Origin and mechanisms of K–Si-metasomatism of ca. 3.4–3.3 Ga volcaniclastic deposits and implications for Archean seawater evolution: Examples from cherts of Kittys Gap (Pilbara craton, Australia) and Msauli (Barberton Greenstone Belt, South Africa)

The effects of K–Si-metasomatism during the formation of Early Archean replacement cherts have been quantified in this study by the investigation of two well-known stratigraphic sections: the Msauli chert (MC, Barberton greenstone belt, South Africa) and the Kittys Gap chert (KGC, Pilbara craton, Western Australia). The KGCs have a dacitic precursor similar to Duffer Formation dacites (Pilbara craton), while the MCs are derived from Al-depleted komatiites similar to those from the Weltevreden Formation (Barberton greenstone belt). Mass balance calculations reveal that the volcaniclastic deposits had initial porosities of up to 85 vol.% for the KGC and of 65 vol.% for the MC. Secondary porosities (27 vol.%: MC, 8 vol.%: KGC) produced during K-metasomatism are proportional to the dissolution of Fe, Ca, Mg-rich glass and precursor minerals. Komatiites have a higher chemical exchange potential than dacites, each gram releasing 1.2 mmol Fe²⁺, 2.8 mmol Mg²⁺, 1.4 mmol Ca²⁺ and 1.1 mmol Na⁺ to seawater, together with 4.4 mmol O²⁻. K-metasomatism of 1 g of komatiite further implies an uptake of 0.67 mmol of K⁺ and 2.7 mmol of H⁺. The highest silica uptake is achieved for the KGC (82 mmol/g of precursor). This silica enrichment most likely operated in the water column and at the sediment–water interface by sorption mechanisms on the surface of detrital particles and particulate organic matter, as a result of seawater silica-saturation. Acidic conditions (pH 5.5–6.5) and hot temperatures (>70 °C) favored the formation of K-rich phyllosilicates by interaction with seawater during the early diagenetic alteration of the volcaniclastic particles. The widespread occurrence of K–Si-metasomatism in volcanic and sedimentary rocks can be regarded as a general alteration process of the Early Archean seafloor, with a major influence on seawater composition. The highly K-selective metasomatism confirms previous studies suggesting that the Archean ocean was acidic and probably in equilibrium with a CO₂-rich atmosphere.     

江西浒坑钨矿含矿石英脉的地质特征及成矿构造演化

位于赣西武功山地区的江西浒坑钨矿是一个大型石英脉型钨矿床,与赣南典型的“五层楼”模式不同,矿脉主要集中在岩体内接触带。含矿石英脉除了普通的块状构造以外,还普遍存在条带状构造。详细的野外编录和镜下研究表明含矿块状石英脉在形成后遭受不同程度的韧性剪切,从而形成不同成分的分异条带。剪切带以出现新生的面理和线理（拉伸线理）为特征。岩石学研究表明条带状矿石属于糜棱岩,具有丰富的塑性变形显微构造特征。通过对含矿石英脉的构造解析,认为与岩浆岩有关的原生节理系统基本上是同时形成的,沿节理充填的石英脉经历了长期的、多期次的构造运动,从而形成了复杂的石英脉和矿石类型。建立了原生节理形成→石英充填→韧性剪切发生→二期石英充填→脆性碎裂的矿区构造演化序列。韧性剪切作用的动力学背景可能是受后期岩浆侵入的影响,最后的脆性破裂应与区域上存在南北向的压应力有关。     

Wind wave-forced fine sediment erosion during the slack water periods in Hangzhou Bay,China

The shallow water wave simulation model-SWAN incorporated with a simple fine sediment erosion model is applied to Hangzhou Bay, China, to model the horizontal distribution of the maximum bottom orbital velocity and corresponding fine sediment erosion rates induced by: (1) southeasterly steady winds (5, 20 and 30 m/s), (2) southwesterly steady winds (5 and 20 m/s); (3) northwesterly steady winds (5 and 20 m/s); (4) east-southeasterly steady winds (5 and 20 m/s); (5) easterly steady winds (5 and 20 m/s) under closed and unclosed boundaries; and (6) unsteady winds during the slack water periods. Results suggest: (1) the steady wind wave-induced maximum bottom orbital velocities and corresponding fine sediment erosion rates generally increased with the increasing steady winds; (2) closed and unclosed boundary conditions had more significant influences on modeled fine sediment erosion rates under 5 m/s easterly steady winds than 20 m/s; and (3) steady and unsteady wind wave-induced maximum bottom currents could be significant in eroding fine sediment bed in Hangzhou Bay. The results show implications for geomorphology, sedimentology, coastal erosion, and environmental pollution mitigation in Hangzhou Bay.     

Recharge source and hydrogeochemical evolution of shallow groundwater in a complex alluvial fan system,southwest of North China Plain

Many cities around the world are developed at alluvial fans. With economic and industrial development and increase in population, quality and quantity of groundwater are often damaged by over-exploitation in these areas. In order to realistically assess these groundwater resources and their sustainability, it is vital to understand the recharge sources and hydrogeochemical evolution of groundwater in alluvial fans. In March 2006, groundwater and surface water were sampled for major element analysis and stable isotope (oxygen-18 and deuterium) compositions in Xinxiang, which is located at a complex alluvial fan system composed of a mountainous area, Taihang Mt. alluvial fan and Yellow River alluvial fan. In the Taihang mountainous area, the groundwater was recharged by precipitation and was characterized by Ca–HCO₃ type water with depleted δ¹⁸O and δD (mean value of −8.8‰ δ¹⁸O). Along the flow path from the mountainous area to Taihang Mt. alluvial fan, the groundwater became geochemically complex (Ca–Na–Mg–HCO₃–Cl–SO₄ type), and heavier δ¹⁸O and δD were observed (around −8‰ δ¹⁸O). Before the surface water with mean δ¹⁸O of −8.7‰ recharged to groundwater, it underwent isotopic enrichment in Taihang Mt. alluvial fan. Chemical mixture and ion exchange are expected to be responsible for the chemical evolution of groundwater in Yellow River alluvial fan. Transferred water from the Yellow River is the main source of the groundwater in the Yellow River alluvial fan in the south of the study area, and stable isotopic compositions of the groundwater (mean value of −8.8‰ δ¹⁸O) were similar to those of transferred water (−8.9‰), increasing from the southern boundary of the study area to the distal end of the fan. The groundwater underwent chemical evolution from Ca–HCO₃, Na–HCO₃, to Na–SO₄. A conceptual model, integrating stiff diagrams, is used to describe the spatial variation of recharge sources, chemical evolution, and groundwater flow paths in the complex alluvial fan aquifer system.     

