.2 Ma,稀有金属成矿年龄为130.5～130.8 Ma。     

北京市不同土地利用类型的土壤镉含量特征

通过对北京市菜地、稻田、果园、绿化地、麦地以及自然土壤6种土地利用类型共595个土壤样品的调查分析,探讨了不同土地利用方式对土壤镉含量的影响。结果表明,绿化地、麦地以及自然土壤与背景值没有显著差别;菜地、稻田、果园的镉含量显著高于背景值。6种土地利用类型中,菜地土壤的镉含量最高,其次为稻田和果园,绿化地以及麦地土壤镉的含量最低。与土壤基线值相比,果园样品有9.5%的样品超出,绿化地与菜地分别有7.7%和4.6%超出。在全部土壤样品中,共有19个样品超标,超标率为3.2%。石景山、门头沟、丰台、海淀等地区的样品超标较多,应该合理规划这些地区的农业土地利用。     

山丘平原过渡区土壤重金属污染特征及评价——以四川省五通桥区为例

采集和分析了五通桥区不同功能区和乡镇73个土壤样品，以了解山丘平原过渡区土壤重金属的含量和污染特征。结果表明，重金属的平均含量为Pb32．18mg／kg、Cd0．82mg／kg、Cu28．61mg／kg、Zn108．08mg／kg、Ni32．66mg／kg、Cr72．44mg／kg；与四川土壤背景值相比，Cu、Ni、Cr的含量与之持平，Pb增加了0．11倍，Zn增加了0．32倍，Cd的积累较为严重，比背景值增加了10倍。污染评价结果显示该过渡区存在一定程度的重金属污染问题，不同功能区的污染程度排序为工业区〉生活区〉农业区。Cd在六种元素的土壤污染分担率中占55．46％，是最主要的污染元素；土壤Cd含量与Pb和Zn存在较高的相关性（相关系数为0．525和0．500），表明存在Pb—Cd和Zn—Cd的复合污染。     

江西东乡铜矿床成因:铜和硫同位素联合约束

东乡铜矿床的赋矿岩石以石炭系砂岩和燕山期花岗斑岩为主。文章对东乡铜矿床同位素地球化学进行了研究,探讨了成矿物质来源及矿床成因。东乡矿区块状矿石和花岗斑岩的黄铁矿δ~(34)S值(0.3‰~1.2‰)非常接近深部地幔硫的值,其δ~(34)S值呈现明显的塔式分布,分布范围较窄,表明矿石中的硫主要来自深源岩浆。δ~(65)Cu值分布范围较窄(-2.10‰~0.17‰),整体接近于零附近,明显不同于块状硫化物矿床(δ~(65)Cu=-0.98‰~3.14‰)、矽卡岩型矿床(δ~(65)Cu=-1.29‰~2.98‰)和热液脉型矿床中δ~(65)Cu值(-3.70‰~0.44‰)的分布范围,其δ~(65)Cu值变化范围大于岩浆矿床的δ~(65)Cu值(-0.62‰~0.40‰),更接近于斑岩型矿床的δ~(65)Cu值(-1.16‰~0.81‰),表明东乡铜矿与岩浆热液作用具有密切的成因联系。因此,推断东乡铜矿为岩浆热液型矿床。     

基于高光谱技术的黑土地微量金属元素探测方法及地学意义

在土壤中重金属含量较低的情况下,重金属的高光谱特征响应非常微弱,不易构建精确的高光谱直接反演模型.为了解决上述问题,依据土壤化学变量间的理化性质,将重金属富集特征转移到与之相关的化学主量元素上,使重金属微弱的信息得以间接定量反演.文中以海伦市黑土土壤为研究对象,通过主成分分析、 聚类分析确定了主量元素氧化铁(Fe2O3...     

新疆双亚幔柱模式及其控矿机制

文章简述了新疆地区的地质理论研究成果、矿产地质特征,认为准噶尔、塔里木双亚幔柱是新疆金属矿产呈现"8"字型分布的主要控制因素;双亚幔拉主体形成时期分别为石炭纪和二叠纪。准噶尔亚幔柱斜向天山造山带,塔里木亚幔柱近垂直,前者作用强烈、短暂,后者温和而漫长。准噶尔、塔里木盆地周缘薄弱带与内部构造体制为地幔深源岩浆及后碰撞造山岩浆的上侵提供了通道。天山造山带形成于晚石炭世,它受双亚幔柱挤压隆起作用有限,成矿局部叠加;二叠纪以来,以相对南北向挤压为主,是能源矿产主要形成时期;阿尔金、昆仑等山脉在新近纪快速隆升。基于幔枝构造启示,建议金属矿产地质找矿勘查与石油、煤炭及铀矿地质勘查展开合作,在准噶尔、塔里木两盆地内进行金属矿产综合找矿。     

DDT residue in soil and water in and around the abounded area of DDT manufacturing factory

Due to the persistent nature of DDT, a persistent organic pollutant and its adverse environmental and health impacts, the present study was undertaken to examine the residual DDT in and around DDT manufacturing factory in Amman Gharh, Nowshera, NWFP. The factory was established in 1963 and remained in operation till 1994. Composite samples of soil, sediments and water were collected in and around the factory area, nearby DDT stores, main factory drain leading to river and nearby villages. Standard procedures were used for the collection, transportation and storage of samples for analysis. Physical parameters for the collected water samples measured were temperature, pH and conductance. Extraction of each sample for DDT analyses was carried out in triplicates using soxhlet extraction apparatus. The extract was transferred to well washed, clean; dry glass vial, sealed and put in the refrigerator. Gas Chromatograph with electron capture detector and capillary column was used for analysis. DDT in the samples was identified on the basis of their retention time and quantified on the basis of peak areas. It is evident from the analytical data obtained in the present study that both water and soil in and around the factory area are still contaminated with DDT, despite the closure of the factory since the past few years.     

