二价铁氧化对铁锰循环功能微生物活性的影响及机制

地质微生物是沉积环境中铁、锰氧化还原循环的主要驱动因子,铁锰共存环境中二价铁氧化对不同铁、锰循环功能微生物活性的影响差异和机制尚不清楚.以铁还原菌Shewanella oneidensis MR-1、铁氧化菌Pseudogulbenkiania sp.strain 2002、锰氧化菌Pseudomonas putida MnB1和Leptothrix discophora SS-1作为代表性的铁、锰循环功能微生物,利用平板计数、荧光显微镜等手段探究了Fe(II)氧化对功能微生物活性的影响差异及机制.结果表明0.05 mM Fe2+氧化60 min可使MR-1和MnB1的活菌数量降低4~5个数量级,SS-1及S.2002无显著失活.Fe(II)氧化产生的吸附态。OH和胞内。OH是细菌失活的主要原因,胞外H₂O₂、胞外游离态。OH和三价铁氧化物是细菌失活的次要原因,SS-1及S.2002产生了氧化应激反应,成功抵御了活性氧化物种.      

ASTER mapping of gypsum deposits of Thumrait region of southern Oman

This study demonstrates the use of ASTER data for the mapping of gypsum deposits and associated geological formations that occurred in the Thumrait region of southern Oman. The measurement of spectra over samples of gypsum in the 1,300–2,500 nm wavelength using a PIMA spectrometer showed the presence of distinct absorptions at 1400–1600, 1750, 1940, 2,100, and 2,400 nm characteristics to O? H stretching, H₂O combinations, and S? O bending overtones and stretching, respectively. Studying the unique spectral absorption characters of gypsum samples, we developed a false color composite (FCC) and an image by decorrelation stretch using the spectral bands 7, 3, and 2 of ASTER. The results FCC showed the regions of gypsum occurrences, and the decorrelated image discriminated the gypsum occurrences from other geological formations of the area. The study of surface mineralogy of the region using the VNIR‐SWIR bands by the spectral angle mapper method showed the presence of sulfate, carbonate, and clay minerals of the geological formations in the study area. We compared the results of ASTER with the results obtained using spectral bands 12, 8, and 4 of Sentinel‐2A processed by the same methods. The study showed that the spectral bands of ASTER can be used for mapping the gypsum and associated geological formations.     

国内外CO2地质封存潜力评价方法研究现状

碳捕集与封存(Carbon Capture and Storage,CCS)技术作为缓解全球气候变暖、减少CO₂排放的有效路径之一,其潜力评估至关重要。目前CCS技术主要包括CO₂强化石油(天然气)开采封存技术、CO₂驱替煤层气封存技术以及咸水层CO₂封存技术3类。各类封存技术利用了不同的封存机制,其潜力评估方法也略有差别。油气藏封存和咸水层封存主要利用了构造圈闭储存、束缚空间储存、溶解储存、矿化储存等封存机制,煤层气封存主要利用了吸附封存机制。国内外学者和机构针对各类封存技术提出了相应的计算方法,依据其计算原理可归纳为4类: 物质平衡封存量计算法、有效容积封存量计算法、溶解机制封存量计算法以及考虑多种捕获机制的综合封存量计算法。通过对各类经典方法及其计算原理进行综述,剖析潜力封存量计算方法的内涵原理和应用场景,分析了CO₂地质封存潜力评价方法在实际应用中面临的问题,有助于提升我国的CCS潜力评价质量。     

鄂尔多斯盆地CO2地质封存适宜性与潜力评价

针对目前利用层次分析法对CO₂地质封存进行适宜性评价过程中,极少结合研究区域实际计算低层次评价指标权重,对适宜性评价结果又缺少进一步的分析,结合鄂尔多斯盆地的地质特征,通过计算指标组成权重和适宜性得分对盆地开展了CO₂地质封存适宜性评价,并以适宜区杏子川油田长4+5盖层为例,开展了盖层封闭性评价实验研究。同时,采用相应的计算方法对鄂尔多斯盆地深部咸水层和油藏的CO₂地质封存潜力进行了计算。结果表明：鄂尔多斯盆地在三叠系开展CO₂地质封存的适宜性最好,石炭-二叠系和奥陶系则次之;杏子川油田三叠系延长组长4+5盖层对区域开展CO₂地质封存具备良好的封闭性;鄂尔多斯盆地深部咸水层和油藏的CO₂有效封存量分别为1.33×10 ¹⁰ t和1.91×10 ⁹ t,且在延长石油吴起、靖边及杏子川油田共有56个CO₂地质封存适宜区,其CO₂有效封存量可达1.77×10 ⁸ t。     

模式内部变率引起的1.5℃和2℃升温阈值出现时间模拟的不确定性研究

模式内部变率是模拟结果不确定性的重要来源,然而它对于1.5℃和2℃升温阈值出现时间不确定性的影响尚不清楚。因此,基于耦合模式比较计划第五阶段(CMIP5)的多模式数据研究了模式内部变率对1.5℃和2℃升温阈值出现时间不确定性的影响以及对未来排放情景的敏感性。结果表明,模式内部变率对升温阈值出现时间模拟的影响与外强迫的影响相当,单个模式内部不同成员达到全球平均1.5℃或2℃增温的年份相差2~12年;其影响具有明显的空间差异,影响极大值出现在欧亚大陆以北洋面、白令海峡周围区域、北美东北部及其与格陵兰岛之间的海域、南半球高纬地区等;低排放情景下模式内部变率的影响大于高排放情景。     

An Operational Precipitable Water Vapor Retrieval Algorithm for Fengyun-2F/VISSR Using a Modified Three-Band Physical Split-Window Method

