High Arctic wetlands: Their occurrence, hydrological characteristics and sustainability

High Arctic wetlands, though limited in occurrence, are an important ecological niche, providing the major vegetated areas in an arid and cold polar desert environment. These wetlands are often found as patches in the barren landscape. At a few locales which may be ice-wedge polygonal grounds, glacial terrain and zones of recent coastal uplift, wetland occurrence can become extensive, forming a mosaic that comprises patches of different wetland types. Reliable water supply during the thawed season is a deciding factor in wetland sustainability. The sources include meltwater from late-lying snowbanks, localized ground water discharge, streamflow, inundation by lakes and the sea, and for some ice-wedge wetlands, ground-ice melt. Different types of wetlands have their own characteristics, and peat accumulation or diatom depositions are common. The peat cover insulates the wetland from summer heating and encourages permafrost aggradation, with the feedback that a shallow frost table reduces the moisture storage capacity in a thinly thawed layer, which becomes easily saturated. All the wetlands studied have high calcium content since they are formed on carbonate terrain. Coastal wetlands have high salt concentration while snowmelt and ground-ice melt provides dilution. The sustainability of High Arctic wetlands is predicated upon water supply exceeding the losses to evaporation and lateral drainage. Disturbances due to natural causes such as climatic variations, geomorphic changes, or human-induced drainage, can reduce inundation opportunities or increase outflow. Then, the water table drops, the vegetation changes and the peat degrades, leading to the detriment of the wetlands.     

Provenance and Evolution of the Guarguariiz Complex, Cordillera Frontal, Argentina

The Guarguardz Complex, basement of the Cordillera Frontal, included in the proposed Chilenia Terrane, consists of metasedimentary rocks deposited in clastic and carbonatic platforms. Turbiditic sequences point out to slope or external platform environments. According to geochemical data, the sedimentary protoliths derived through erosion of a mature cratonic continental basement. Volcanic and subvolcanic rocks with N and E-MORB signature were interbeded in the metasedimentary rocks during basin development. A compressional stage, starting with progressive deformation and metamorphism, followed this extensional stage. Continuing deformation led to the emplacement of slices of oceanic crust, conforming an accretionary prism during Late Devonian. The Guarguardz Complex and equivalent units in western Precordillera and also in the Chilean Coastal Cordillera share common evolutional stages, widely represented along the western Gondwana margin. These evidences imply that Chilenia is not an allochthonous terrane to Gondwana, but a portion of its Early Paleozoic margin. Regional configuration indicates that the Guarguardz Complex and equivalent units represent the accretionary prism of the Famatinian arc (Middle Ordovician-Late Devonian).     

Joints,faults and palaeostress evolution in the Campo de Dalias (Betic Cordilleras,southeastern Spain)

The Campo de Dal??as, located between the central and eastern Betic Cordilleras, shows an evolution determined by the overprinting of two main stress fields since Pliocene times. The first of these develops hybrid and tensional joint sets up to Pleistocene (100 000 yr) and is characterized by NNW–SSE horizontal trend of compression and an ENE–WSW horizontal extension. The second stress field has prolate to triaxial extensional ellipsoids, also with ENE–WSW horizontal extension, and continues to be active today. The most recent stresses produce the reactivation of previous joints as faults whose trends are comprised mainly from N120°E to N170°E and have a normal and transtensional regime, with dextral or sinistral components. The palaeostress evolution of this region is similar to that undergone by other basins of the Eastern Betic Cordilleras, although the Pliocene–Pleistocene transcurrent deformations in the Campo de Dal??as only develop joints and not strike-slip faults.     

