黄铁矿与沥青铀矿的共生条件及在沥青铀矿形成过程中所起作用的实验研究

高价铁与高价铀混合溶液在还原场中形成了共生的黄铁矿与沥青铀矿,该过程必须在弱酸性-中性-碱性介质中进行,其中在弱酸性至中性介质中易形成大的黄铁矿单晶。高价铀溶液流经黄铁矿矿区时,若在高温高压条件下,有新生的黄铁矿或白铁矿与沥青铀矿共生。黄铁矿还原六价铀形成沥青铀矿时,起还原作用的是二价硫。赤铁矿常与沥青铀矿共生,但它们是热液演化过程中不同阶段的产物,赤铁矿形成于体系氧逸度高的氧化环境,沥青铀矿形成于体系氧逸度低的还原环境,赤铁矿形成于沥青铀矿之前。     

Ra法找矿及其在异常评价中的应用

本文介绍带电收集片测定土等粉末样品的 Ra 含量来找 U 矿的方法,称为 Ra 法。此法灵敏度高,操作简便,成本低,可以使用~(210)Po 法曲仪器和铜片,便于推广使用。文中介绍了测 Ra 流程,测定误差和灵敏度.Ra 法在详查和区调阶段的用途。总结了深部盲矿、地表矿化和非矿异常地段上地表的 Ra、Po 和γ异常的特征,指明 Ra 法和 Po 法结合可用于评价异常,提高找深部铀矿的能力。     

古风化壳是碳酸盐岩一个重要的储集层(体)类型

大量含油气区的勘探开发证明，古风化壳是碳酸盐岩一个重要的储集层（体），作者以塔里木盆地下古生界古风化壳储集层（体）为基础，结合鄂尔多斯地区和任丘油田，从地层、岩矿组成、成岩作用、古岩溶、垂向结构、储集性能、测井曲线、地震反射和含油气性诸方面进行了详细研究，大量资料证明，古风化壳是经长期表生成岩作用形成的特有的地质体，其内部具有特有的分带性结构和含油气性，用岩溶并不能代表它的特殊性和整体概念，应黎     

Determination of arsenic(III) for the investigation of the microbial oxidation of arsenic(III) to arsenic(V)

Recent evaluations of acute and chronical toxicity of arsenic resulted in a reduction of the standard value for total arsenic from 40 μg/L to 10 μg/L in drinking water which will be valid in Germany after a transition period as from January 1996. Arsenic is well known as substance of deep groundwaters, mainly of geogenic origin and normally found as As(III) or As(V). As(V) is well removable by flocculation and filtration after adding iron salts. As(III), however, has to be oxidized first to As(V). Therefore, it is important for treatment techniques to be able to distinguish between As(III) and As(V). A modified determination of As(III) using flow injection analysis was installed and optimized in order to investigate whether As(III) may be oxidized to As(V) by bacteria in natural waters. The results showed that at 4°C, no As(III)-oxidation was observed within 14 days. At room temperature, however, in the bacteria-containing samples, an As(III)-oxidation was found starting after 3 to 7 days. After 14 days, no As(III) was left over. In contrast, in the sterile samples, no As(III)-oxidation could be observed within 14 days. These results demonstrated that microbial processes influence the oxidation of As(III) to As(V) in natural waters.     

Trace analysis of quaternary aminoalcohols as degradation products from softeners in wastewater

The sensitive and selective determination of polyalcohols without chromophores or fluorophores in the lower ppb-level is still an analytical task of high interest, especially in the field of environmental investigations. This paper describes a cation-exchange HPLC procedure for the separation and fluorescence detection of two quaternary ammonium compounds with polyalcoholic groups (degradation products of fabric softener) after derivatization with 9-fluorenylmethyl chloroformate (FMOC). Detailed experiments were carried out to determine optimum reaction conditions (pH, reaction time, temperature), linear range, detection limits, and kinetics of the reaction. The HPLC separation on a cation-exchange column includes a gradient program which provides complete separation from neutral compounds also reacting with FMOC and its hydrolysis products formed during the reaction in alkaline medium. High specificity for both investigated ammonium compounds with detection limits in the range of 1 ppb could be achieved.     

