Structure cristalline d'une ménéghinite naturelle pauvre en cuivre,Cu0,58Pb12,72(Sb7,04Bi0,24)S24Crystal structure of a Cu-poor natural meneghinite,Cu0.58Pb12.72(Sb7.04Bi0.24)S24

Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å³, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu_0.15Pb₂(Pb_0.53Sb_0.47)(Pb_0.46Sb_0.54)(Sb_0.75Pb_0.19Bi_0.06)S₆; the reduced one: Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536.     

Rifting and early evolution of ancient ocean basins: the record of the Mesozoic Tethys and of the Galicia-Newfoundland margins

Although of different age, the undeformed Cretaceous Iberia/Newfoundland margins and the relics of the Jurassic Briançonnais/Adriatic margins preserved in the Alps document a similar spatial and temporal evolution of rifting suggesting that the evolution of both pairs of margins was controlled by the same processes. Rifting appears to depend strongly on the thermal history of the lithosphere, which controls the rheology and consequently also the structural evolution of the margin. The tectonic evolution of non-volcanic margins appears to be distinctly different from that of volcanic ones.     

Complex Growth Textures in a Polymetamorphic Metabasite from the Kraubath Massif (Eastern Alps)

Zoned garnet and amphibole occur in metabasites of the KraubathMassif, Eastern Alps, that contain relic magmatic clinopyroxene.The amphibole composition gradually changes from core (X_Mg =0·83) to rim (X_Mg = 0·6–0·7). A numberof compositional varieties of garnet occur in the metabasite.An older porphyroblastic garnet (Py_23–27, Alm_41–43,Grs_29–33) has two different compositional domains, onerelatively rich in Mg (Py_27–30) and the other rich inCa (Grs_35–38) with a low Mg (Py_20–25) content. Theyoungest variety, which forms rims on, or microveins in, theporphyroblastic garnet, has high Ca and low Mg (Grs_40–57,Py_2–7, Alm_46–51). The amphibole cores and garnetporphyroblasts are interpreted to represent minerals formedduring Variscan regional metamorphism under amphibolite-faciesconditions. Alpine metamorphism is represented by the most recentCa-rich and Mg-poor variety of garnet that coexists with theamphibole rims, epidote and chlorite. Fracturing in the porphyroblasticgarnet probably originated during retrogression of the Variscanamphibolite-facies assemblages. Textural relations suggest thatthe garnet in the microveins formed by dehydration of hydrousphases during an Alpine metamorphic overprint that reached P–Tconditions of 550–583°C at 1·0 GPa. KEY WORDS: microveins; garnet; metabasites; Kraubath Massif; Eastern Alps     

Dynamics of an active rock glacier (Ötztal Alps, Austria)

The rock glacier Innere Ölgrube, located in a small side valley of the Kauner Valley (Ötztal Alps, Austria), consists of two separate, tongue-shaped rock glaciers lying next to each other. Investigations indicate that both rock glaciers contain a core of massive ice. During winter, the temperature at the base of the snow cover (BTS) is significantly lower at the active rock glacier than on permafrost-free ground adjacent to the rock glacier. Discharge is characterized by strong seasonal and diurnal variations, and is strongly controlled by the local weather conditions. Water temperature of the rock glacier springs remains constantly low, mostly below 1°C during the whole melt season. The morphology of the rock glaciers and the presence of meltwater lakes in their rooting zones as well as the high surface flow velocities of >1 m/yr point to a glacial origin. The northern rock glacier, which is bounded by lateral moraines, evolved from the debris-covered tongue of a small glacier of the Little Ice Age with its last highstand around A.D. 1850. Due to the global warming in the following decades, the upper parts of the steep and debris-free ice glacier melted, whereas the debris-covered glacier tongue transformed into an active rock glacier. Due to this evolution and due to the downslope movement, the northern rock glacier, although still active, at present is cut off from its ice and debris supply. The southern rock glacier has developed approximately during the same period from a debris-covered cirque glacier at the foot of the Wannetspitze massif.     

