长江流域河水和悬浮物的锂同位素地球化学研究

深入理解流域侵蚀过程中的锂同位素分馏对于运用锂同位素来示踪化学循环和气候变化是十分必要的。研究集中在长江干流和主要支流的水体和悬浮物的锂及锂同位素组成。长江流域水体的锂及锂同位素组成（δ⁷Li）分别为150~4 570 nmol/L和+7.6‰~+28.1‰,两者沿上游至下游的变化趋势相反。悬浮物锂同位素组成（δ⁷Li）变化比较稳定,分别为41~92 μg/g和-4.7‰~+0.7‰,而且总是低于相应水体的锂同位素组成。悬浮物和流体之间的锂同位素分馏系数在0.977和0.992之间,与悬浮物的量及组成存在明显相关性,反映了粘土矿物的吸附和化学风化的程度。锂含量与锂同位素组成之间良好的负相关性表明流域水体的锂来自2个端元混合：其一可能是蒸发盐岩,并伴有深部热泉水;其二可能是硅酸岩。     

Whole-rock chemistry of the Gameleira I uranium deposit,Lagoa Real,Brazil

The Lagoa Real uranium (U) province, referred to as Lagoa Real, is located in the state of Bahia, north-eastern Brazil. Lagoa Real has ∼112,000 metric tonnes and average grade of 2700 ppm of U₃O₈, being one of the largest U deposits in the world and the largest in Brazil. Despite its economic and strategic importance, there are gaps in the geological knowledge of the Lagoa Real U deposits. One of them is the lack of extensive whole-rock chemical data sets. Here, we present whole-rock chemical analyses for major and trace elements, including the rare-earth elements (REE), from barren country rocks to uraniferous ore shoot, systematically sampled from an exploratory drill hole. The chemical data indicate that albitite rocks, with and without uraniferous mineralisation, cannot result from sodic syenitic magmatism, as proposed by recent studies. Petrographical and geochemical evidence supports the previously suggested concept that the Lagoa Real albitite rocks resulted from sodic metasomatism of the granitic country rock, known as the São Timóteo granite. Their ore-mineral assemblages and geochemical characteristics are similar to albitite-hosted U deposits worldwide.     

Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).     

Circulating planning ideas from the metropole to the colonies: understanding South Africa's segregated cities through policy mobilities

In the early part of the twentieth century, South African cities were segregated in accordance with British city planning concepts that embodied the belief that social order can be manipulated through the urban form. This paper surveys the history of South African planning practices to understand the spread of segregation policies and practices. Whereas scholars tend to agree that the apartheid city (post?1948) is a more highly organized and structured version of the colonial city (pre?1910), the literature lacks consensus on the development of the segregated city (1910?1948) within South Africa. How did concepts of segregation circulate and why was it implemented with such consistency? Accordingly, this paper employs concepts of policy mobilities to trace historical configurations in South Africa to international influences. The focus on the circuits of knowledge explains how concepts and designs transplanted from elsewhere helped create the form of South African cities today. Understanding the movement of planning ideas through policy mobilities furthers geographical understandings of historical circulation processes, the role of the local actors, and policy mobilities failure. This history of learning also challenges the assumption that South African cities are unique and in so doing opens the doors for knowledge sharing between postcolonial cities.     

Analysis of Multiple Tourist Agents’ Symbiotic Relationship on the View of Tourist Enterprises Based on a Grey Correlation Model: A Case Study of Qinghai Lake,China

Tourism symbiosis is a social phenomenon consisting of many complex factors, and the reciprocal cooperation among multiple tourist agents at tourist destinations is the crux of the sustainable development of tourism. This study is from the perspective of tourist enterprises, and introduces the Symbiosis Theory of genecology. A quantitative evaluation is used to analyze both the equilibrium state of the combined symbiotic behavior routes and the behavior patterns of tourist enterprises with local governments, community residents, tourists and tourist enterprises around Qinghai Lake. The findings reveal: (1) the symbiotic behavior routes of the multiple tourist agents “E→G-R-T-E” in the Qinghai Lake area are constituted of intense symbiotic indications, while the maximum dimensionality of symbiotic interest of “E→G-R-T-E” is still in the state of disequilibrium and dissymmetry; (2) the symbiotic model of multiple tourist agents “E→G-R-T-E” in the Qinghai Lake area is an asymmetrically positive symbiotic model. It is proposed that, by establishing symbiotic mechanisms for guidance, decisions, supervisory control and profit distribution, the participation mechanism for multiple agents “E-G-R-T” can be further standardized. Moreover, tourist enterprises should be regarded as the primary agents to optimize the symbiotic model for “E→G-R-T-E” through the reinforcement of integrative supply and the construction of integrative effect, and finally promote the integrative symbiotic model of symmetrical reciprocity of the E-R-G-T model “driven by scenic areas, responsive to community residents, affected by local governments and enjoyed by tourists.”     

Tafoni on coastal slopes,South Devon,U.K.

Cavernous weathering (tafoni development) occurs on coastal slopes in greenschist bedrock at elevations up to 40 m above sea level. The freshly weathered surfaces of the cavern interiors are irregular in morphology, discordant to major rock structure, formed by substantially weakened rock and associated with granular weathering debris. The weathering debris contains soluble elements in proportions similar to those present in seawater, and the penetration of elements associated with sea salts into the weathering surface to estimated depths of at least 0·1–0·2 m is indicated by the presence of chlorine. Scanning electron microscopy and microprobe analyses suggest that rock breakdown occurs principally through limited chemical weathering at grain boundaries. The mechanism for the emplacement of marine salts within sheltered rock surfaces in the tafoni is postulated to be a combination of dry deposition under turbulent atmospheric conditions and wetting by coastal fog.     

化学试剂管理数据库的设计与开发——以华东地质学院化学试剂管理数据库为例

论述了采用客户／服务器模型设计、实现化学试剂管理数据库的方法和技术。通过网络平台完成院各部门的年度化学试剂申报、统计和管理工作，可以充分发挥校园网的通讯优势。解决了长期存在的化学试剂手工管理所带来的效率低、申报不及时甚至重复申报等问题。     

农业生态的化学元素分类及其与作物优质高产的关系

利用国家科学技术成果，并根据国内外研究现状，将103个化学元素分成对作物生长发育、增产起显著作用、起一定作用、起有害作用和起未知作用4个农业生态元素类型，进而论述了它们与作物优质高产的关系。