Deep seismic soundings in southern Spain

Summary In 1974 and 1975 deep seismic sounding experiments were carried out in the area of the Betic Cordillera in southern Spain. A network of crustal seismic profiles was established with shotpoints at sea close to Cádiz, Adra and Cartagena and on land at Alquife near Guadix. The lengths of the profiles range from 50 km near Alquife to 440 km for the main profile between Cádiz and Cartagena parallel to the strike of the Betic Cordillera. The main profile was supplemented by a reversed recording line close to the Mediterranean coast between Adra and Cartagena and another one perpendicular to the main tectonic strike from Adra towards the north. The first interpretation of the data indicates considerable variation in the crustal thickness. A preliminary inversion leads to a three-layered model of the crust. The mean compressional velocity is about 5.1 km/s down to a depth of 4 km. Below this the velocity is 6.13 km/s from 4 to 16 km where it increases to 7.14 km/s. TheP _n-velocity is 8.18 km/s. The crust-mantle boundary is reached at a depth of 27 km near Cartagena and lies 32 km deep near Adra, Underneath the gravity minimum of the Betic Cordillera the crust-mantle boundary is found at a depth of about 36 km. Below the Betic zone a pronounced zone of low velocity with 7.7 km/s seems to exist in the depth range from 40 to 60 km.Contribution No. 4, Grupo de Trabajo de Perfiles Sismicos, Comisión Española del Proyecto Geodinámico, C.S.I.C., Madrid, Spain.Contribution No. 139, Geophysical Institute, University of Karlsruhe, Hertzstrasse 16, D-75 Karlsruhe 21, Germany.Contribution No. 217, Institut de Physique du Globe, Université Paris VI, 4 Place Jussieu, F-75230 Paris Cedex 05, France.Contribution No. 11, Instituto y Observatorio de Marina, San Fernando (Cádiz), Spain.Contribution No. 163, Institute of Geophysics, Swiss Federal Institute of Technology, ETH-Hönggerberg, CH-8093 Zürich, Switzerland.     

Environmental assessment of elements and polyaromatic hydrocarbons emitted from a Canadian coal-fired power plant

A detailed assessment of elements was carried out at a power plant rated at approximately 760 MW of electricity using western Canadian subbituminous coal. The concentrations of elements of environmental concern (As, Cd, Cr, Hg, Ni, and Pb) in milled coals, ashes, stack-emitted materials. Speciation of As, Cr, and Ni were determined. The polyaromatic hydrocarbons (PAHs) emitted from the stack were also measured. The rates of input of elemental input for As, Cd, Cr, Hg, Ni, and Pb were 28, 0.94, 230, 0.44, 44, and 88 kg/day, respectively; of which only 0.16, 0.01, 0.40, 0.27, 0.15, and 0.04 kg/day, respectively, were stack emitted. The total stack emission of toxic elements is 1.02 kg/day, with Cr being the highest contributor to this group with 0.4 kg/day. However, Hg at 0.27 kg/day has the highest percentage rate of emission at about 60%, while Cd has the lowest at about 1%. The electrostatic precipitator (ESP) removes a significant portion of the elements indicated by their relative enrichment (RE) ratios greater than 0.7. The results show that most of the elements in milled coal are low compared to world coals and other Canadian milled coals.Mercury is mostly ( 81%) emitted as gaseous elemental mercury (GEM), with 19% as reactive gaseous mercury (RGM). Particulate mercury is very low and averages about 0.1% of the total mercury at this station. Most of the arsenic in the milled coal is primarily associated with pyrite or as arsenate in its less toxic form of As⁺⁵ (> 95%). In both bottom and fly ashes, more than 95% of the total arsenic is present as As⁺⁵. Chromium in the milled coal and bottom ash is mostly non-toxic (Cr⁺³). The more toxic Cr⁺⁶ comprise less than 5% of the total Cr in the ESP fly ash and the stack-emitted ash. Nickel in milled coal and ashes is in the form of non-toxic Ni⁺², predominantly in coordination with oxygen.The emitted PAHs include acenapthene, fluorene, 2-methyl-fluorene, phenathrene, anthracene, fluoanthene, and pyrene; which are emitted from stack at the combined rate of 3.6 g/day. The concentrations of elements of environmental concern (As, Cd, Hg, Ni, and Pb) emitted to the atmosphere by the power plant in the zone of maximum impact at ground level are lower than those listed in the Health Guidelines of the USEPA and Canadian National Air Pollution Surveillance. This is based on stable meteorological conditions, down wind from the power plant for a maximum distance of 3 km.     

