Stormflow concentration–discharge dynamics of suspended sediment and dissolved phosphorus in an agricultural watershed

Concentration–discharge (C-Q) relationships are an effective tool for identifying watershed biogeochemical source and transport dynamics over short and long timescales. We examined stormflow C-Q, hysteresis, and flushing patterns of total suspended sediment (TSS) and soluble reactive phosphorus (SRP) in two stream reaches of a severely impaired agricultural watershed in northeastern Wisconsin, USA. The upper watershed reach—draining a relatively flat, row crop-dominated contributing area—showed predominantly anti-clockwise TSS hysteresis during storms, suggesting that particulate materials were mobilized more from distal upland sources than near- and in-channel areas. In contrast, the incised lower watershed reach produced strong TSS flushing responses on the rising limb of storm hydrographs and clockwise hysteresis, signalling rapid mobilization of near- and in-channel materials with increasing event flows. C-Q relationships for SRP showed complex patterns in both the upper and lower reaches, demonstrating largely non-linear chemodynamic C-Q behaviour during events. As with TSS, anti-clockwise SRP hysteresis in the upper reach suggested a delay in the hydrologic connectivity between SRP sources and the stream, with highly variable SRP concentrations during some events. A broad range of clockwise, anti-clockwise, and complex SRP hysteresis patterns occurred in the lower watershed, possibly influenced by in-channel legacy P stores and connection to tile drainage networks in the lower watershed area. Total suspended sediment and SRP responses were also strongly related to precipitation event characteristics including antecedent precipitation, recovery period, and precipitation intensity, highlighting the complexity of stormflow sediment and phosphorus responses in this severely impaired agricultural stream.     

Tropical precipitation anomalies and d‐excess evolution during El Niño 2014‐16

The last 2014‐16 El Niño event was among the three strongest episodes on record. El Niño considerably changes annual and seasonal precipitation across the tropics. Here, we present a unique stable isotope data set of daily precipitation collected in Costa Rica prior to, during, and after El Niño 2014‐16, in combination with Lagrangian moisture source and precipitation anomaly diagnostics. δ²H composition ranged from ‐129.4 to +18.1 (‰) while δ¹⁸O ranged from ‐17.3 to +1.0 (‰). No significant difference was observed among δ¹⁸O (P=0.186) and δ²H (P=0.664) mean annual compositions. However, mean annual d‐excess showed a significant decreasing trend (from +13.3 to +8.7 ‰) (P<0.001) with values ranging from +26.6 to ‐13.9 ‰ prior to and during the El Niño evolution. The latter decrease in d‐excess can be partly explained by an enhanced moisture flux convergence across the southeastern Caribbean Sea coupled with moisture transport from northern South America by means of an increased Caribbean Low Level Jet regime. During 2014‐15, precipitation deficit across the Pacific domain averaged 46% resulting in a very severe drought; while a 94% precipitation surplus was observed in the Caribbean domain. Understanding these regional moisture transport mechanisms during a strong El Niño event may contribute to a) better understanding of precipitation anomalies in the tropics and b) re‐evaluate past stable isotope interpretations of ENSO events in paleoclimatic archives within the Central America region.     

The Upstream “Strong Signals” of the Water Vapor Transport over the Tibetan Plateau during a Heavy Rainfall Event in the Yangtze River Basin

A heavy rainfall event that occurred over the middle and lower reaches of the Yangtze River Basin(YRB) during July11–13 2000 is explored in this study. The potential/stream function is used to analyze the upstream "strong signals" of the water vapor transport in the Tibetan Plateau(TP). The studied time period covers from 2000 LST 5 July to 2000 LST 15 July(temporal resolution: 6 hours). By analyzing the three-dimensional structure of the water vapor flux, vorticity and divergence prior to and during the heavy rainfall event, the upstream "strong signals" related to this heavy rainfall event are revealed. A strong correlation exists between the heavy rainfall event in the YRB and the convective clouds over the TP. The "convergence zone" of the water vapor transport is also identified, based on correlation analysis of the water vapor flux two days and one day prior to, and on the day of, the heavy rainfall. And this "convergence zone" coincides with the migration of the maximum rainfall over the YRB. This specific coupled structure actually plays a key role in generating heavy rainfall over the YRB. The eastward movement of the coupled system with a divergence/convergence center of the potential function at the upper/lower level resembles the spatiotemporal evolution of the heavy rainfall event over the YRB. These upstream "strong signals" are clearly traced in this study through analyzing the three-dimensional structure of the potential/stream function of upstream water vapor transport.     