Geomorphic evolution of the Southern Alps,New Zealand

The Southern Alps are the topographic expression of late Cenozoic (<8 Ma ago) uplift of the crust of the leading edge of the Pacific plate in South Island, New Zealand. New fission track data on the basement exposed in the Southern Alps quantify the age, amount, and rate of rock uplift, and in combination with geomorphic parameters permit the construction of a new model of the geomorphic evolution of the Southern Alps. The model emphasizes the development over time and space of rock uplift, mean surface elevation, exhumation of crustal section, and relief. The earliest indications of mean surface uplift are between 4 and 5 Ma ago at the Alpine Fault. Mean surface uplift, which lagged the start of rock uplift, propagated southeastward from the Alpine Fault at a rate of 30 km/Ma. By about 4 Ma ago, exhumation had exposed greywacke basement adjacent to and east of the entire 300 km long central section of the Alpine Fault. At 3 Ma ago, greenschist was exposed in the southern parts of the Southern Alps near Lake Wanaka, and since then has become exhumed along a narrow strip east of the Alpine Fault. The model infers that amphibolite grade schist has been exhumed adjacent to the Alpine Fault only in the last 0·3 Ma. The age of the start of rock uplift and the amount and rate of rock uplift, all of which vary spatially, are considered to be the dominant influences on the development of the landscape in the Southern Alps. The Southern Alps have been studied in terms of domains of different rock uplift rate. At present the rate of rock uplift varies from up to 8–10 mm/a adjacent to the Alpine Fault to 0·8–1·0 mm/a along the southeastern margin of the Southern Alps. This spectrum can be divided into two domains, one northwest of the Main Divide where the present rock uplift rates are very high (up to 8–10 mm/a) and exceed the long-term value of 0·8–1·0 mm/a, and another to the southeast of the Main Divide where the long-term rate is 0·8–1·0 mm/a. A domain of no uplift lies immediately to the east of the Southern Alps, and is separated from them by a 1·0–1·5 km step in the basement topography. We argue that this spatial sequence of uplift rate domains represents a temporal one. The existing models of the geomorphic development of the Southern Alps—the dynamic cuesta model of J. Adams and the numerical model of P. Koons—are compared with the new data and evolutionary model. Particular constraints unrealized by these two earlier models include the following: the earlier timing of the start of rock uplift of the Southern Alps (8 Ma ago); the spatial variation in the timing of the start of rock uplift (8 Ma ago to 3 Ma ago); the lower long-term rock uplift rate (0·8–1·0 mm/a) of the Southern Alps for most of the late Cenozoic; the lag between the start of rock uplift and the start of mean surface uplift; and the patterns of the amounts of late Cenozoic rock uplift and erosion across the Southern Alps.     

TBP－（X－5）反相色谱分离m－NPF分光光度法测定铀

本文研究了以磷酸三丁酯为固定相，大孔聚乙烯苯（Ｘ－５型）为担体的浸渍树脂、垂直型反相色谱柱，对铀分离富集的基本性能，以及铀（Ⅳ）－间硝基苯基萤光酮（ｍ－ＮＰＦ）一氨三乙酸（ＮＴＡ）－吐温－８０显色体系的反应条件，提出了ＴＢＰ（Ｘ－５）分离，ｍ－ＮＰＦ－ＮＴＡ－吐温－８０光度法测定铀，经标准样品验证，结果满意。     

西藏扎布耶湖ZK91-2钻孔沉积特征与气候环境演化

扎布耶盐湖位于西藏高原腹地,1991年在其南部干盐滩中钻取了20m深湖相沉积,以5～10cm/个的密度进行高分辨率取样,详细探讨了沉积标志、矿物组合（尤其Mg、Ca、Li碳酸盐）、干旱与潮湿两种气候类型的元素组合等气候环境指标,推导了晚更新世以来该湖区湖面涨缩、水质咸谈及气温高低变化。     

A CASE OF MESOSCALE CONVECTIVE COMPLEX EVOLVING INTO A VORTEX*

A case of mesoscale convective complex(MCC) which evolved into a vortex is documented in this paper.As the MCC entered into the dissipating phase,a well-defined spirally banded structure became visible in the satellite image.The blackbody temperature(TBB) of the residual cold-cloud-shield indicates the vortex existed in the layer from 400 to 250 hPa.According to the upper air analysis,the upper level vortex was an anticyclone.The MCC-generated vortex was visualized in the satellite images because it was located in the subtropical high where the wind field was very weak.     

CLIMATIC CHARACTERISTICS OF EARTH-ATMOSPHERE OUTGOING LONGWAVE RADIATION OVER CHINA*

ERBE and ISCCP data are used to investigate the cloud forcing and latitude and atmospheric temperature effects on outgoing longwave radiation(OLR) in the earth-atmosphere system,and the similarity of OLR field to 500 hPa and surface effective radiation fields.Also,discussion is taken up of the OLR distribution on a nationwide basis,indicating that the winter(summer) OLR pattern is roughly a zonal type(asymmetrical saddle) with the annual pattern analogous to the January one.In the end the yearly OLR variation features are addressed on a regional basis.