济阳拗陷特殊生物降解油的初步研究

济阳拗陷草古100平19井奥陶系储层原油,饱和烃馏分均已损失殆尽,仅残余藿烷系列化合物;同时,芳烃馏分化合物也已损失殆尽,仅残余三芳甾烷系列化合物。上述芳烃化合物俱已损失殆尽的蚀变特征,在相关文献中的报道较为少见。原油中不受水洗作用影响的正构烷烃和不受生物降解作用影响的有机硫化合物(苯并噻吩和二苯并噻吩)均已损失殆尽,显然暗示了原油蚀变是遭受水洗作用和生物降解作用共同作用的结果。原油芳烃馏分的“UCM”鼓包幅度明显大于饱和烃馏分的“UCM”鼓包,暗示了芳烃化合物的降解速率平行甚至超过饱和烃的降解速率。原油中低分子量芳烃化合物的快速降解,暗示了油藏可能是在氧化条件下而非在还原条件下发生蚀变的。     

Tectonic evolution of the West Kunlun Orogenic Belt along the northern margin of the Tibetan Plateau:Implications for the assembly of the Tarim terrane to Gondwana

The West Kunlun orogenic belt(WKOB) along the northern margin of the Tibetan Plateau is important for understanding the evolution of the Proto-and Paleo-Tethys oceans. Previous investigations have focused on the igneous rocks and ophiolites distributed mostly along the Xinjiang-Tibet road and the China-Pakistan road, and have constructed a preliminary tectonic model for this orogenic belt. However, few studies have focused on the so-called Precambrian basement in this area. As a result, the tectonic affinity of the individual terranes of the WKOB and their detailed evolution process are uncertain. Here we report new field observations, zircon and monazite U-Pb ages of the "Precambrian basement" of the South Kunlun terrane(SKT) and the Tianshuihai terrane(TSHT), two major terranes in the WKOB. Based on new zircon U-Pb age data, the amphibolite-facies metamorphosed volcanosedimentary sequence within SKT was deposited during the late Neoproterozoic to Cambrian(600-500 Ma), and the flysch-affinity Tianshuihai Group, as the basement of the TSHT, was deposited during the late Neoproterozoic rather than Mesoproterozoic. The rock association of the volcano-sedimentary sequence within SKT suggests a large early Paleozoic accretionary wedge formed by the long-term lowangle southward subduction of the Proto-Tethys Ocean between Tarim and TSHT. The amphibolitefacies metamorphism in SKT occurred at ca. 440 Ma. This ca. 440 Ma metamorphism is genetically related to the closure of the Proto-Tethys Ocean between Tarim and the Tianshuihai terrane, which led to the assembly of Tarim to Eastern Gondwana and the final formation of the Gondwana. Since the late Paleozoic to early Mesozoic, the northward subduction of the Paleo-Tethys Ocean along the HongshihuQiaoertianshan belt produced the voluminous early Mesozoic arc-signature granites along the southern part of NKT-TSHT. The Paleo-Tethys ocean between TSHT and Karakorum closed at ca. 200 Ma, as demonstrated by the monazite age of the paragneiss in the Kangxiwa Group. Our study does not favor the existence of a Precambrian basement in SKT.     

150kaBP以来巴丹吉林沙漠东南区域地层序列的新研究

巴丹吉林沙漠东南部边缘查格勒布鲁剖面中更新统/上更新统下部、上更新统下部/上更新统上部和上更新统上部/全新统的地质界线依次发生在59AGS/60L、39FD/40G和9L/10FD之沉积界面上。其时限依次大致为150kaBP、75kaBP和10kaBP,该剖面记录了150kaBP以来25个旋回的沙漠与湖相等沉积交替变更的历史过程。通过该剖面粒度和SiO₂、Al₂O₃、Fe₂O₃、FeO在地层中的分布特征、软体动物化石指示的古生态等综合研究表明,所述这些沉积旋回是自那时以来,在北半球冰期间冰期气候波动影响下,冬夏古季风往复更迭所导致的非季风沙区沙漠期与间沙漠期多次正逆交替演变的结果。     