Mineral assemblages of the Francisco I. Madero Zn–Cu–Pb–(Ag) deposit, Zacatecas, Mexico: Implications for ore deposit genesis

The Francisco I. Madero deposit, central Mexico, occurs in the Mesozoic Guerrero Terrane, which hosts many ore deposits, both Cretaceous (volcanogenic massive sulfides) and Tertiary (epithermal and skarn deposits). It is hosted by a 600 m-thick calcareous-pelitic unit, of Lower Cretaceous age, crosscut by porphyritic dikes that strike NW–SE. A thick felsic volcanic Tertiary sequence, consisting of andesites and rhyolitic ignimbrites, unconformably overlies the Cretaceous series. At the base, the mineralization consists of several mantos developed within calcareous beds. They are dominantly composed of sphalerite, pyrrhotite and pyrite with minor chalcopyrite, arsenopyrite and galena. At the top of the orebody, there are calcic skarns formed through prograde and retrograde stages. The resulting mineral assemblages are rich in manganoan hedenbergite (Hd_75–28Di_40–4Jh_40–20), andraditic garnets (Adr_100–62Grs_38–0), epidote (Ep_95–36Czo_60–5Pie_8–0), chamosite, calcite and quartz. The temperature of ore deposition, estimated by chlorite and arsenopyrite geothermometry, ranges from 243° to 277 °C and from 300° to 340 °C, respectively. The pressure estimated from sphalerite geobarometry averages 2.1 kbar. This value corresponds to a moderately deep skarn and agrees with the high Cu content of the deposit. Paragenesis, P–T conditions and geological characteristics are compatible with a distal, dike-related, Zn skarn deposit. Its style of mineralization is similar to that of many high-temperature carbonate replacement skarn deposits in the Southern Cordillera.     

Estimation of Shallow Geothermal Energy Resource in Canada: Heat Gain and Heat Sink

Maps of shallow depth (down to −250 m) temperature distribution across Canada show large variability, related mainly to surface climatic forcing. Very small changes of temperature with depth in the upper 250 m are related to heat gained by the subsurface due to recent global warming. Temperature data compiled from precise temperature logs in equilibrium wells, and temperature time series from a network of meteorological stations, allow calculation of the available heat energy for heating in the cold period and for cooling in peak warm months. Utilization of this energy resource has the potential for significant CO₂ reduction in Canada. The geothermal energy stored in the ground can be used, with the help of heat pumps, for heating, given very low winter temperatures. The amount of potential heat available is vast. In Canada, south of permafrost border, the integrated value of potentially available heat during the heating season down to −50 m is 1.1 E21 J (1100 quads).     

Visualization of spatial patterns and temporal trends for aerial surveillance of illegal oil discharges in western Canadian marine waters

This paper examines the use of exploratory spatial analysis for identifying hotspots of shipping-based oil pollution in the Pacific Region of Canada’s Exclusive Economic Zone. It makes use of data collected from fiscal years 1997/1998 to 2005/2006 by the National Aerial Surveillance Program, the primary tool for monitoring and enforcing the provisions imposed by MARPOL 73/78. First, we present oil spill data as points in a “dot map” relative to coastlines, harbors and the aerial surveillance distribution. Then, we explore the intensity of oil spill events using the Quadrat Count method, and the Kernel Density Estimation methods with both fixed and adaptive bandwidths. We found that oil spill hotspots where more clearly defined using Kernel Density Estimation with an adaptive bandwidth, probably because of the “clustered” distribution of oil spill occurrences. Finally, we discuss the importance of standardizing oil spill data by controlling for surveillance effort to provide a better understanding of the distribution of illegal oil spills, and how these results can ultimately benefit a monitoring program.