石煤钒矿成分分析标准物质的研制

石煤钒矿资源的开发和合理利用需要对其成分进行准确的分析测试和质量控制.目前,国内外尚未有石煤钒矿成分分析的标准物质,现有钒成分分析标准物质无论是其五氧化二钒含量,还是定值成分都无法满足我国对石煤钒矿勘查、开发和研究需要.本文对采自湖北省崇阳县小源冲钒矿、湖南省芷江县牛牯坪钒矿、湖南省古丈县岩头寨钒矿和湖南省凤凰县黑冲钒...     

科尔沁湿草甸参考作物蒸散发模拟分析

为探明气候变化下干旱半干旱地区湿草甸参考作物蒸散发(ET₀)影响因子,使用FAO 56 P-M模型对科尔沁湿草甸ET₀进行模拟,利用涡度相关系统对模型的适用性进行评价,并通过通径分析及指标敏感性分析对ET₀的影响因子进行辨识。结果表明:(1)小时尺度模拟精度最高,日尺度次之,月尺度较差,小时尺度上晴、阴、雨3种天气条件下模拟效果不同,晴天最优,阴雨天较差。(2)ET₀年内变化呈单峰曲线状,生长季明显高于非生长季,集中在3—10月,占全年89.79%。生长季典型晴天ET₀逐小时分布特征遵循倒“U”单峰型变化规律。(3)通径分析结果显示,对ET₀的通径系数以及对回归方程估测可靠程度E的总贡献均表现为VPD(饱和水汽压差) > T_min(最低气温) > R_n(冠层表面净辐射)>u₂(2 m高度风速),即VPD为影响ET₀最重要的因子;指标敏感性分析中,在去除VPD后引起的E变化最大,说明ET₀对VPD的变化最为敏感,其次为u₂、T_min和R_n。     

长距离GPS/BDS参考站网多频载波相位整周模糊度解算方法

长距离网络RTK是实现GPS/BDS高精度实时定位的主要手段之一,其核心是长距离参考站网GPS/BDS整周模糊度的快速准确确定。本文提出了一种长距离GPS/BDS参考站网载波相位整周模糊度解算方法,首先利用GPS双频观测数据计算和确定宽巷整周模糊度,同时利用BDS的B2、B3频率观测值确定超宽巷整周模糊度。然后建立GPS载波相位整周模糊度和大气延迟误差的参数估计模型,附加双差宽巷整周模糊度的约束,解算双差载波相位整周模糊度,并建立参考站网大气延迟误差的空间相关模型。根据B2、B3频率的超宽巷整周模糊度建立包含大气误差参数的载波相位整周模糊度解算模型,利用大气延迟误差空间相关模型约束BDS双差载波相位整周模糊度的解算。克服了传统的使用无电离层组合值解算整周模糊度的不利影响。采用实测长距离CORS网GPS、BDS多频观测数据进行算法验证,试验结果证明该方法可实现长距离参考站网GPS/BDS载波相位整周模糊度的准确固定。     

利用GPS拖体在万山区域测量平均海面技术研究

Wanshan area has been chosen to be the specified field to calibrate and validate(Cal/Val) the HY-2 altimeter and its follow-on satellites. In March 2018, an experiment has been conducted to determine the sea surface height(SSH) under the HY-2 A ground track(Pass No. 203). A GPS towing-body(GPS-TB) was designed to measure the SSH covering an area of about 6 km×28 km wide centered on the HY-2 A altimeter satellite ground track. Three GPS reference stations, one tide gauge and a GPS buoy were placed in the research area, in order to process and resolve the kinematic solution and check the precision of the GPS-TB respectively. All the GPS data were calculated by the GAMIT/GLOBK software and TRACK module. The sea surface was determined by the GPS-TB solution and the tide gauge placed on Zhiwan Island. Then the sea surface of this area was interpolated by Arc GIS10.2 with ordinary Kriging method. The results showed that the precision of the GPS-TB is about 1.10 cm compared with the tide gauge placed nearby, which has an equivalent precision with the GPS buoy. The interpolated sea surface has a bias of –1.5–4.0 cm with standard deviation of 0.2–2.4 cm compared with the checking line. The gradient of the measured sea surface is about 1.62 cm/km along the HY-2 orbit which shows a good agreement compared with the CLS11 mean sea surface(MSS). In the Cal/Val of satellites, the sea surface between the tide gauge/GPS buoy and the footprint of altimeter can be improved by this work.     

经济地理学制度理论的发展与建构的重要方向

在中国制度差异显著与目前区域发展不平衡不充分的现实下,经济地理学与制度相结合的研究显得尤为必要。通过系统地梳理经济地理学与制度的关系发现,经济地理学与制度在历史上存在先分离后融合的情况,并且目前经济地理学与制度研究结合态势不容乐观,制度研究在本体论、方法论、时间维度、空间尺度、研究方法等方面仍然存在不足。通过文献梳理与理论分析,认为经济地理学的制度理论应基于演化经济地理学进行建构,并提出了建构的方向:1)以系统论、层级观为指导,注重构建制度的层级结构;2)以反还原论为基础,寻求方法论的突破;3)借助演化的思想与路径依赖理论,强调时间在制度系统中的作用;4)加强对各空间尺度的制度研究;5)注重工具方法的借鉴与创新。     

实时卫星钟差基准精化方法

在基于精密单点定位(PPP)的授时方法中,卫星钟差产品的高精度时间基准至关重要.针对实时卫星钟差产品时间基准不够稳定的问题,本文采用一组具有原子钟外部输入的国际全球卫星导航系统(GNSS)服务(IGS)跟踪站建立了顾及原子钟变化特性的基准精化方法.该方法首先采用阿伦方差对不同的IGS跟踪站外接原子钟进行稳定度分析,挑选出一组稳定度高的原子钟用以精化时间基准.在此基础上,利用阿伦方差分析各台原子钟的噪声参数特征,并确定不同原子钟之间的权比关系.最终,建立时间基准改正量的随机模型,并计算出精化后的时间基准.通过实例验证表明:与IGS事后精密钟差产品定义的时间基准比较,改正后的实时钟差基准单天内的标准差(STD)优于0.1 ns,相比于改正前最高提升了93%.同时,基准改正后的天内万秒稳达到10^-15量级,实现了一个量级的提高.此外,通过相对钟差精度的分析,表明钟差基准修正不影响PPP的定位精度.     