Modeling of water–rock interactions in an aquitard of sandy clay in the coastal area near Beihai,China

Unconsolidated sand, gravel and clay deposits near Beihai and in the Leizhou Peninsula in southern China form an unconfined aquifer, aquitard and a confined aquifer. Water and soil samples were collected from the two aquifers in the coastal Beihai area for the determination of chemical compositions, minerals and soluble ions. Hydrogeochemical modeling of three flow paths through the aquitard are carried out using PHREEQC to determine water–rock interactions along the flow paths. The results indicate that the dissolution of anorthite, fluorite, halite, rhodochrosite and CO₂, and precipitation of potash feldspar and kaolinite may be occurring when groundwater leaks through the aquitard from the unconfined aquifer to the confined aquifer. Cation exchanges between Na and Ca can also happen along the flow paths.     

Deep-seated gravitational slope deformations and their influence on consequent mass movements (case studies from the highest part of the Czech Carpathians)

Gravitational spreading of mountain ridges displays primary disequilibrium of flysch mountain areas of the Czech Carpathians. The progression of various types of mass movements is a product of long-term ridge disintegration and is predisposed by the geological structure of the area and the upper Tertiary-Quaternary morphogenesis of the mountain area. Deep-seated slope deformations are spatially interconnected by the occurrence of some other types of slope deformations (e.g. debris flows, debris slides, slumps, rock avalanches, etc.), which pose a considerable risk for the existence of human society. An important causative factor in these dynamically developing hazardous processes is, among other factors, the way in which land has been used in the last three centuries. Therefore, the occurrence of various types of slope deformations is studied in terms of their relation to deep-seated gravitational deformations and in terms of other limiting factors (structural geological, morphological and climatic factors, manmade impacts, etc.). The paper presents several case studies of slope deformations (Velká Čantoryje Mt, Lysá hora Mt, Ropice Mt and Smrk Mt) in the area of the Outer Carpathians within the territory of the Czech Republic and also adverts to some consequences in terms of the socioeconomic structure of the landscape.     

墨西哥湾GC238区冷泉碳酸盐岩的微结构与石化微生物特征

采于墨西哥湾GC238海底天然气渗漏区浅表层的冷泉碳酸盐岩呈结核状产出,由方解石微晶和胶结物及少量的黄铁矿构成。胶结物由直径为0.1～0.5 m的方解石化的球体、卵形体、棒状体组成,充填于方解石晶体之间。冷泉碳酸盐岩结核下表面发育有由方解石化的球体、卵形体、棒状体组成的薄层,其中的一些球状集合体（约5 m）断面显示发育有核和外壳的层圈结构。黄铁矿呈草莓状,也具有相似的层圈结构。这种层状结构与活体古细菌被硫酸盐还原细菌包裹的层圈结构相似。样品中所保存的球体、卵形体、棒状体及其所组成的层圈结构可能是石化的甲烷氧化古细菌和硫酸盐还原细菌。     

饱和粉砂不稳定性的试验研究

通过对净砂和级配良好粉砂(含10 %粉土)进行一系列三轴固结不排水试验（CU）,研究了粉土、孔隙比和围压对饱和粉砂不稳定性的影响。试验结果表明,净砂与粉砂在不排水剪切条件下均会出现应变软化现象（即不稳定性）。同一围压下脆性指数(IB)随孔隙比增加,但不稳定线的应力比随孔隙比增加而减小。引用等效粒间孔隙比(ege)后,净砂和粉砂在ege-ln p?平面上拥有基本相同的临界状态线。在临界状态理论及等效粒间孔隙比的基础上,提出在同一修正状态参数(?ge)下净砂和级配良好粉砂有相似的不稳定性。     

烟台港和邻近锚地及其入境船舶压舱水中的浮游植物

本文根据2003年5月到2004年4月间烟台港和邻近锚地水域及其船舶压舱水中的浮游植物调查资料,对浮游植物的群落结构和压舱水对其影响进行了初步研究。结果表明,烟台港和临近锚地的浮游植物群落主要由温带沿岸性物种组成,以硅藻为主,还有少量甲藻和金藻;对比船舶压舱水中浮游植物群落发现:压舱水中浮游植物群落和本地群落的结构有很大差异,有害物种在压舱水中出现的频率较高。     

Glass inclusions in volcanic rocks in the Okinawa Trough back-arc basin:constraints on magma genesis and evolution

INTROOUcr1ONThe Okinawa Trough is a typical marginal back-arc basin, where its oPening began in rela-tively recent years* There is a great controversy about the origin of its initial magYna. haltand acid volcanic pumice make up the bimedal volcanism in the Okinawa Trough. MOSt of geol-ogists believed that the acid pumice was the preduct of extremely crystal fractionation of baseltInagTna, but the others argued that it should com from the melting of lower-crust. Som de-tailed petrolOgic…