Long-Term Variability of the Wind Field over the Indian Ocean Based on ERA-Interim Reanalysis

A detailed study of long-term variability of winds using 30 years of data from the European Centre for Medium-range Weather Forecasts global reanalysis (ERA-Interim) over the Indian Ocean has been carried out by partitioning the Indian Ocean into six zones based on local wind extrema. The trend of mean annual wind speed averaged over each zone shows a significant increase in the equatorial region, the Southern Ocean, and the southern part of the trade winds. This indicates that the Southern Ocean winds and the southeast trade winds are becoming stronger. However, the trend for the Bay of Bengal is negative, which might be caused by a weakening of the monsoon winds and northeast trade winds. Maximum interannual variability occurs in the Arabian Sea due to monsoon activity; a minimum is observed in the subtropical region because of the divergence of winds. Wind speed variations in all zones are weakly correlated with the Dipole Mode Index (DMI). However, the equatorial Indian Ocean, the southern part of the trade winds, and subtropical zones show a relatively strong positive correlation with the Southern Oscillation Index (SOI), indicating that the SOI has a zonal influence on wind speed in the Indian Ocean. Monsoon winds have a decreasing trend in the northern Indian Ocean, indicating monsoon weakening, and an increasing trend in the equatorial region because of enhancement of the westerlies. The negative trend observed during the non-monsoon period could be a result of weakening of the northeast trade winds over the past few decades. The mean flux of kinetic energy of wind (FKEW) reaches a minimum of about 100?W?m^?2 in the equatorial region and a maximum of about 1500?W?m^?2 in the Southern Ocean. The seasonal variability of FKEW is large, about 1600?W?m^?2, along the coast of Somalia in the northern Indian Ocean. The maximum monthly variability of the FKEW field averaged over each zone occurs during boreal summer. During the onset and withdrawal of monsoon, FKEW is as low as 50?W?m^?2. The Southern Ocean has a large variation of about 1280?W?m^?2 because of strong westerlies throughout the year.     

敦密断裂带白垩纪两期重要的变形事件

本文报道了敦密断裂带糜棱岩中黑云母~(40)Ar/~(39)Ar定年结果和大规模走滑-逆冲断裂的几何学、运动学特征及其形成时代,以便揭示断裂带两期变形事件的构造属性。黑龙江省密山市花岗质糜棱岩中黑云母~(40)Ar/~(39)Ar加权平均年龄为132.2±1.2Ma,它是敦密断裂带经历伸展事件的冷却年龄,也是东北亚大陆边缘在早白垩世Hauterivian期-Albian期发生强烈区域伸展作用的产物。密山市至辽宁省清原县系列大型走滑-逆冲断层和断层相关褶皱揭示出在晚白垩世晚期-末期发生右旋走滑-逆冲事件,该事件规模大,影响范围广,导致整个断裂带遭受到强烈改造,形成对冲式断裂系统。将研究区走滑-逆冲断裂与山东省郯庐断裂带中段挤压构造对比,认为郯庐断裂带北段和中段在晚白垩世末期都发生了强烈的走滑-逆冲事件,它们具有相同的构造特征和构造属性。     

Oil dispersal modelling: reanalysis of the Rena oil spill using open-source modelling tools

ABSTRACT

Oil spill forecast modelling is typically used immediately after a spill to predict oil dispersal and promote mobilisation of more effective response operations. The aim of this work was to map oil dispersal after the grounding of the MV Rena on Astrolabe Reef and to verify the results against observations. Model predictions were broadly consistent with observed distribution of oil contamination. However, some hot spots of oil accumulation, likely due to surf-zone and rip current circulation, were not well represented. Additionally, the model was run with 81 differing wind conditions to show that the events occurring during the grounding represented the typical likely behaviour of an oil spill on Astrolabe Reef. Oil dispersal was highly dependent on prevailing wind patterns; more accurate prediction would require better observations of local wind patterns. However, comparison of predictions with observations indicated that the GNOME model was an effective low-cost approach.     

