Formation of iron-containing colloids by the weathering of phyllite

The formation of colloids during the weathering of phyllite was investigated by exposing ground phyllite to Milli-Q water. Secondary mineral colloids of 10¹–10² nm were detected in significant concentrations. At pH of about 8.5, the solution concentration of these colloids reached up to 10 mg/L (however, acidification to pH 4.0 prevented the formation of the colloids). The mineralogical composition of the secondary mineral colloids is assumed to be a mixture of ferrihydrite, manganese oxyhydroxides, aluminosilicates, amorphous Al(OH)₃ and gibbsite with possible additions of iron silicates and␣iron-alumino silicates. The colloids were stable over longer periods of time (at least several weeks), even in the presence of suspended ground rock. Direct formation of iron-containing secondary mineral colloids at the rock–water interface by the weathering of rock material is an alternative to the well-known mechanism of iron colloid formation in the bulk of water bodies by mixing of different waters or by aeration of anoxic waters. This direct mechanism is of relevance for colloid production during the weathering of freshly crushed rock in the unsaturated zone as for instance crushed rock in mine waste rock piles. Colloids produced by this mechanism, too, can influence the transport of contaminants such as actinides because these colloids have a large specific surface area and a high sorption affinity.     

Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

Faulted backfold versus reactivated backthrust: the role of inherited structures during late extension in the frontal Piémont nappes east of Pelvoux (Western Alps)

In the central part of the internal Western Alps, widespread multidirectional normal faulting resulted in an orogen-scale radial extension during the Neogene. We revisit the frontal Piémont units, between Doire and Ubaye, where contrasting lithologies allow analysing the interference with the N–S trending Oligocene compressive structures. A major extensional structure is the orogen-perpendicular Chenaillet graben, whose development was guided by an E–W trending transfer fault zone between the Chaberton backfold to the north and the Rochebrune backthrust to the south. The Chaberton hinge zone was passively crosscut by planar normal faults, resulting in a E–W trending step-type structure. Within the Rochebrune nappe, E–W trending listric normal faults bound tilted blocks that slipped northward along the basal backthrust surface reactivated as an extensional detachment. Gravity-driven gliding is suggested by the general northward tilting of the structure in relation with the collapse of the Chenaillet graben. The stress tensors computed from brittle deformation analysis confirm the predominance of orogen-parallel extension in the entire frontal Piémont zone. This can be compared with the nearby Briançonnnais nappe stack where the extensional reactivation of thrust surfaces locally resulted in prominent orogen-perpendicular extension. Such a contrasting situation illustrates how the main direction of the late-Alpine extension may be regionally governed by the nature and orientation of the pre-existing structures inherited from the main collision stage.     

Investigating the scale of structural controls on chlorinated hydrocarbon distributions in the fractured-porous unsaturated zone of a sandstone aquifer in the UK

Contaminant migration behaviour in the unsaturated zone of a fractured porous aquifer is discussed in the context of a study site in Cheshire, UK. The site is situated on gently dipping sandstones, adjacent to a linear lagoon historically used to dispose of industrial wastes containing chlorinated solvents. Two cores of more than 100 m length were recovered and measurements of chlorinated hydrocarbons (CHCs), inorganic chemistry, lithology, fracturing and aquifer properties were made. The results show that selecting an appropriate vertical sampling density is crucial both to providing an understanding of contaminant pathways and distinguishing whether CHCs are present in the aqueous or non-aqueous phase. The spacing of such sampling should be on a similar scale to the heterogeneity that controls water and contaminant movement. For some sections of the Permo-Triassic aquifer, significant changes in lithology and permeability occur over vertical distances of less than 1 m and samples need to be collected at this interval, otherwise considerable resolution is lost, potentially leading to erroneous interpretation of data. At this site, although CHC concentrations were high, the consistent ratio of the two main components of the plume (tetrachloroethene and trichloroethene) provided evidence of movement in the aqueous phase rather than in dense non-aqueous phase liquid (DNAPL).     

关于角平分线法建立线状缓冲区算法的改进

分析了用对角平分线法建立缓冲区的算法,提出了一种新的求角平分线和缓冲点的方法,实践证明其在算法实现方面是可行的,而且效果比较理想。     

新疆卡拉麦里金矿带成矿规律及找矿预测

新疆卡拉麦里成矿带内地层较全、构造发育、岩浆活动频繁，志留系、泥盆系和石炭系在带内广泛发育，为本区主要含金地层．卡拉麦里深断裂严格控制区内侵入岩、次一级构造和矿产分布，构成岩浆侵入的主要通道，与此有关的次一级断层和裂隙则构成良好的赋存空间．卡拉麦里深大断裂纵贯全区，金成矿地质条件优越，沿走向Au异常、金矿床(点)成群成带分布，最后确定了7个金找矿远景区．     

T市平面控制网的扩建及与1954北京坐标系的关系

本文论证了58T市独立坐标系与87T市独立坐标系的区别，使用T市扩建二等GPS网的平差成果，给出了87T市独立坐标系精确变换到1954北京坐标系的方法与参数。     

近20年全球总云量变化趋势分析

利用ISCCP月平均云气候资料集的总云量资料, 采用趋势分析的方法, 得到1983年7月至2001年9月近20年来全球平均总云量的变化趋势, 并分析云量变化的可能原因。近20年全球增温幅度加快, 研究这期间云的变化, 对气候研究和模拟具有重要的意义。结果表明:平均大气环流决定总云量的分布;全球平均总云量的变化趋势在20世纪80年代末发生逆转, 即由增加转为减少;全球平均云量呈减少的变化趋势, 2000年与1987年相比, 减少量约占平均总云量的4%;从地理位置上看, 云量的变化存在区域性差异, 热带和中纬度地区的总云量减少较多, 高纬度地区云量略有增加, 其中南极大陆云量增加较多。     

A multidisciplinary multi-scale framework for assessing vulnerabilities to global change

Terrestrial ecosystems provide a number of vital services for people and society, such as food, fibre, water resources, carbon sequestration, and recreation. The future capability of ecosystems to provide these services is determined by changes in socio-economic factors, land use, atmospheric composition, and climate. Most impact assessments do not quantify the vulnerability of ecosystems and ecosystem services under such environmental change. They cannot answer important policy-relevant questions such as 'Which are the main regions or sectors that are most vulnerable to global change?’ 'How do the vulnerabilities of two regions compare?’ 'Which scenario is the least harmful for a sector?’This paper describes a new approach to vulnerability assessment developed by the Advanced Terrestrial Ecosystem Analysis and Modelling (ATEAM) project. Different ecosystem models, covering biodiversity, agriculture, forestry, hydrology, and carbon sequestration are fed with the same Intergovernmental Panel on Climate Change (IPCC) scenarios based on the Special Report on Emissions Scenarios (SRES). Each model gives insights into specific ecosystems, as in traditional impact assessments. Moreover, by integrating the results in a vulnerability assessment, the policy-relevant questions listed above can also be addressed. A statistically derived European environmental stratification forms a key element in the vulnerability assessment. By linking it to other quantitative environmental stratifications, comparisons can be made using data from different assessments and spatial scales.     

当代气候研究计划

就气候系统问题，国际上与气候及其变化有关的重要科学计划、尤其是气候变化及可预报性研究（CLIVAR）计划，作了简要介绍，同时还就气候预测问题作了讨论。