TMS320C25高速A/D接口电路的设计

本文介绍了TMS320C25高速接口电路的设计方法,并以高速A/D接口为例,说明接口电路设计中的一些技巧。这对充分利用TMS320C25的硬件资源有非常重要的意义。     

Origin and occurrence of 25-norhopanes: a statistical study

The alkane fraction of more than 200 rocks, biodegraded oils and non-biodegraded oils, have been analysed by means of computerized GC-MS, in order to investigate the effect of natural biodegradation on the occurrence of “demethylated hopanes”, i.e. 17α-25-norhopanes. The results obtained indicate that 25-norhopanes are preexisting biomarkers the concentration of which is enhanced by selective biodegradation of more readily degradable homologs, i.e. regular hopanes, rather than by demethylation of hopanes in reservoirs. However, the use of 25-norhopane enrichment as a palaebiodegradation indicator in apparently non-biodegraded oils is still valuable providing the initial background content in the corresponding source rocks is known. Furthermore, 25-norhopanes appear to be diagnostic of specific environmental conditions (marine and lacustrine source rocks, dysoxic and not very hypersaline). Lastly, one other (novel) bacterially resistant rearranged hopanoic compound, namely a C₂₉ neohopane, is applicable for both biodegradation and maturation evaluation.     

Organic geochemistry of Cuban oils—I. The northern geological province

The isoprenoid, hopanoid and steroid compositions of 15 oils from the most productive oil fields in Cuba were studied to determine source-rock depositional environments and organic matter sources. The oils, which are from the northern geological province of Cuba and can be defined by the position with respect to the overthrust belt, can be grouped into two families: those from the Remedios (1) and those from the Placetas (2) tectonostratigraphic units.Remedios oils contain 17α(H)-diahopane, high relative amounts of 18α(H)-22,29,30-trisnorneohopane and diasteranes, which is indicative of generation from clay-rich source rocks. The crude oils of the Placetas Unit exhibit a sterane/hopane composition consistent with a carbonate origin. Nevertheless, these polycyclic hydrocarbons exhibit significant changes in composition, indicating that several organic matter sources, e.g. a carbonate/evaporitic origin of Varadero and Varadero Sur oils, have contributed to the oils from this Unit. The Remedios oils are more mature [evaluated from the and sterane indices] than the Placetas oils.A wide range of biodegradation levels are encountered in these oils (from 0 to 7–8 using the scale derived by Volkman et al. (1983). The high relative abundance of 25-norhopanes is a distinctive feature of Remedios oils. The presence of these compounds in lightly biodegraded or nondegraded oils corresponds to a mixing of paleobiodegraded oil with more recently sourced nondegraded oil in the reservoir. The most biodegraded oil, Cantel, exhibits and sterane ratios, and hopane ratios that have been altered by microbial attack.     

面向带洞面状对象间的拓扑关系描述模型

为研究带洞面状对象间的拓扑关系,提出了一种25IM(25交集模型)。以点集拓扑理论为基础,对带洞面状区域的内部、边界和外部进行定义。分析了9IM(9交集模型)在表达带洞面状对象间拓扑关系方面存在的问题,将带洞面状对象分为内部、外边界、内边界、外边界外部、内边界外部共5部分,提出了一种5×5的矩阵模型,即25IM。基于点集拓扑理论,定义了8条规则来排除不符合逻辑的拓扑关系。基于25IM,对8种基本拓扑关系:相离、相接、重叠、覆盖、包含、相等、被覆盖和被包含,进行细分描述。结果表明,本文提出的25IM能够更为详细地表达带洞面状对象间的拓扑关系。     

