太原冬季PM2.5中有机碳和元素碳的变化特征

2005年12月—2006年2月在太原市区持续观测了气溶胶细粒子PM_2.5, 并应用Sunset碳分析仪进行了有机碳 (organic carbon, OC) 和元素碳 (elemental carbon, EC) 的测定。结果表明:太原冬季PM_2.5, OC和EC浓度均较高, 其中PM_2.5日平均浓度变化范围为25.4~419.0 μg/m3, 日平均浓度为193.4±102.3 μg/m3, OC平均浓度为28.9±14.8 μg/m3, EC平均浓度为4.8±2.2 μg/m3, OC/EC平均比值是7.0±3.9, 即太原市冬季PM_2.5和碳气溶胶污染严重。OC在PM _2.5中占18.6%, EC占2.9%, 这表明碳气溶胶是太原大气细粒子污染控制的关键组分。在太原市冬季, 采暖燃烧的煤是OC和EC的主要贡献源, 造成OC大大高于EC, 从而使OC/EC比值增大。各种气象条件对PM_2.5, OC, EC和OC/EC比值的变化都有不同程度的影响, 特别是大雾天气、相对湿度、风速和降雪是影响碳气溶胶浓度变化的重要因素。     

Impact of regional geology, land use and flow path on stream water chemistry in a small watershed

Stream water chemistry is dependent on the physical, chemical and biological processes occurring in the watershed. Understanding the governing mechanism of the stream water chemistry in a watershed is the first step for the water quality management. The study area drains a total catchment area of 1.46 km^2 and consists of forest （80%）, upland （15%） and rice paddy field （5%）. The studied area has two distinctive bedrocks, quartzite and schist. We periodically collected the stream water samples at mainstream and tributaries and the pH, electrical conductivity （EC）, alkalinity and the concentrations of cations and anions of the collected stream water samples were determined in the field and laboratory. The all collected water samples were nearly neutral and the EC and concentrations of Na, K, Ca, Sr, Si and HCO3 of the stream water samples collected from the schist terrain had greater values than those from the quartzite terrain. The mainstream running along the boundary of schist and quartzite terrains had the intermediate values of the tributaries. The stream water samples collected in and near the upland showed a high concentration of NO3^- than those of forest regardless the lithology. The stream pathway was also directly reflected on the chemistry of stream water. The stream water drained in the forest of quartzite terrain had the lowest values of alkalinity, EC and concentrations of cations and anions but the stream water drain in the upland of schist terrain had the highest values of EC and concentrations of cations and anions, especially NO3^-.     

多道面波分析方法在测量土壤压实度方面的应用研究

在农业和工程领域，土壤压实度是一个重要问题。虽然采用钻孔方法可以探测土壤压实度情况，但费用较高。本文采用多道面波分析方(MASW)研究了土壤压实度的问题，并将试验结果同电阻率测井数据、岩心数据、测井速度做了对比，结果表明该方法可以用于土壤压实度的探测，而且速度快、费用低、结果准确可信。     

基于球谐函数区域电离层模型建立

利用GPS双频观测数据建立高精度、准实时的区域电离层总电子含量(TEC)模型是电离层研究的一个重要手段。文中探讨IGS观测站数据结合4阶球谐函数建立区域电离层格网模型的方法,并对硬件延迟(DCB)和TEC建模结果的可靠性进行分析,结果表明,DCB解算精度在0.4ns以内,TEC内外精度优于1.4TECU(1TECU=1016电子数/m2)和1.5TECU,满足导航定位中电离层改正的需要。     

数值预报产品检验和评估

通过国家级数值预报T213模式、EC模式下发产品对影响海南的热带气旋主观性检验结果表明,T213模式不管是对稳定路径还是转折路径的热带气旋在生成、移动路径以及登陆点都与实况相差很大;而EC模式对不管是转折还是稳定路径的热带气旋,都能够对移动路径、登陆点以及转折点都能够做出准确的预报;而在客观性检验的结果中也可看出T213模式和EC模式的预报能力的优劣性。因此,总体来说,在热带气旋的数值预报产品中,EC模式的预报能力明显比T213模式强,具有很高的参考意义。另外在温度场的预报中,T213模式相对于MM5模式,其预报能力具有一定的可信度,在日常预报中具有参考价值。     

