Application of Zn isotopes in environmental impact assessment of Zn–Pb metallurgical industries: A mini review

Zn and Pb smelters are the major contributors to Zn and Pb emissions among all anthropogenic sources, thus, it is essential to understand Zn isotopic variations within the context of metallurgical industries, as well as its fractionation in different environments impacted by smelting activities. This mini review outlines the current state of knowledge on Zn isotopic fractionation during the high-temperature roasting process in Zn and Pb refineries; δ⁶⁶Zn values variations in air emissions, slags and effluents from the smelters in comparison to the geogenic Zn isotopic signature of ores formation and weathering. In order to assess the environmental impact of these smelters, the available and measured δ⁶⁶Zn values are compiled for smelter impacted natural water bodies (groundwater, stream and river water), sediments (lake and reservoir) and soils (peat bog soil, inland soil). Finally, the discussion is extended to the fractionation induced during numerous physicochemical reactions and transformations, i.e. adsorption, precipitation as well as both inorganic and organic surface complexation.     

Late Oligocene–Early Miocene palaeoecology based on pollen data from the Kalkım-Gönen Basin (Northwest Turkey)

Radiometric and palynological data of the Upper Oligocene–Lower Miocene Soma Formation from the Kalk?m-Gönen Basin yield new results related to age and palynological contents. In this study, Upper Oligocene strata from the Dani?ment and Linfa areas and Lower Miocene strata from the Bengiler area were sampled palynologically and for radiometric dating. The Dani?ment assemblage, which is older than the Linfa assemblages, mainly contains coniferous and evergreen to deciduous mixed mesophytic forest elements. Relatively high quantities of the altitudinal plants Picea and Abies, indicate a cooler palaeoclimate. The Linfa associations mainly include coniferous and riparian elements. Pollen of the riparian plant Alnus and Taxodiaceae indicative for the swamp forest community was predominant, probably as a result of a high lake level. There is a hiatus during the Oligocene–Miocene transition, probably showing a non-depositional phase and sea-level fall indicating the Mi-1 glaciation event. Higher in the sequence, the Aquitanian Bengiler sediments include high amounts of coniferous forest elements as well as components indicative for the evergreen and deciduous mesophytic forest and also riparian forest and swamp forest. Due to presence of thermophilous taxa Reveesia, Mastixiaceae and Arecaceae, a warm and humid palaeoclimate is inferred according to quantitative analyses using the Coexistence Approach.     

四川盆地回龙地区下侏罗统自流井组大安寨段混积岩特征及模式

川西回龙地区自流井组大安寨段发育湖相碳酸盐岩和碎屑岩的混合沉积,结合野外露头、钻井岩芯、测井和显微组构等资料的综合分析,对该研究区混积岩沉积微相特征进行了精细刻画。研究认为,回龙地区大安寨段属湖泊混合沉积相,分为滨浅湖混合沉积和半深湖混合沉积两个亚相,并划分了五个沉积微相,分别为高能介壳滩混合沉积微相,低能介壳滩混合沉积微相,砂质浅滩混合沉积微相,浅湖混合沉积微相以及半深湖混合沉积微相。基于所划分的混合沉积相的特征和四川盆地以及研究区回龙大安寨段在侏罗纪的沉积相演变过程,分析了该区混积岩的成因及混合沉积演化模式。得出结论:研究区湖相混合沉积主要受物源供给和水动力条件的控制,在五种不同混合沉积微相控制作用下形成了不同类型的混积岩。     