Late Variscan “Basin and Range” magmatism and tectonics in the Central Alps: evidence from U-Pb geochronology

Abstract

Towards the end of the Variscan orogeny, volcano-sedimentary basins were formed within the mountain hell. U-Pb age determinations on zircons of volcanic and plutonic rocks from intramontane basins of the Central Alps allows us to define the age of two volcano-sedimentary units: The former one was dated older than 333 Ma (probably Visean), the younger one was deposited in a short time span between 303 and 298 Ma (Stephanien). The latter contains tuffs (303 ± 4 Ma), ignimbrites and microgranites (299 ± 2 Ma) and intrusive rhyolites (300 ± 2 Ma) that are all coeval within analytical precision. Granitoid rocks intruded into the volcano-sedimentary rocks at 333 ± 2 Ma, 310 ± 3 Ma and 298 ± 2 Ma. An angular unconformity between the older and the younger units in the Tö di area (Aar massif) indicates uplift and erosion between 310 and 303 Ma.

Our results suggest the existence of two periods of late Variscan extension (or transtension) in the Alpine realm, both combined with magmatic activity. The extensional event of Stephaniun age is characterized by a short duration of only a few million years, between 303 and 298 Ma, comprising tectonic activity, volcanism and plutonism. The plutonic rocks are characterized by a dominant lithospheric mantle component, which was contaminated by different amounts of crostai material and might have been increasingly influenced by aslhcnos-pherie mantle melts in the course of crostai thinning. The ealc-alkaline geochemical characteristics of the granites may be explained as an inherited source feature.

The overall tectonic style and the mode of magmatism resembles the situation of the Basin-and-Kange Province (eastern USA). Consequently there is no need to invoke a late-Variscan Andean-type subduction to explain the geochemical composition of the magmatic rocks. We conclude that late-orogenic extension is an important tectonic stage of the Variscan orogeny, which lasted for some 50 million years. The extension led to thinning of the crust and upwelling of hot mantle, causing high heat flow, intrusion of mantle melts and formation of huge volumes of acid melts.     

Ar / Ar dating of high-pressure rocks from the Ligurian Alps: Evidence for a continuous subduction–exhumation cycle

We present ³⁹Ar–⁴⁰Ar dating of phengite, muscovite and paragonite from a set of mafic and metasedimentary rocks sampled from the high-pressure (HP) metaophiolites of the Voltri Group (Western Alps) and from clasts in the basal layer conglomerates from the Tertiary molasse which overlie the high-pressure basement. The white mica-bearing rocks display peak eclogitic and blueschist-facies parageneses, locally showing complex greenschist-facies replacement textures. The internal discordance of age spectra is proportional to the chemical complexity of the micas. High-Si phengites from eclogite clasts record a ³⁹Ar–⁴⁰Ar age of ca. 49 Ma for the eclogite stage and ca. 43 Ma for the blueschist retrogression; phengites from a blueschist basement sample yield an age of ca. 40 Ma; low-Si muscovite from a metasediment dates the formation of the greenschist paragenesis at ca. 33 Ma. Our data indicate that the analyzed samples reached high-pressure conditions at different times over a time-span of c.a. 10 Ma. Subduction was continuing during exhumation and blueschist retrograde re-equilibration of higher-pressure, eclogite-facies rocks. This process kept the isotherms depressed, allowing the older HP-rocks to escape thermal re-equilibration. Our results, added to literature data, fit a tectonic model of a subduction–exhumation cycle, with different tectonic slices subducted at different times from Early Eocene until the Eocene–Oligocene boundary.     

Regionalization of rainfall thresholds: an aid to landslide hazard evaluation

 Rainfall, soil properties, and morphology are major factors controlling shallow landsliding. A series of meteorological events that triggered soil slips in northern Italy were studied to define rainfall thresholds and to evaluate a possible regionalization. Soil properties, triggering rainfall, and local lithological and morphometrical settings of different sites were used as input to an infiltration model. The approach allows the recognition of several triggering conditions in the Piedmont, Pre-Alpine and Alpine regions. This suggests the need for different rainfall thresholds with respect to those derived with other methods. Intensity versus rainfall duration relationships become particularly important when related to soil permeability and thickness, and demonstrate the role of antecedent precipitation. Events with exceptional water discharge from obstructed road culverts reveal the role played by anthropic structures in triggering such phenomena. Different approaches to slope stability analysis are shown, taking into account bedrock lithology, topography, seepage, and local saturation conditions. Received: 23 October 1997 · Accepted: 25 June 1997     

