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61.
Jean?VallanceEmail author Marie-Christine?Boiron Michel?Cathelineau Serge?Fourcade Michel?Varlet Christian?Marignac 《Mineralium Deposita》2004,39(3):265-281
The Moulin de Chéni orogenic gold deposit is the only granite-hosted deposit of the Saint-Yrieix district, French Massif Central. It occurs in 338±1.5 Ma-old peraluminous leucogranites and is characterized by intense microfracturing and bleaching of the granite in relation to pervasive sulfide crystallization. Formation of quartz veins and gold deposition occurred in two successive stages: an early mesozonal stage of quartz-sulfide (Fe-As-S) deposition, usually devoid of gold and a late epizonal stage of base metal and gold deposition. Both stages postdate peak metamorphism and granite intrusion. The genesis of the deposit is the result of four successive fluid events: (1) Percolation of aqueous-carbonic metamorphic fluids under an assumed lithostatic regime of 400–450 °C, at a maximum depth of 13 km; (2) Formation of the main quartz lodes with coeval K-alteration and introduction of As and S from aqueous-carbonic fluids percolating along regional faults. Arsenopyrite and pyrite deposition was linked to the alteration of Fe-silicates into K-feldspar and phengite at near-constant iron content in the bulk granite. Temperature was similar to that of the preceding stage, but pressure decreased to 100–50 MPa, suggesting rapid uplift of the basement up to 7.5 km depth; (3) The resulting extensional tectonic leads to the deposition of gold, boulangerite, galena and sphalerite in brecciated arsenopyrite and pyrite from aqueous fluids during a mixing process. Temperature and salinity decrease from 280 to 140 °C and 8.1 wt% eq. NaCl to 1.6 wt% eq. NaCl, respectively; (4) Sealing of the late fault system by barren comb quartz which precipitated from dilute meteoric aqueous fluids (1.6 wt% eq. NaCl to 0.9 wt% eq. NaCl) under hydrostatic conditions at 200–150 °C.Editorial handling: B. Lehmann 相似文献
62.
Ilhem Bentaleb Cyril Langlois Céline Martin Paula Iacumin Matthieu Carré Pierre-Olivier Antoine Francis Duranthon Issam Moussa Jean-Jacques Jaeger Nicholas Barrett Ron Kandorp 《Comptes Rendus Geoscience》2006,338(3):172-179
The relationship between the oxygen isotope ratio of mammal tooth enamel and that of drinking water was used to reconstruct changes in the Miocene oxygen isotope ratio of rainfall (meteoric water OMW). These, in turn, are related to climatic parameters (temperature, precipitation and evaporation rate). O values of rhinocerotid teeth from the Aquitaine Basin (southwestern France) suggest a significant climatic change between 17 and 12 Ma, characterized by cooling together with precipitation increase, in agreement with other terrestrial and oceanic records. To cite this article: I. Bentaleb et al., C. R. Geoscience 338 (2006). 相似文献
63.
Oxygen deficient perovskites in the system CaSiO3–CaAlO2.5 and implications for the Earth’s interior
U. W. Bläß F. Langenhorst D. J. Frost F. Seifert 《Physics and Chemistry of Minerals》2007,34(6):363-376
Oxygen deficient perovskites of the system CaSiO3–CaAlO2.5 have been synthesised at high-pressure and -temperature conditions relevant to the Earth’s transition zone in order to investigate
their stabilities in the Earth’s mantle and determine structural properties associated with vacancy incorporation. Two polysomes
of thermodynamically stable defect perovskites with Ca(Al0.4Si0.6)O2.8 and Ca(Al0.5Si0.5)O2.75 stoichiometry have been identified. The ordering of oxygen defects into pseudo-cubic (111) layers results in well-ordered
ten- or eightfold superstructures, respectively. At all other compositions examined, a metastable formation of perovskites
has been observed instead, which are assumed to grow initially disordered. These are now characterised by tiny domains, formed
due to subsequent ordering of vacancies along various pseudo-cubic {111} layers. Both ordered defect perovskites show a large
P–T stability field ranging from about 9–18 GPa and 4–12 GPa, respectively. Microstructural TEM analyses revealed the presence
of growth and ferroelastic twins, which indicate a phase transition from rhombohedral to monoclinic symmetry during quenching.
