A combined pyrolysis mass spectrometric and light microscopic study of peatified Calluna wood isolated from raised bog peat deposits

Stem wood of the Angiosperm Calluna vulgaris (Scotch heather), isolated at different depths from a selection of raised bog peat deposits, was chemically characterized using in-source pyrolysis mass spectrometry (Py-MS) and Curie-point pyrolysis gas chromatography mass spectrometry (Py-GC-MS). Light microscopy was performed to relate mass spectrometric characteristics with anatomical features. Peatified wood samples, isolated from increasing depth show a gradual decrease in carbohydrate content. This decrease in anatomically reflected in a selective removal of secondary cell wall material from the fibre-tracheids and wood parenchyma. During prolonged peatification a selective removal of hemicellulose sugars is observed, while a part of the cellulose fraction is preserved. This highly resistant cellulose is mainly located in the secondary cell walls of the vessels. The lignin macromolecule is preserved, but a gradual decrease in syringyl to guaiacyl ratio (S/G) is observed during peatification. Because no increase in catechol and phenolic compounds is observed, we conclude that S/G shifts are due to removal the of syringyl-rich secondary cell wall material and the retention of guaiacyl-rich compound middle lamella. Small chemical changes in the lignin macromolecule involve shifts in oxygen substitutions on the aliphatic side chains of the methoxyphenolics and the occurrence of aromatic acids.     

荷叶塘陨石:一个L3型普通球粒陨石的岩石学和地球化学特征

荷叶塘为一块我国降落的原始3型普通球粒陨石,因此具有重要研究意义。本文对荷叶塘陨石光薄片及粉末样品的岩石学、矿物学和全岩组成地球化学特征进行研究,为这块陨石的深入研究提供重要基础数据。研究表明荷叶塘陨石具L3型陨石岩石学特征,具典型的球粒陨石结构,球粒清晰,球粒结构类型多,基质重结晶程度低,组成模式为:球粒80vol%,金属和硫化物含量为5vol%,基质15vol%。矿物化学成分表明,该陨石球粒以Ⅰ型(贫铁型)球粒为主,橄榄石Fa0.41-34.1(PMD=51),低钙辉石Fs1.82-27.2(PMD=88),Wo0.18-3.13(PMD=103),铁纹石中Co含量平均0.62%(PMD=20),矿物成份不均一程度高,橄榄石矿物结晶颗粒内部化学成分变化大,呈正环带分布,与岩浆型结晶顺序一致,球粒与基质及间隙物成分明显不同,表现为不同物质来源。化学成分全岩分析结果显示,荷叶塘陨石亲石、亲铁元素含量均为L型陨石特征。依据以上岩石矿物学和化学组成特征,依照陨石亚分类参数,将其类型划分为L3.4型普通球粒陨石。冲击变质程度S2,风化程度W1。研究结果表明荷叶塘陨石为一块受后期水、热蚀变和风化影响较少的原始类型陨石。组成矿物成分极不均一,在矿物晶体内部,球粒内部及球粒与基质间均有明显变化。     

冀东、五台和吕梁地区条带状铁矿的稀土元素特征及其地质意义

详细报道了冀东、五台和吕梁地区条带状铁矿全岩样品的稀土元素分析结果。结果表明,研究区BIF具有非常相似的特征：稀土总量均较低;经页岩标准化的稀土元素配分模式均呈现轻稀土亏损、重稀土富集的特征;Y/Ho比值较高;具有明显的Eu、Y、La的正异常,且这些特征表明研究区BIF的稀土元素来源于火山热液和海水的混合溶液。虽然BIF均显示Eu正异常,但不同类型、不同沉积年龄BIF的铕异常程度不同：与吕梁地区Superior型铁矿相比,冀东和五台地区的Algoma型铁矿显示了更大的Eu正异常;并且自中太古代-新太古代-古元古代,BIF的铕正异常逐渐减小,这可能反映了随着BIF沉积年龄的减小,进入到该地区海水中的高温热液流体逐渐减少;同时,研究区BIF缺乏明显的Ce负异常,可能暗示在BIF沉积时海水的氧化还原状态为缺氧环境。     

桑托斯盆地L构造Aptian期火山喷发旋回特征与Itapema组介壳灰岩沉积

桑托斯盆地裂陷初期岩浆活动与储层发育关系密切。本文以盆地L区块火成岩-介壳灰岩复合体为研究对象,通过对火成岩岩石学、年代学测试及钻井、测井资料分析等,首次明确了桑托斯盆地裂陷初期岩浆活动特征及其对介壳灰岩沉积过程的控制,并指出介壳灰岩储层的分布特征。L区块内火成岩分属晚白垩世Santonian期—Campanian期和早白垩世Aptian两期岩浆活动产物,并以Aptian期为主,至少经历了7次不连续喷发和3次侵入过程,形成了块状玄武岩、杏仁状玄武岩和玻基斑状玄武岩(含再沉积玻基斑状玄武岩)等喷发相火成岩和以辉绿岩(局部属粗玄岩)、煌斑岩形式产出的侵入相火成岩。Aptian期岩浆多期活动重塑了古地貌,形成了局部构造凸起,促成并控制了下白垩统Itapema组至少6期介壳灰岩沉积,最终形成了～620 m厚火成岩-介壳灰岩复合体。介壳灰岩储层呈透镜体形状,以“散点式”不连续分布在Aptian期盆内古隆、古断阶(坡)等区域,横向连续性差,垂向连通性受限,其发育规模和质量受古地貌及水深条件等影响。     