极端生物降解沥青中8,14- 开环藿烷系列及其地球化学意义

借助色谱- 质谱（GC- MS）和色谱- 质谱- 质谱（GC- MS- MS）分析,对黔南坳陷凯里残余油藏凯棠和洛棉剖面上储层沥青中的烃类组成进行了系统分析,以判断其所遭受生物降解作用的程度,探寻在极端降解原油中是否还存在原生生物标志物,为这类原油的油源研究开拓新的途径和方法。结果表明：凯棠剖面上的储层沥青中尽管仍可检测到较为完整的C19- 30三环萜烷和C27- 35藿烷系列,但C19- 29脱甲基三环萜烷系列和C26- 34 25- 降藿烷系列丰富而完整,甾烷系列中C21- 22低分子量甾烷和重排甾烷优势明显,这一系列特征表明这些沥青遭受了剧烈生物降解作用的改造。但三芳甾类仍保存完好,依据原油生物降解程度的评判标准,判断其生物降解级别介于8~9级之间。洛棉剖面上的储层沥青中藿烷系列基本消失殆尽,三环萜烷系列及其脱甲基产物和25- 降藿烷系列的分布因极端生物降解作用而发生显著变异,某些化合物如C23T、C24T、C23NTE和C28- 29NH成为优势成员;甾烷系列中C21- 22低分子量甾烷占绝对优势,三芳甾类完全消失,据此判断该剖面上沥青的生物降解级别已达到10级或更严重。由于这两个剖面上的沥青遭受了极端生物降解作用的改造,常用的甾、萜类生物标志物完全失去了实用价值。但是,在所分析的这些沥青中都检测到三个系列的C27- 35 8,14- 开环藿烷系列,它们与塔里木盆地塔中地区海相端元油中存在的同类标志物的分布特征相似。正常海相端元油和极端生物降解沥青中同时检测到这三个系列的8,14- 开环藿烷,这一事实表明这类生物标志物在成因上具有原生性,而与生物降解作用无关。此外,在极端生物降解作用沥青中的完好保存,表明它们具有极强的抗生物降解能力,因而它们在此类原油的油源研究中可能具有潜在的实用价值。     

北极冰海耦合模式对两种不同大气再分析资料响应的分析

本文中我们比较了Climate Forecast System Reanalysis(CFSR)高分辨率的再分析数据集和低分辨率的Japanese 25-year Reanalysis Project(JRA25)再分析数据集在向下短波辐射、向下长波辐射、10m风场、近地面气温、降水、湿度上的不同,发现二者差异最大的为降水数据,其次为向下短波辐射数据、向下长波辐射数据。用这两个数据集驱动同一冰海耦合模式,CFSR强迫的海冰、北冰洋中层水和加拿大海盆温盐结构与实测相比有很大差距,等密度面上的地转流速在加拿大海盆和欧亚海盆比JRA25强迫的结果高20%,同时等密度面的深度偏深、位温偏高,在弗拉姆海峡的流通量也比海洋再分析数据Simple Ocean Data Assimilation(SODA)偏多。CFSR的向下辐射数据更加接近实测,采用此数据的敏感性实验模拟结果与实测符合的更好。对于海冰的模拟,云量起着至关重要的作用,降水带来的淡水通量通过影响大西洋入流水携带的热量进而影响到冰区。此外,CFSR过量的降水也是二者对于北冰洋温盐结构、弗拉姆海峡流通量以及地转流强度模拟产生偏差的主要原因。尽管风场的分辨率不同,在海盆尺度上对于海冰和海水温盐结构的影响并不大。     

长白山圆池泥炭沼泽演变及环境信息记录

通过分析长白山圆池泥炭剖面总有机碳含量、总正构烷烃含量、奇偶优势指数、(C23+C25)含量和2C31/(C27+C29)比值,讨论了泥炭发育不同时期植物输入情况,同时结合210Pb测年建立的年代序列来探讨该区的气候变化规律.研究结果显示,约1400年前,气候干冷,圆池尚没有出现沼泽化;1400年开始,气候稍暖,少量植物输入,圆池开始沼泽化;约从1860年至今,气候逐步转暖,大量植物输入,圆池沼泽化速度加快.