Late Holocene glacial and periglacial evolution in the upper Orco Valley, northwestern Italian Alps

The sediments present in some areas of the Orco Valley provide indications on climatic variations that occurred during the last 6000 years on the southern slopes of the Alps. In particular, distribution and ages of peat layers help define periods and extent of glacial fluctuation in the last 2200 years. Sampling of soils involved in periglacial processes provided a basis for development of a chronological framework of late Holocene environmental change. The data indicate a trend toward cooler climate in the second half of the Holocene. A strong relationship exists between phases of River Po flooding and expansion/retreat phases of the Swiss glaciers: major glacial advances were coeval with periods of intense flooding of the River Po, whereas the phases of glacial retreat coincided with periods of little flooding of the Po. Only in three cases do relationships between glacier activity and floods show weak correlations; two of the cases relate to the warmest periods in approximately the last 2200 years, while the third is the present period. Paleoclimatic evidence from the study region indicates the relatively warm Roman Period between about 2200 and 1900 cal yr BP appears to better represent modern conditions than does the Medieval Warm Period.     

A review of the thermal regime of the Eastern Alps with respect to the effects of paleoclimate and exhumation

Transient thermal signals such as Pleistocene surface temperature variations or exhumation of great rock volumes are important for the current thermal regime of the Eastern Alpine crust. In this study transient 1-D forward simulations and an analytical approach were used to estimate the order of magnitude of these effects. A comparison with numerical forward simulations and inverse analyses of steady-state heat conduction yields the following main conclusions with respect to the thermal regime of the Eastern Alps along the TRANSALP profile: (1) The change of surface temperatures in the past affects mainly the uppermost part of the Eastern Alpine crust. It results in a maximum thermal signature of more than − 6 K at a depth of 2 km. The deviations from a steady-state temperature gradient and heat flow in the region of the Tauern Window range from 0.3–4 K km^− 1 and 0–6 mW m^− 2, respectively, with maximum values at the surface. (2) Exhumation of the Eastern Alpine lithosphere may result in a thermal signature of up to 4 K at a depth of 1 km. The thermal signature increases further with depth to a maximum of approximately 80 K at a depth of 50 km. As the temperature gradient of the exhumation signal is almost zero at the base of the crust, Moho heat flow appears to be not critically perturbed. (3) The combined effect of exhumation and changing surface temperatures at the Tauern Window amounts to less than 15% of the steady-state temperatures at a depth of  8 km and to less than 10% at the base of Eastern Alpine root. The corresponding perturbation in heat flow is less than 20% at a depth of 4 km, approaching zero below 40 km.     

Transient sediment supply in a high‐altitude Alpine environment evidenced through a 10Be budget of the Etages catchment (French Western Alps)

Although beryllium‐10 (¹⁰Be) concentrations in stream sediments provide useful synoptic views of catchment‐wide erosion rates, little is known on the relative contributions of different sediment supply mechanisms to the acquisition of their initial signature in the headwaters. Here we address this issue by conducting a ¹⁰Be‐budget of detrital materials that characterize the morphogenetic domains representative of high‐altitude environments of the European Alps. We focus on the Etages catchment, located in the Ecrins‐Pelvoux massif (southeast France), and illustrate how in situ ¹⁰Be concentrations can be used for tracing the origin of the sand fraction from the bedload in the trunk stream. The landscape of the Etages catchment is characterized by a geomorphic transient state, high topographic gradients, and a large variety of modern geomorphic domains ranging from glacial environments to scarcely vegetated alluvial plains. Beryllium‐10 concentrations measured in the Etages catchment vary from ~1 × 10⁴ to 4.5 × 10⁵ atoms per gram quartz, while displaying consistent ¹⁰Be signatures within each representative morphogenetic unit. We show that the basic requirements for inferring catchment‐wide denudation from ¹⁰Be concentration measurements are not satisfied in this small, dynamic catchment. However, the distinct ¹⁰Be signature observed for the geomorphic domains can be used as a tracer. We suggest that a terrestrial cosmogenic nuclide (TCN) budget approach provides a valuable tool for the tracing of material origin in basins where the ‘let nature do the averaging’ principles may be violated. Copyright © 2013 John Wiley & Sons, Ltd.