The Visible and Infrared Spin-Scan Radiometer(VISSR) onboard the Fengyun-2(FY-2) satellite can provide valuable thermal infrared observations to help create a precipitable water vapor(PWV) product with high spatial and temporal resolutions. The current FY-2/VISSR PWV product in operation is produced by using a traditional two-band physical split-window(PSW) method, which produces low quality results under dry atmospheric conditions. Based on the sensitivity characteristics of FY-2 F/VISSR water vapor channel and two split-window channels to atmospheric water vapor, this study developed a new, robust operational PWV retrieval algorithm for FY-2 F to improve the operational precision of the current PWV product. The algorithm uses a modified three-band PSW method, which adds a scale for the water vapor channel in the improved three-band PSW method. Integrated PWV products from the radiosonde data in 2016 are used here to validate the precision of the PWV retrieved by the modified three-band and traditional two-band PSW methods. The mean bias, root mean square error(RMSE), and correlation coefficient of the PWV retrieved by the modified three-band PSW method are 0.28 mm, 4.53 mm, and 0.969, respectively. The accuracy is much better than the PWV retrieved by the two-band method, whose mean bias, RMSE, and correlation coefficient are 12.67 mm, 29.35 mm, and 0.23. Especially, in mid-or high-latitude regions, the RMSE of the PWV is improved from 10 to 2 mm by changing the inversion in the two-band method to the modified three-band PSW method. Furthermore, the modified three-band PSW results show a better consistency with the radiosonde PWV at any zonal belt and season than the two-band PSW results. This new algorithm could significantly improve the quality of the current FY-2 F/VISSR PWV product, especially at sites where the actual PWV are lower than 15 mm.     

NUMERICAL PREDICTION OF AN EXTREME RAINSTORM OVER THE PEARL RIVER DELTA REGION ON 7 MAY 2017 BASED ON WRF-ENKF

An ensemble Kalman filter based on the Weather Research and Forecasting Model (WRF-EnKF) is used to explore the effectiveness of the assimilation of surface observation data in an extreme local rainstorm over the Pearl River Delta region on 7 May 2017. Before the occurrence of rainstorm, the signals of weather forecasts in this case are too weak to be predicted by numerical weather model, but the surface temperature over the urban area are high. The results of this study show that the wind field, temperature, and water vapor are obviously adjusted by assimilating surface data of 10-m wind, 2-m temperature, and 2-m water vapor mixing ratio at 2300 BST 6 May, especially below the height of 2 km. The southerly wind over the Pearl River Delta region is enhanced, and the convergence of wind over the northern Guangzhou city is also enhanced. Additionally, temperature, water vapor mixing ratio and pseudoequivalent potential temperature are obviously increased over the urban region, providing favorable conditions for the occurrence of heavy precipitation. After assimilation, the predictions of 12-h rainfall amount, temperature, and relative humidity are significantly improved, and the rainfall intensity and distribution in this case can be successfully reproduced. Moreover, sensitivity tests suggest that the assimilation of 2-m temperature is the key to predict this extreme rainfall and just assimilating data of surface wind or water vapor is not workable, implying that urban heat island effect may be an important factor in this extreme rainstorm.     

利用FY-2F快速扫描资料分析对流初生阶段的云顶物理量特征

基于FY-2F静止气象卫星提供的2015年5—9月的高分辨率数据,通过温度阈值法识别出深、浅对流后,分析和比较了深、浅对流在对流初生(convective initiation,CI)至发展阶段中云顶高度、云顶快速降温率(cloud top cooling rate,CTC)以及多通道差值等云顶物理量特征的变化异同。结果表明:深、浅对流在CI阶段的云顶物理量特征具有相似变化特征,即云顶高度均在短时间内快速上升,CTC值均先减小后增大;深、浅对流差异表现为深(浅)对流云顶上升高度能(不能)超越水汽层高度;深对流CTC最低值较浅对流CTC最低值更低。基于CI阶段深、浅对流的CTC最低值的差异,通过个例验证,表明利用深、浅对流CTC最低值的差异,可以在识别出CI的基础,判断出CI是否发展成为深对流,从而能提前做出预警。     

基于模糊熵的GLLE熵阈值分割方法

图像分割是计算机视觉中基础且重要的一个问题.熵阈值图像分割作为一种有效的分割方法,被广泛应用于模式识别和图像处理中.传统的图像分割方法并不能获得足够有效的图像特征.为解决这个问题且进一步探究熵阈值在图像分割中的应用,引入一种GLLE（Gray Level and Local Entropy）二维直方图改进熵阈值图像分割模型,并提出了基于模糊熵的方法计算所建立的二维直方图模型.通过标准实验数据集上的对比实验表明,基于模糊熵的GLLE熵阈值分割方法可以得到更加准确的阈值,提高了分割精度.同时在处理不同类型图像的表现上优于往常的算法,具有更强的鲁棒性.     

柱撑蛭石吸附去除废水中重金属离子的实验研究

分别利用有机柱化剂十二烷基磺酸钠(SDS)和无机柱化剂聚羟基铝(HA)对蛭石进行柱撑制得十二烷基磺酸钠柱撑蛭石(SDS-V erm icu lite)和聚羟基铝柱撑蛭石(HA-V erm icu lite),并通过XRD、红外光谱、ZETA电位等表征手段对柱撑蛭石进行表征,同时针对柱撑蛭石对Cu2 ,Cd2 ,C r3 3种重金属离子的吸附进行研究,结果表明:吸附去除率受反应时间、重金属离子的初始浓度、pH值等因素的影响,经柱撑后的蛭石对重金属离子吸附的吸附性能比蛭石原矿要强。柱撑蛭石吸附3种重金属离子的动力学吸附过程可用E lov icb方程和双常数方程进行较好的拟合。