海山富钴结壳标准物质研制

报道了我国与俄罗斯合作研制的三个海山富钴结壳标准物质GSMC-1,2,3.这三个标准物质的原样分别取自西太平洋麦哲伦海山和中太平洋海山.样品经风干、选配、球磨制备成均匀的粉体样品,其均匀性采用高精度的X-射线荧光光谱法检验.样品的化学组分采用国内外多实验室协同分析方式定值,有八个国内实验室和八个国外实验室参加了合作分析.测试组分均为57个,其中GSMC-1,2有43个组分定为保证值,10个组分作为参考值;GSMC-3有45个组分定为保证值,8个组分作为参考值.经2a多的试用,三个标准物质已于2005年被国家计量部门批准为国家一级标准物质,其编号分别为GBW07337,GBW07338和GBW07339.     

现今绝对板块运动

根据热点假设,热点对于中间层是固定的.相对热点的板块运动叫做绝对板块运动.绝对板块运动模型可以通过反演火山链传播的速率和走向数据以确定相对板块运动在角速度空间的原点来得到.利用一组近来(0～7.8 Ma)全球分布的热点的迁移速率和走向数据,结合板块运动模型NNR-NUVEL1A,已研制出一个叫做APM2的现今绝对板块运动模型.按照该模型,太平洋板块围绕60.063°S、102.210°E处的极以(0.833 0°±0.013 3°)/Ma的速率运动,非洲板块围绕46.849°N、44.372°W的极以(0.101 5°±0.013 4°)/Ma的速率运动,南极板块的运动则以46.871°N、146.942°E为极,速率为(0.084 6°±0.017 7°)/Ma,欧亚板块的运动更慢,极为27.291°N、171.925°W,速率为(0.065 5°±0.020 6°)/Ma.这一模型表明,岩石圈相对深部地幔有一个以49.423°S、90.625°E为极,速率为(0.198 3°±0.013 5°)/Ma的净旋转.表明太平洋热点同印度-大西洋热点不一致,显示太平洋热点的运动也不一致.为了分析和比较,还给出了仅用全球分布的热点的走向数据和仅用印度-大西洋热点的走向数据得到的板块绝对运动的角速度.     

Three-dimensional liquid sloshing in a tank with baffles

A numerical model has been developed to study three-dimensional (3D) liquid sloshing in a tank with baffles. The numerical model solves the spatially averaged Navier-Stokes equations, which are constructed on a non-inertial reference frame having six degree-of-freedom (DOF) of motions. The large-eddy-simulation (LES) approach is employed to model turbulence by using the Smagorinsky sub-grid scale (SGS) closure model. The two-step projection method is employed in the numerical solutions, aided by the Bi-CGSTAB technique to solve the pressure Poisson equation for the filtered pressure field. The second-order accurate volume-of-fluid (VOF) method is used to track the distorted and broken free surface. The baffles in the tank are modeled by the concept of virtual boundary force (VBF) method. The numerical model is first validated against the available analytical solution and experimental data for two-dimensional (2D) liquid sloshing in a tank without baffles. The 2D liquid sloshing in tanks with baffles is then investigated. The numerical results are compared with other results from available literatures. Good agreement is obtained. Finally, the model is used to study 3D liquid sloshing in a tank with vertical baffles. The effect of the baffle is investigated and discussed.     

Triangulated spherical splines for geopotential reconstruction

We present an alternate mathematical technique than contemporary spherical harmonics to approximate the geopotential based on triangulated spherical spline functions, which are smooth piecewise spherical harmonic polynomials over spherical triangulations. The new method is capable of multi-spatial resolution modeling and could thus enhance spatial resolutions for regional gravity field inversion using data from space gravimetry missions such as CHAMP, GRACE or GOCE. First, we propose to use the minimal energy spherical spline interpolation to find a good approximation of the geopotential at the orbital altitude of the satellite. Then we explain how to solve Laplace’s equation on the Earth’s exterior to compute a spherical spline to approximate the geopotential at the Earth’s surface. We propose a domain decomposition technique, which can compute an approximation of the minimal energy spherical spline interpolation on the orbital altitude and a multiple star technique to compute the spherical spline approximation by the collocation method. We prove that the spherical spline constructed by means of the domain decomposition technique converges to the minimal energy spline interpolation. We also prove that the modeled spline geopotential is continuous from the satellite altitude down to the Earth’s surface. We have implemented the two computational algorithms and applied them in a numerical experiment using simulated CHAMP geopotential observations computed at satellite altitude (450 km) assuming EGM96 (n _max = 90) is the truth model. We then validate our approach by comparing the computed geopotential values using the resulting spherical spline model down to the Earth’s surface, with the truth EGM96 values over several study regions. Our numerical evidence demonstrates that the algorithms produce a viable alternative of regional gravity field solution potentially exploiting the full accuracy of data from space gravimetry missions. The major advantage of our method is that it allows us to compute the geopotential over the regions of interest as well as enhancing the spatial resolution commensurable with the characteristics of satellite coverage, which could not be done using a global spherical harmonic representation. The results in this paper are based on the research supported by the National Science Foundation under the grant no. 0327577.