鄂尔多斯盆地晚三叠世延长期古湖盆生物相带划分及地质意义

鄂尔多斯盆地晚三叠世发育大型坳陷型湖盆。湖水的升降影响着湖盆水体面积的大小、深浅以及沉积体系发育分布,进而影响全盆地晚三叠延长统地层生储盖组合的发育特征。通过野外剖面、钻井岩芯中古生物化石的鉴定,结合古生物组合特征对鄂尔多斯盆地晚三叠世湖盆的古生物生态环境进行了恢复。确定鄂尔多斯晚三叠世湖盆是一个最大水深不超过60 m的浅水湖盆,属于温暖潮湿的淡水-半咸水环境。从湖岸到湖心,可以划分为预测古水深1～2 m的河流-沼泽生物相带;预测古水深3～15 m的滨岸-河口三角洲生物相带;预测古水深15～35 m的浅湖生物相带;预测古水深在35～60 m范围的半-深湖生物相带。这些生物相带的划分,为恢复鄂尔多斯盆地晚三叠世时期的岩相古地理奠定了基础,为盆地延长组沉积边界、盆地内沉积体系发育展布以及沉积相带的划分提供了坚实的地质依据,具有理论与实际意义。     

胶莱盆地白垩系林寺山组砾岩沉积特征及盆地演化意义

胶莱盆地下白垩统莱阳群底部林寺山组主要由砾岩组成。通过对盆地及周缘18个地点林寺山组砾岩系统的调查,从砾岩组分、砾径和长轴排列方向的统计分析出发,研究该砾岩沉积相类型、盆地物源区、古水流及林寺山组上覆地层中砂岩碎屑锆石U-Pb年龄谱特点,并进一步讨论了盆地演化的意义。研究表明,林寺山组底部砾岩以冲积扇相为主,但不同地点亚、微相类型又有差异。原型胶莱盆地由莱阳、海阳-即墨和诸城-五莲3个独立盆地组成,被6个隆起区所分隔。莱阳盆地的物源主要来自胶北隆起和苏鲁造山带北部;海阳-即墨盆地以苏鲁造山带北部隆起区、即墨-牟平隆起、胶南隆起为主物源区;诸城-五莲盆地以胶南隆起和马山-李党家低隆起为主要物源区。林寺山组砾岩的出现标志着苏鲁造山带大规模塌陷和胶莱盆地的形成。     

广西凭祥盆地深水底流沉积类型及其研究意义

内波、内潮汐沉积和复合流沉积是二十余年来在古代深水环境中新发现的一种具牵引流性质的沉积相类型,由于地层沉积记录十分有限,制约了深水底流沉积的沉积学研究。大比例尺实测地质剖面和精细露头测量表明,底流沉积发育于凭祥盆地深水沉积之中,通过对其沉积构造精细剖析和古水流测量,识别出内波、内潮汐沉积和复合流沉积,其中内波、内潮汐沉积以双向交错层理、单向交错层理、透镜状层理为特征,复合流沉积以复合流层理、丘状交错层理和较陡的爬升波纹层理为特征,进一步表明存在浊流和底流的交互作用,为古代地层中的深水底流沉积提供了又一研究实例。     

成岩作用与油气侵位对砂岩铀成矿的约束--以准南硫磺沟地区头屯河组砂岩铀成矿为例

为了解准噶尔盆地南缘硫磺沟地区中侏罗统头屯河组砂岩成岩-流体演化与铀成矿响应,进而客观评价其成矿潜力。通过光薄片鉴定、X衍射、扫描电镜分析得出:目的层主要为岩屑细砂岩,依次经历了浅埋藏、深埋藏和表生-热液成岩阶段,遭受较强的机械压实、胶结及溶蚀作用。其黏土矿物以高岭石为主,碳酸盐矿物有细亮晶和泥晶两类,硅质胶结微弱,局部见细晶黄铁矿及其褐铁矿氧化产物。成岩环境可能经历了由酸性到弱碱性再到酸性,由同生期氧化-浅埋期还原-短暂抬升期氧化还原过渡-缓慢沉降期还原增强-快速抬升期氧化的演化过程。砂岩中存在较多油气包裹体;酸解总烃为5.72~449.14 μL/kg,以CH₄为主;方解石脉δ13C_V-PDB为-25‰~-6.7‰,δ18O_V-SMOW为11.1‰~18.9‰;结合野外调查认为目的层存在一期中等偏弱的后生油气侵位,从而影响了砂体的Eh及pH值。以上成岩过程及烃类流体活动使得目的层早期形成了小型层间氧化带型铀矿并得以局部保存,晚期形成了一定规模的地表潜水氧化带型铀矿体。     