Response of alpine chironomid communities (Lake Chuna, Kola Peninsula, northwestern Russia) to atmospheric contamination

A short sediment core from the deepest part of an alpine lake (Lake Chuna, Kola Peninsula, northwestern Russia), covering about the past 200 yrs of sediment accumulation, was analysed for chironomid head capsule remains. The lake has been receiving acidic precipitation and heavy metals loading from the atmosphere since the 1940's. A total of 22 chironomid taxa were recorded. The most important taxa were typical elements of oligotrophic lakes, i.e.Micropsectra insignilobus, Paratanytarsus penicillatus, Stictochironomus spp. and Heterotrissocladius marcidus. Based on the cluster analyses results for the reconstructed environmental variables and chironomid communities, three developmental stages were distinguished from the lake history: (1) Natural ontogeny stage (before ~1945); (2) Initial stage of anthropogenic ontogeny (~1945-~1982); and (3) Anthropogenic ontogeny stage (~1982-~1996). During the first period, the changes in the chironomid fauna were characterized as an anthropogenically undisturbed community, with M. insignilobus dominating (46-66%). The changes during the second period reflected the initial phase of anthropogenic succession associated with the beginning of acidification and heavy metal pollution. The main species showed opposite distributional patterns in this period; the abundance of the group M. insignilobus/Stictochironomus spp. decreased, whereas the abundance of P. penicillatus/H. marcidus increased. The third period was characterized by a major shift in the faunal assemblages, from M. insignilobus to other dominant species including P. penicillatus (19-30%). The increases of Orthocladiinae relative abundance and total organic content in the uppermost sediment layers may be explained by a decrease in lake productivity. The decreases of cold-stenothermal taxa Stictochironomus spp. and M. insignilobus in the uppermost sediment layers can be explained by the global warming during the 20th century. The lake ecosystem is likely to be affected by both inputs of airborne contaminants and climate changes.     

长沙、株洲、湘潭三市土壤中重金属元素的来源

为追踪长沙、株洲、湘潭3个城市表层土壤中Cd、As、Pb等重金属元素的来源,分析了土壤、基岩、大气干湿沉降、水、悬浮物等介质之间重金属元素的质量平衡和土壤自身重金属元素含量随时间变化的特点。结果显示,除As外,区内基岩中的重金属元素含量低于克拉克值;残积物中Cd相对基岩贫化,As、Pb、Cu、Hg等重金属元素相对基岩的富集小于3倍;大气干湿沉降重金属元素相对土壤富集了数倍至数十倍;湘江水体主要向沿江潮土提供As、Cd物源:近50年内土壤重金属元素有较高的增加速率。不同介质间重金属元素的质量变化特点支持长沙、株洲、湘潭三市土壤重金属元素富集的主要物源为大气沉降,地表水及悬浮物是沿江湖土重金属元素的主要物源,基岩对土壤提供的物源有限的结论。     

矿物法--环境污染治理的第四类方法

总结介绍了近10年开展环境矿物材料研究所取得的较为系统的研究成果。新提出环境矿物材料基本性能,包括矿物表面效应、孔道效应、结构效应、离子交换效应、结晶效应、溶解效应、水合效应、氧化还原效应、半导体效应、纳米效应及矿物生物交互效应等。展示环境矿物材料开发应用方面的崭新成就,包括利用天然铁的硫化物矿物强还原性,发明一步法还原Cr(Ⅵ)与沉淀Cr(Ⅲ)废水处理新工艺;利用天然锰的氧化物矿物强氧化性,发明处理高浓度与强污染的印染和酚类废水新方法;利用天然钛的氧化物矿物日光催化性,发明光催化降解卤代有机污染物新方法;利用天然蛭石高温脱水膨胀热效应,发明能大幅度提高型煤固硫率与除尘新方法;利用天然钙基蒙脱石低成本制备出同时防止水体与无机和有机污染物渗漏的自愈性强的填埋场衬层建造用新型防渗材料,发明生活垃圾尤其是危险废物填埋场衬层建造新工艺;发现凝灰岩与花岗岩中长石类矿物发育有良好的孔道结构,核素进入可发生固定化作用,成为有效阻滞核素迁移的天然屏障;利用天然纳米管状纤蛇纹石成功制备二氧化硅纳米管,接枝有机物可由亲水性变为疏水性;利用黄钾铁矾的胶体特征作为多金属矿山废石堆隔离防渗层,防止金属硫化物矿物氧化分解与矿山酸性废水污染等。着重指出今后环境矿物?