Electron energy loss spectroscopy of Si and Al K edges point at the presence of tetrahedral, octahedral and maybe some pentacoordinated silicon, whereas aluminium is predominantly
octahedrally coordinated with minor fractions in lower coordination. Observed properties are interpreted in terms of a new
structural model, explaining the observed phase transition and formation of different twin laws as well as giving reasons
for the development of such large superstructures. With respect to phase relations of the transition zone, the potential occurrence
of such defect perovskites in the Earth’s interior is discussed. 相似文献
64.
Miyuki Tahata Yusuke Sawaki Yuichiro Ueno Manabu Nishizawa Naohiro Yoshida Toshikazu Ebisuzaki Tsuyoshi Komiya Shigenori Maruyama 《地学前缘(英文版)》2015,6(1):121-136
Important ecological changes of the Earth(oxidization of the atmosphere and the ocean) increase in nutrient supply due to the break-up of the super continent(Rodinia) and the appearance of multi-cellular organisms(macroscopic algae and metazoan) took place in the Ediacaran period,priming the Cambrian explosion.The strong perturbations in carbon cycles in the ocean are recorded as excursions in carbonate and organic carbon isotope ratio(δ~(13)C_(carb) and δ~(13)C_(org)) from the Ediacaran through early Cambrian periods.The Ediacaran-early Cambrian sediment records of δ~(13)C_(carb) and δ~(13)C_(org),obtained from the drill-core samples in Three Gorges in South China,are compared with the results of numerical simulation of a simple one-zone model of the carbon cycle of the ocean,which has two reservoirs(i.e.,dissolved organic carbon(DOC) and dissolved inorganic carbon(DIC).The fluxes from the reservoirs are assumed to be proportional to the mass of the carbon reservoirs.We constructed a model,referred to here as the Best Fit Model(BFM),which reproduce δ~(13)C_(carb) and δ~(13)C_(org) records in the Ediacaran-early Cambrian period noted above.BFM reveals that the Shuram excursion is related to three major changes in the carbon cycle or the global ecological system of the Earth:(1) an increase in the coefficient of remineralization by a factor of ca.100,possibly corresponding to a change in the dominant metabolism from anaerobic respiration to aerobic respiration,(2) an increase of carbon fractionation index from 25‰ to 33‰,possibly corresponding to the change in the primary producer from rock-living cyanobacteria to free-living macro algae,and(3) an increase in the coefficient of the organic carbon burial by a factor of ca.100,possibly corresponding to the onset of a biological pump driven by the flourishing metazoan and zooplankton.The former two changes took place at the start of the Shuram excursion,while the third occurred at the end of the Shuram excursion.The other two excursions are explained by the tentative decrease in primary production due to cold periods,which correspond to the Gaskiers(ca.580 Ma) and Bikonor(ca.542 Ma) glaciations. 相似文献
65.