Isotopic Tracing of Trophication Processes over the Last Millennia on Lake Chenghai

Multi-parameter studies (stable isotopes in carbonate and organic matter, pigment,organic carbon and nitrogen contents) from a 660-yr continuous sediment core from Lake Cheng-hai, a closed, eutropic lake in southern China, provide information on lake historical eutrophi-cation. During the last 660 years, great changes have taken place in productivity and eutrophi-cation of Lake Chenghai in response to human activities. In 1690, the productivity of the lakebegan to increase as Lake Chenghai became closed from agriculture in the lake‘‘ s watershed. In 1942, Lake Chenghai evolved to eutrophic state, marked by an increase in organic carbon, ni-trogen, CaC03, pigment contents and obvious negative values of stable isotopes, which is more or less simultaneous with the large-scale population immigration during the period. In 1984, in-tensive human activities induced modern lacustrine productivity and eutrophic level. Human-in-duced trophic changes during the past few decades have affected the Lake Chenghai ecosystem tosuch an extent that it has never experienced before in the last 660 years.     

桐柏山L构造岩形成机制构造解析及其对造山带演化的制约

桐柏杂岩中发育一套典型的L构造岩,其构造位置位于桐柏造山带核部,被两条近似对称的韧性剪切带所夹持,北侧剪切带左旋,南侧剪切带右旋。由于L构造岩构造位置特殊,其位于剪切带、桐柏背形、桐柏穹窿等多种构造体的交叉部位,L构造岩的构造成因解析可以为桐柏造山带的形成演化提供重要制约。通过对桐柏造山带L构造岩的构造成因机理解析和其变形温压条件的研究,同时结合前人对桐柏山其它主要构造单元的研究,我们提出,桐柏山L构造岩的形成主要受其南北两侧两条韧性剪切带控制,传统意义的桐柏杂岩体白垩纪之前与南北一体的韧性剪切带沿近似东西方向发生管状韧性剪切,剪切作用形成了一套典型的L构造岩。L构造岩的形成指示了桐柏山单元可能经历了一期中下地壳物质的管状的韧性的向东剪切流动,后期白垩纪桐柏山核部的L构造岩经历了大规模的岩浆上升与浮力增加,该L构造岩同剪切带一起发生隆升但管状剪切构造特征并未被改造,随着不均匀隆升桐柏山出现了现今的几何学特征。L构造岩反映出管状剪切形成了现今桐柏造山带近东西向线状构造样式的主体。     

主成分分析在航空瞬变电磁去噪中的应用

由于航空瞬变电磁二次场数据是一种宽频带信号且幅度较小,因此常常受到随机噪声、天电噪声以及人文噪声的影响。研究针对上述噪声的去噪方法,可以提高处理和解释的精度。这里给出了基于主成分分析的航空瞬变电磁去噪方法,首先应用主成分分析方法对叠加抽道后的单测点衰减曲线进行分解,然后应用曲线趋势对比法和L曲线法对分解后的成分进行分析,确定出有效信号成分,最后使用这些有效信号成分进行重构,从而达到抑制噪声的目的。模拟信号分析以及实测数据的实验结果表明,应用主成分分析法处理航空瞬变电磁数据,在保持反映地下介质分布的有效信号幅度基本不变的条件下,能有效抑制天电噪声和人文噪声,为保幅处理和解释奠定了良好的基础。     

Suppressing non‐Gaussian noises with scaled receiver wavefield for reverse‐time migration: comparison of different approaches

Numerical implementation of the gradient of the cost function in a gradient‐based full‐ waveform inversion (FWI) is essentially a migration operator used in wave equation migration. In FWI, minimizing different data residual norms results in different weighting strategies of data residuals at receiver locations prior to back‐propagation into the medium. In this paper, we propose different scaling methods to the receiver wavefield and compare their performances. Using time‐domain reverse‐time migration (RTM), we show that compared to conventional algorithms, this type of scaling is able to significantly suppress non‐Gaussian noise, i.e., outliers. Our tests also show that scaling by its absolute norm produces better results than other approaches.     

厚层黄土状土中扩底墩竖向承载性状

根据同一试验场地厚层非湿陷性黄土状土中8根大直径扩底墩、2根等直径桩的竖向承载力静载试验,对扩底墩的竖向承载性状进行了研究。结果表明,在其他条件相同时,随扩底墩直径D的增大,虽单位面积极限端阻力有不同程度的降低,但墩的极限承载力Qu增大;当D和墩身直径d不变时,总极限侧阻力所占墩顶极限荷载的百分比随长径比L/d的增大而增大;d不变时,随长径比L/D的增加,各墩的墩顶荷载呈起伏变化,总端阻所占百分比（比等直径桩大）相应降低,平均极限侧阻力（比等直径桩小）相应增大,而L/D = 3时,其承载性状较好;在扩底墩墩身直径d与等直径桩相同、入土长度相当的情况下,前者承载力比后者大,且沉降小。