Analysis of threshold and incipient conditions for sediment movement

Prediction of threshold conditions and incipient motion is the essential issue for the study of sediment transport. This work compares existing empirical threshold curves proposed for Shields diagram, a method based on the concept of probability of sediment movement, and an empirical method based on movability number. These methods are used to predict the incipient motion conditions for experimental runs taken from various studies. Most of the experimental data, used in this work, have not been used before in derivation of alternative formulations for Shields diagram and other methods. The empirical threshold curves based on the Shields entrainment function was the least successful at predicting the measured incipient motion conditions, while the use of the movability number gives good predictions of critical shear velocity compared with experimental data.     

低速十字路口交通流模型相图

研究由两个单车道构成低速十字路口交通流模型.模型中两车道上的车辆更新遵循无交通灯管制下的并行规则.依据构建相图的原则并采用局部占有概率方法,建立相图,给出相图中的各部分区域的流量表达式.两车道均采用周期边界条件和确定性FI模型进行数值模拟,模拟结果与理论分析精确一致.模型中两条车道的行车规则更接近实际道路交通,该结果为交通管理提供一定的指导作用.     

基于模糊聚类分析的莱州湾南岸地下水化学分布特征研究

针对莱州湾南岸咸水入侵区地下水质连续、渐变和边界模糊的特征,利用规格化变换对莱州湾南岸地下水化学组分数据进行标准化,采用夹角余弦法作为相似系数,用平方法计算传递闭包构造模糊等价矩阵进行模糊聚类分析,将莱州湾南岸地下水划分为3类并绘制其平面分区图.在此基础上,用探索性数据分析技术的箱线图分别识别各类地下水各组分的分位数、中位数、极值等数据分布情况,并结合 Radial 图绘制各类地下水各组分均值;利用基于 CA 舒卡列夫分类方法的 Piper三线图识别了各类地下水的水化学类型;最后在相关分析基础上选取代表性指标绘制等值线图,结合模糊聚类分区探讨了分区各指标的空间结构特征及内在机理.综合上述分析,定义玉区为海水入侵重点治理区,域区为海水入侵综合防范与整治区,芋区为卤水区.     

锂光卤石X-ray衍射标准图谱

盐湖卤水提锂过程中需了解与掌握锂元素结晶析出与赋存状态,锂光卤石(LiCl·MgCl_2·7H_2O)作为重要的中间产物,其结构与种类均需鉴别,但由于缺乏锂光卤石的X-ray衍射标准图谱,使得常见的Xray衍射方法无法应用。利用相图原理,通过湿固相法制备高纯锂光卤石,然后对其进行X-ray衍射分析,从而提供锂光卤石X-ray衍射的标准图谱,为高镁锂比盐湖卤水提锂过程分析提供可靠的理论支撑。     

基于两阶段稳定图的随机子空间识别结构模态参数

基于振动的结构健康监测的前提是从振动测试信号中提取结构模态参数。随机子空间方法是近年来发展起来的一种线性系统辨识方法,可以有效地从环境激励的结构响应信号中提取结构模态参数。在随机子空间识别方法中,确定系统的阶数是该方法的关键工作,稳定图方法是一种比较新颖的确定系统阶次的方法。但是随机子空间方法容易产生虚假模态,这也是随机子空间方法的一个主要缺陷。因此针对于这一缺陷提出了一种基于两阶段稳定图的随机子空间识别结构模态参数方法,该方法的基本思想是将在现场采集的结构的输出信号进行分段,将各段信号用随机子空间结合稳定图进行识别,然后将所有各段所识别的模态参数再一次用稳定图方法进行分析,得出结构的模态参数。最后用一三跨连续梁的数值模型对该方法进行验证,结果表明该方法具有良好的识别效果。     

An automated strategy for calculation of phase diagram sections and retrieval of rock properties as a function of physical conditions

We formulate an algorithm for the calculation of stable phase relations of a system with constrained bulk composition as a function of its environmental variables. The basis of this algorithm is the approximate representation of the free energy composition surfaces of solution phases by inscribed polyhedra. This representation leads to discretization of high variance phase fields into a continuous mesh of smaller polygonal fields within which the composition and physical properties of the phases are uniquely determined. The resulting phase diagram sections are useful for understanding the phase relations of complex metamorphic systems and for applications in which it is necessary to establish the variations in rock properties such as density, seismic velocities and volatile‐content through a metamorphic cycle. The algorithm has been implemented within a computer program that is general with respect to both the choice of variables and the number of components and phases possible in a system, and is independent of the structure of the equations of state used to describe the phases of the system.     

The chemical changes of DOM from black waters to coastal marine waters by HPLC combined with ultrahigh resolution mass spectrometry

How dissolved organic matter (DOM) undergoes chemical changes during its transit from river to ocean remains a challenge due to its complex structure. In this study, DOM along a river transect from black waters to marine waters is characterized using an offline combination of reversed-phase high performance liquid chromatography (RP-HPLC) coupled to electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS), as well as tandem ESI-FTICR-MS. In addition, a water extract from degraded wood that mainly consists of lignins is used for comparison to the DOM from this transect. The HPLC chromatograms of all DOM samples and the wood extract show two major well-separated components; one is hydrophilic and the other is hydrophobic, based on their elution order from the C₁₈ column. From the FTICR-MS analysis of the HPLC fractions, the hydrophilic components mainly contain low molecular weight compounds (less than 400 Da), while the hydrophobic fractions contain the vast majority of compounds of the bulk C₁₈ extracted DOM. The wood extract and the DOM samples from the transect of black waters to coastal marine waters show strikingly similar HPLC chromatograms, and the FTICR-MS analysis further indicates that a large fraction of molecular formulas from these samples are the same, existing as lignin-like compounds. Tandem mass spectrometry experiments show that several representative molecules from the lignin-like compounds have similar functional group losses and fragmentation patterns, consistent with modified lignin structural entities in the wood extract and these DOM samples. Taken together, these data suggest that lignin-derived compounds may survive the transit from the river to the coastal ocean and can accumulate there because of their refractory nature.     

A ternary solid solution model for omphacite and its application to geothermobarometry of eclogites from the Middle Adula nappe (Central Alps, Switzerland)

A ternary solid solution model for omphacite with the end-members jadeite (NaAlSi₂O₆), diopside (CaMgSi₂O₆) and hedenbergite (CaFeSi₂O₆) was derived from experimental data from the literature. The subregular solution model, fitted by linear programming, is best suited to omphacites with very little aegirine component in common eclogites. Applying this solution model to the calculation of equilibrium phase diagrams of eclogites from the Adula nappe (Central Alps, Switzerland) results in large stability fields for common eclogite assemblages (garnet+omphacite+quartz+H₂O±kyanite). Within this field the compositions of garnet and omphacite show very little variation. A precise determination of the peak-pressure and temperature is not possible. The occurrence of amphibole, overgrowing the peak-pressure assemblage in fresh eclogite, suggests retrograde re-equilibration, still under eclogite facies conditions. The computation of isopleths for garnet and pyroxene end-members allows the estimation of the pressure and temperature conditions of this re-equilibration event (19–21  kbar, c .  700 °C).     

硅灰石、透辉石在陶瓷中的基本反应和作用

本文以硅灰石和高岭石、透辉石和高岭石为端元组分,推导了二元假相图。根据这两个假相图,提出了四个基本固相反应。用这些基本反应以及硅灰石、透辉石的矿物学性质,说明了它们对陶瓷坯体工艺性能的作用。