Determination of copper complexation in surface microlayer of Daya Bay and Jiaozhou Bay

1 INTRODUCTION Bioavailability to the biota and the biogeo-chemistry of trace metals in marine environment areaffected by their chemical speciation in the naturalsystem (Bruland et al., 1991; Van den Berg andDonat, 1992; Wells et al., 1998). Therefore, thesetwo parameters, the ligands concentrations andconditional stability constants, are important todetermine the complexing capacity. Sea surface microlayer (SML), the thin interfa-cial boundary between ocean and atmosphere, playsan imp…     

Pixel‐scale evaluation of SSM/I sea‐ice algorithms in the marginal ice zone during early fall freeze‐up

Observed reduction in recent sea ice areal extent and thickness has focused attention on the fact that the Arctic marine system appears to be responding to global‐scale climate variability and change. Passive microwave remote‐sensing data are the primary source underpinning these reports, yet problems remain in geophysical inversion of information on ice type and concentration. Uncertainty in sea‐ice concentration (SIC) retrievals is highest in the summer and fall, when water occurs in liquid phase within the snow–sea‐ice system. Of particular scientific interest is the timing and rate of new ice formation due to the control that this form of sea ice has on mass, energy and gas fluxes across the ocean–sea‐ice–atmosphere interface. In this paper we examine the critical fall freeze‐up period using in situ data from a ship‐based and aerial survey programme known as the Canadian Arctic Shelf Exchange study combined with microwave and optical Earth observations data. Results show that: (1) the overall physical conditions observed from aerial survey photography were well matched with coincident moderate‐resolution imaging spectroradiometer data and Radarsat ScanSAR imagery; (2) the shortwave albedo was linearly related to old ice concentration derived from survey photography; (3) the three SSM/I SIC algorithms (NASA Team (NT), NASA Team 2 (NT2), and Bootstrap (BT)) showed considerable discrepancies in pixel‐scale comparison with the Radarsat ScanSAR SICs well calibrated by the aerial survey data. The major causes of the discrepancies are attributed to (1) the inherent inability to detect the new thin ice in the NT and BT algorithms, (2) mismatches of the thin‐ice tie point of the NT2 algorithm, and (3) sub‐pixel ambiguity between the thin ice and the mixture of open water and sea ice. These results suggest the need for finer resolution of passive microwave sensors, such as AMSR‐E, to improve the precision of the SSM/I SIC algorithms in the marginal ice zone during early fall freeze‐up. Copyright © 2006 John Wiley & Sons, Ltd.     

Bulk organic δ13C and C/N ratios as palaeosalinity indicators within a Scottish isolation basin

Microfossils in isolation basin sediments are frequently used to reconstruct sea‐level change, but preservation problems and non‐analogue situations can limit their usefulness. Here we investigate the potential of stable carbon isotopes (δ¹³C) and C/N ratios from bulk organic matter, as an alternative proxy of salinity within isolation basin sediments from a basin in northwest Scotland. Within the Holocene sediment δ¹³C and C/N are determined largely by the mean weighted values of the predominant source of the organic material. Analysis of modern materials and comparison with the diatom record shows that the marine parts of the sequence are dominated by high δ¹³C and variable C/N. In the fresh water sequences the organic material is a mixture of both freshwater aquatic and terrestrial plant input that have relatively low δ¹³C and high C/N. The application of δ¹³C and C/N ratios in the studied basin in general follow the environmental change recorded by the diatoms and shows the potential of bulk organic matter in the investigation of salinity change in isolation basins. Copyright © 2005 John Wiley & Sons, Ltd.     

Annual cycle and budgets of nutrients in the Bohai sea

The environmental problems in the Bohai Sea have become more serious in the last decade. High nutrient concentration contributes much to it. A Sino-German cooperation program has been carried out to improve the understanding of the ecosystem by observations and modelling. A three-dimensional ecosystem model, coupled with a physical transport model, is adopted in this study. The simulation for the year 1982 is validated by the data collected in 1982/1983. The simulated annual mean nutrient concentrations are in good agreement with observations. The nutrient concentrations in the bohai Sea, which are crucial to the algal growth, are high in winter and low in summer. There are depletion from spring to summer and elevation from autumn to winter for nutrients. The nutrients’ depletion is a response to the consumption of the phytoplankton bloom in spring. Internal recycle and external compensation affect the nutrient cycle. Their contributions to the nutrient budgets are discussed based on the simulated results. Production and respiration are the most important sink and source of nutrients. The process of photosynthesis consumes 152 kilotons-P and 831.1 kilotons-N while respiration releases 94.5 kilotons-P and 516.6 kilotons-N in the same period. The remineralization of the detritus pool is an important source of nutrient regeneration, It can compensate 23 percent of the nutrient consumed by the production process. The inputs of phosphates and nitrogen from rivers are 0.55 and 52.7 kilotons respectively. The net nutrient budget is −3.05 kilotons-P and 31.6 kilotons-N.     