Integrative assessment of organotin contamination in a southern European estuarine system (Ria de Aveiro, NW Portugal): tracking temporal trends in order to evaluate the effectiveness of the EU ban

Organotin (OT) compounds have been used as biocide agents in antifouling paints since the mid 1960s and are now ubiquitous in the marine environment. Due to their high toxicity to non-target species they were banned from antifouling paints in the European Union in 2003 (2002/62/EC directive). The aim of the present work is to assess any obvious decline of the OT environmental levels at Ria de Aveiro (NW Portugal) after the ban. The organotins - monobutyltin (MBT), dibutyltin (DBT), tributyltin (TBT), monophenyltin (MPT), diphenyltin (DPT), triphenyltin (TPT), monoctyltin (MOT), dioctyltin (DOT) and trioctyltin (TOT) - were quantified in the gastropod Nassarius reticulatus, in the mussel Mytilus galloprovincialis and in sediments. Imposex (imposition of male characters on females of gonochorist gastropods) in N. reticulatus was additionally used as a biomarker of TBT pollution. Time comparisons show a slight decrease of imposex between 2003 and 2005 probably as a consequence of the EU ban, though in some cases this trend seems to have started earlier since 2000. The fraction of TBT relatively to its metabolites has been decreasing over the last years but still remains high suggesting that there are still recent inputs of this compound into the study area.     

埃玛图状态曲线和几个特殊指标的其他算法

文章阐述了另外一种温度对数压力图(Emagram)制作方法,根据该方法对状态曲线以及对流有效位能(CAPE)、对流抑制能量(CIN)、自由对流高度(LFC)和平衡高度(EC)进行了计算。     

地基GPS与掩星联合的电离层层析成像方法研究

由于有限视角、稀疏布站等原因,地基G PS电离层层析成像存在垂直分辨率不高的问题,联合掩星进行电离层层析成像是一个重要的解决途径。一方面地基G PS观测能保证电离层层析成像的时间连续性和区域覆盖性;另一方面由于掩星信号能够提供地基G PS没有的水平射线信息,提升了电离层层析成像的垂直分辨率水平。利用地基GPS站与COSMIC卫星的掩星观测进行的仿真结果表明：与仅利用地基G PS相比,联合掩星进行电离层层析成像,不仅在电离层电子密度反演精度方面有明显提升,而且在电离层F2层峰值高度（hm F2）和电离层总电子含量（T EC ）的精度方面同样有明显提高。     

乐山寒潮客观预报及其效果检验分析

本文对＂基于EC产品的乐山寒潮预报系统＂的预报原理进行了介绍;并对2005年10月~2014年4月该预报系统的使用效果、预报准确率和误差进行了详细的分析,对预报工具和集体预报的预报情况进行了对比分析。结果表明,该寒潮预报系统具有较好的可用性和有效性,有利于提高寒潮以及强降温天气过程的预报能力。     

WRF、EC和T639模式在福建沿海冬半年大风预报中的检验与应用

基于福建省冬半年沿海和港湾岛屿自动站的逐时极大风观测资料和WRF(Weather Research and Forecast)、EC(European Centre for Medium-Range Weather Forecasts)细网格以及T639(TL639L60)三种模式预报的10 m 风场资料, 将模式预报的风向风速与观测资料进行对比检验, 结果表明: 福建省沿海冬半年大风的盛行风向以东北风为主, 大风的时空分布极为不均, 沿海风力的脉动性、跳跃性、局地性突出。从三种模式对风速风向的模拟效果来看, WRF 和EC 细网格的预报效果较好, 有可参考性, T639可参考性不高。对于风速, 模式预报结果相比实况极大风速偏小, 港湾岛屿代表站风速的平均绝对误差均小于沿海代表站, 预报平均误差由沿海向内陆逐渐减小, 由中部向南北逐渐减小。风向相比风速的预报效果要差, WRF 和EC 细网格的风向预报误差在45°～50°, 有一定的参考意义; 港湾岛屿代表站风向的平均绝对误差大于沿海代表站, 以浮标站的误差最大。当观测风速出现7 级及以上风速时, 若对大风进行分级检验, 则较低风速的预报平均绝对误差小于较高风速; 风向预报的平均绝对误差也大大降低, 且误差都在45°以内, 具有良好的参考性。