泥河湾侯家窑遗址古河流及环境考古意义

侯家窑遗址位于泥河湾盆地西北部,自发现至今,历经40余年,但遗址年代和古人类生存环境问题仍悬而未决。本文基于地质地貌观测、电阻率测深、高程测量等工作,试图通过遗址区地层结构和古河流发育情况研究,阐释上述问题。结果如下:①伴随着泥河湾古湖的快速萎缩,在侯家窑遗址区发育了一条源自北部熊耳山、宽逾1 km的古河流。它形成于240 ka B.P.前,消亡于晚更新世初,发育历史贯穿了侯家窑古人类生存阶段的始终。②遗址古文化遗存不是埋藏在湖相泥河湾层中,而是埋藏于距今约224~161 ka的牛轭湖沉积层和壤化黏土层内,表明古人类在此倚河而居长达6万年。③遗址区面向东南的宽阔圈椅状地形,为古人类生存造就了相对温和舒适的地理环境;古河流既为古人类提供了水源,良好的流域生态环境也给古人类提供了富足的食物;熊耳山既是古河流源地,也是优质石料产地,古河流将石料搬运至遗址附近,石器制作便利。因此,在寒冷气候条件下生活的古人类,选择生境较好的侯家窑遗址区倚河而居势成必然。④遗址区古河流发育在易遭侵蚀的泥河湾湖相沉积层之上,河水泥沙含量高、浑浊,唯有遗址附近的牛轭湖区水流缓滞、清澈,而且植物繁茂,是各类动物优先猎食和饮水的地方。但牛轭湖独特的地貌特点,使动物们在急迫情况下难以逃脱,古人类此地围猎,远较他地成功率高。     

海-塔盆地中部断陷带南屯组沉积体系配置及有利相带分析

本文充分利用岩芯、测井、地震及分析化验等资料,对海-塔盆地中部断陷带4个主力凹陷的南屯组砂体类型及分布特征进行了详细研究。结果表明,南屯组主要发育扇三角洲、近岸水下扇、辫状河三角洲和湖底扇等4种典型类型砂体,并从沉积背景、发育部位、沉积特征、搬运机制以及地震反射特征等5个方面,分不同角度、不同层次详细阐述了扇三角洲、近岸水下扇、辫状河三角洲和湖底扇的识别标志;其中扇三角洲主要分布在乌尔逊凹陷和贝尔凹陷的陡坡带,近岸水下扇主要分布在南贝尔凹陷和塔南凹陷的陡坡带,而辫状河三角洲主要分布乌尔逊凹陷、贝尔凹陷和南贝尔凹陷的缓坡带。从盆地边部向盆地中心方向,沉积相由扇三角洲、近岸水下扇和辫状河三角洲沉积逐渐过渡为半深湖-深湖相沉积,局部半深湖-深湖相中发育湖底扇沉积体系,整体具有“南北分块、东西分带”的沉积格局。综合研究表明,扇三角洲前缘、近岸水下扇中扇和辫状河三角洲前缘砂体是油气富集的有利沉积相带,而洼槽边缘的湖底扇砂体为岩性油气藏勘探的重点对象。     

A note on “Origin of components in Chilean thermal waters” by

Risacher et al. (2011) have presented voluminous data on thermal waters of Chile that is quite appreciable; however, their work still falls short on several counts. The most notable shortcoming of the work is the presentation and treatment of data. The interpretations are based on questionable premises (viz., extent of seawater intrusion) and considerations (viz., using average chemical composition of rock types for geochemical modeling, considering volcanic rocks as the only rock type in contact with the geothermal fluids) and assumptions not always substantiated by facts (with proper references) could have been corroborated. Use of Cl/Br ratio for discrimination purpose is unconvincing, considering the uncertainty in the measurement of low (<1 mg/L) Br concentration.