西太平洋暖池热盐结构盐度场变异的主模态

基于1950~2011年间的月平均温、盐度资料,以28℃等温线作为西太平洋暖池的定义标准,并取ΔT=-0.4℃,分别计算了暖池区(20°N~15°S,120°E~140°W)各格点混合层、障碍层和深层的平均盐度,构成了暖池热盐结构的盐度场.据此,运用EOF分解法分析了暖池热盐结构盐度距平场主要模态的变化特征及其与ENSO间的关系,并探讨了主要模态的年际变异机理.结果表明,暖池热盐结构盐度场第一模态揭示了盐度场变异的关键区位于暖池中部;该模态具有2~4a的年际变化和准10a的年代际变化,并在1977年前后经历了一次气候跃变(此外,深层盐度场第一模态还在1999年前后发生了一次气候跃变),且在跃变前后与不同类型的ENSO事件有较密切的联系.暖池中部混合层和障碍层盐度的变化比较一致,即在跃变前盐度为偏高期,而在跃变后则变为偏低期.暖池中部深层盐度在1977年以前和1999年之后皆处于偏高期,而在1978~1999年间则处于偏低期.而且,从混合层至深层,盐度的变化幅度逐渐变小.进一步分析表明,暖池中部混合层和障碍层盐度的年际变化主要是由纬向风、南赤道流(SEC)和降水共同引起的,即当东风增强(减弱)时,强(弱)SEC将携带更多(少)的高盐水进入混合层或潜沉至障碍层,同时局地降水的减少(增多),也使得混合层和障碍层的盐度增加(减少);深层盐度的年际变化主要是由SEC和赤道潜流(EUC)导致的,即当SEC增强(减弱)时,将有更多(少)的高盐水进入暖池,而当EUC增强(减弱)时则有更多(少)的低盐水流出暖池,从而使得暖池的深层盐度升高(降低).     

Occurrence and Chemical Compositions of Amphiboles in Altered Dioritic Rocks of Laiwu Skarn‐Type Iron Deposit in West Shandong Area,China

The Laiwu Fe deposit is the largest skarn‐type deposit in West Shandong in China, with an estimated reserve of 290 Mt of iron ore. Here, we investigate the occurrence and chemical composition of amphiboles in altered dioritic rocks of this deposit. Three generations of amphibole group minerals were identified in these rocks. The first type (Type 1) is a hornblende with a generally euhedral crystal shape, 150–500 μm in size, and dominantly occurs in the host monzonite. The second type (Type 2) of hornblende occurs as fine grains (<100 μm) or concentric rims, less than 50 μm in thickness, around the Type 1 hornblende. The third type (Type 3) of amphibole is anhedral actinolite occurring along the boundary or the cracks of the Type 1 or 2 hornblende grains. The Type 1 hornblende has higher FeO (12.5–15.6 wt.%) and lower MgO contents (11.2–14.6 wt.%) than the Type 2 hornblende, which has an FeO content ranging from 8.8 to 10.5 wt.% and MgO content ranging from 14.2 to 17.1 wt.%. The Type 3 actinolite shows the lowest FeO (4.6–6.4 wt.%) and highest MgO (19.8–21.2 wt.%) contents. We infer that the Type 2 hornblende formed from Fe‐rich hydrothermal fluids released during rapid upwelling of the crystallizing magma. The fluids were relatively reduced and enriched in Fe. The Type 3 actinolite formed by coupled dissolution and reprecipitation, and its formation is one of the features denoting Fe‐enrichment events. Our study of these types of amphibole provides insights into the ore formation process.     

辽南新元古代桥头组海相冰碛沉积事件

通过对辽南瓦房店市岳山地区详细的野外地质调查,在桥头组中首次发现两处冰筏坠石冰碛沉积现象。坠石大小不等,均呈椭球倒锥状,磨圆较好,岩性分别为灰褐色细粒石英砂岩和黄褐色铁质胶结细粒石英砂岩,寄主围岩岩性为黄绿色粉砂质页岩且环绕坠石沉积,两者岩性差别较大,界线清晰。另外在桥头组中采集的碎屑锆石最小~(206)Pb/~(238)U年龄为662±16 Ma(~(207)Pb/~(206)Pb年龄为884±28 Ma),可以推断桥头组形成晚于800 Ma,应为新元古代中晚期沉积产物。根据以上证据及层序学资料,笔者把辽宁地区出露的桥头组、长岭子组(康家组)厘定为辽宁地区第二次冰碛事件,形成时代确定为新元古代中北方世(南华世)。