广东省应大力发展海洋牧场

综述了我国及广东省十多年来鱼虾种苗人工放流及人工鱼礁的投放情况，结合广东省广大海区的水温、盐度、ｐＨ值、海流、营养盐含量情况及天然饵料的种类、分布等，提出了除在大亚湾已设置了水产增殖站以外，还应该在广东东部的南澳和西部的湛江各设一个增殖站，会收到更大的效果。人工鱼礁应总结过去投放的经验，加强礁区管理，逐步解决投资与收益的关系问题，并进一步扩大投放人工鱼礁的地点和密度，把广东海区切实建成理想的海洋牧场。     

Relative sea‐level changes,glacial isostatic modelling and ice‐sheet reconstructions from the British Isles since the Last Glacial Maximum

While contributing <1 m equivalent eustatic sea‐level rise the British Isles ice sheet produced glacio‐isostatic rebound in northern Britain of similar magnitude to eustatic sea‐level change, or global meltwater influx, over the last 18 000 years. The resulting spatially variable relative sea‐level changes combine with observations from far‐field locations to produce a rigorous test for quantitative models of glacial isostatic adjustment, local ice‐sheet history and global meltwater influx. After a review of the attributes of relative sea‐level observations significant for constraining large‐scale models of the isostatic adjustment process we summarise long records of relative sea‐level change from the British Isles and far‐field locations. We give an overview of different global theoretical models of the isostatic adjustment process before presenting intercomparisons of observed and predicted relative sea levels at sites in the British Isles and far‐field for a range of Earth and ice model parameters in order to demonstrate model sensitivity and the resolving power available from using evidence from the British Isles. For the first time we show a good degree of fit between relative sea‐level observations and predictions that are based upon global Earth and ice model parameters, independently derived from analysis of far‐field data, with a terrain‐corrected model of the British Isles ice sheet that includes extensive glaciation of the North Sea and western continental shelf, that does not assume isostatic equilibrium at the Last Glacial Maximum and keeps to trimline constraints of ice surface elevation. We do not attempt to identify a unique solution for the model lithosphere thickness parameter or the local‐scale detail of the ice model in order to provide a fit for all sites, but argue that the next stage should be to incorporate an ice‐sheet model that is based on quantitative, glaciological model simulations. We hope that this paper will stimulate this debate and help to integrate research in glacial geomorphology, glaciology, sea‐level change, Earth rheology and quantitative modelling. Copyright © 2006 John Wiley & Sons, Ltd.     

记黄海、渤海海底发现的原始牛新亚种

本文记述的渤海,黄海海底发现的原始牛角心化石(3件),根据形态特征将其定名为Bos primigenius dalianensis subsp.nov.(原始牛大连亚种)。时代屆新生代第四纪晚更新世。这是我国首次于海底发现的原始牛化石。它的发现为探讨晚更新世时期黄海、渤海古地理环境,古气候条件,海水进退,冰期与间冰期的更替,哺乳动物的演化和迁徙提供了新的资料。     

THE DIVERGENCE-CONVERGENCE EFFECT OF SURFACE CURRENT AND ITS ACTION ON THE BOHAI SEA

The action of the wind field and the influence of topography can cause divergence or convergence of surface current. The existence of the divergence-convergence effect is proved and the dynamical significance of the divergent or convergent state and its link with many marine phenomena are pointed out. Divergence fields of surface current in the Bohai Sea in winter and summer are obtained by numerical modelling describing the divergence-convergence character of seasonally wind-driven current. The relation between the effect and seasonal marine phenomena is discussed. Study on the divergence-convergence effect of surface current (DCESC)can be an indirect method for testing the calculated results.