Maria da Glria M. Garcia Mrio C. Campos Neto Anthony E. Fallick 《Journal of South American Earth Sciences》2003,15(8):871-883
Oxygen isotope studies were carried out across units of a Neoproterozoic nappe system, south of São Francisco Craton. A temperature decrease toward the base of the system is found, consistent with a previously recognized inverted metamorphic pattern. The tectonic contact of the basal unit and the reworked southern São Francisco craton show a steep temperature gradient, suggesting that low temperature thrusting acted as the dominant tectonic process. The contrasts between the δ18O values of the Três Pontas-Varginha and Carmo da Cachoeira nappes and the differences among the samples and minerals are consistent with the preservation of sedimentary isotopic composition during metamorphism. The small differences in the δ18O values between the undeformed and the deformed calc-silicate samples (1.6‰) suggest that the δ18O value of mylonitization fluids was close to that which equilibrated with the metamorphic assemblage. The distinct δ18O values of metapelitic and calc-silicate samples and the great temperature difference from one type to the other indicate that no large-scale fluid interaction processes occurred during metamorphism. Oxygen isotopic estimations of both Três Pontas-Varginha undeformed rocks and Carmo da Cachoeira unaltered equivalents indicate δ18O values of up to 18‰. Comparison between these values and those from the ‘basement’ orthogneisses (8.3–8.5‰) indicates the latter are not sources for the metapelites. 相似文献
66.
Elena Dunca Harry Mutvei Peter Göransson Carl-Magnus Mörth Bernd R. Schöne Martin J. Whitehouse Mikael Elfman Susanne P. Baden 《International Journal of Earth Sciences》2009,98(1):3-17
Shells of Arctica islandica collected between 1884 and 2004 from Öresund, Kattegat and Skagerrak (Swedish West Coast) were used to monitor local climate variations and the influence of human activities on the local environment. For this purpose, we analysed the growth, structure and chemical composition of these shells and compared them with shells collected from Kiel Bay, Norway and Iceland. The growth rate of the studied shells registers an NAO periodicity of ca 8 years. However, the observed signal is weak because of other environmental interferences that are either of natural or anthropogenic origin. For example, the oxygen isotope ratios show temperature fluctuation, but also the influx of low salinity water. Higher contents of S, N, Cu, Zn, As, Cd and P in shell portions formed during the last century are related to human activities such as mining and industrial development. Our study indicates that in order to use Arctica shells as archives of climate change it is necessary to study the full range of environmental data that is recorded in the shells by using a multi element and isotope approach in combination with different analytical techniques including investigation of growth rates and shell structure. 相似文献
67.
酸溶——催化极谱法测定地质样品中的钨、钼 总被引:3,自引:0,他引:3
本文采用混合酸溶解样品,对影响催化体系稳定的酸度、温度和不同反应时间的因素分别进行了对比试验,确定催化体系相对稳定的最佳条件,经过大量样品的分析验证,分析方法可靠。 相似文献
68.
69.
Makoto Yamada Shinji Ohsawa Kohei Kazahaya Masaya Yasuhara Hiroshi Takahashi Kazuhiro Amita Hideo Mawatari Shin Yoshikawa 《Journal of Geochemical Exploration》2011
To understand deep groundwater flow systems and their interaction with CO2 emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ13CDIC) and DIC concentrations of the sampled waters show that magma-derived CO2 mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ13CDIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ18O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ13CDIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO2 is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO2 mixes into deeper groundwater flowing nearer the magma conduit or chamber. 相似文献
70.
《Comptes Rendus Geoscience》2015,347(2):77-83
Bacterial activity in the near-field environment of radioactive waste disposal facilities in deep argillaceous rocks is currently under investigation. Bacterial development could be enhanced by the availability of low-molecular-weight organic acids (LMWOA) dissolved in the pore water of clayey rocks. This study firstly aimed at isolating and characterizing the LMWOA of the Toarcian argillite from the Tournemire Underground Research Laboratory (France, Aveyron). It also aimed at assessing the disturbing effects that could be induced by a disposal facility on the type and release of LMWOA (exposure to oxygen, alkaline pH, temperature increase). Under the experimental conditions investigated at 60 °C, the mean dissolved organic carbon (DOC) is about 15 mg L−1 with a LMWOA proportion of 35 %. The main LMWOA are composed of formate, fumarate, propionate, acetate, and lactate. DOC is mainly influenced by both temperature and pH increases, whereas the LMWOA type nature and release are more specifically affected by the exposure to oxygen. 相似文献