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51.
Celestite formation, bacterial sulphate reduction and carbonate cementation of Eocene reefs and basinal sediments (Igualada, NE Spain) 总被引:5,自引:0,他引:5
Conxita Taberner James D. Marshall† James P. Hendry‡ Catherine Pierre§ & M. F. Thirlwall¶ 《Sedimentology》2002,49(1):171-190
Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO4) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr2+ and SO42? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO42? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, 87Sr/86Sr data also suggest that Sr2+ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in 18O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits. 相似文献
52.
Abstract: Carbonate rocks of Cambrian (18 samples) and lower-middle Ordovician (11 samples) ages from South Korea were analyzed for sulfur contents of structurally substituted sulfate (SSS) and sulfides and their δ34 S values. The δ34 S values of SSS ranging from +25.9 to +45.2 permil, are averaged as +33.6 and +33.5 permil for the Cambrian and Ordovician rocks, respectively, which indicate high δ34 S values of the Cambro-Ordovician seawater. The SSS contents in the carbonate rocks are low being 2.9 to 17.3 ppm S (averaged as 7.0 ppm S). Sulfide sulfur, on the contrary, is much abundant containing 3 to 1,880 ppm S and the δ34 S values range widely between –17.6 and +31.1 permil. Sulfide sulfur of the studied rocks excluding impure carbonates has an average content of 187 ppm S and δ34 S value of +12.8 permil (n=24). The estimated δ34 S (sulfate–sulfide) values, which range from 13.8 to 25.4 permil in general with a few exceptions from 36.5 up to 52.3 permil for some impure carbonates, may provide evidence for the persistent oceanic anoxia with its temporary recovery during the Cambro-Ordovician time.
The SSS and sulfide sulfurs have often higher δ34 S values than the Mesozoic-Cenozoic ore sulfur (Ishihara et al., 2000). Since carbonate rocks are very reactive with circulating hydrothermal ore solution, high δ34 S values of the Korean ore deposits might be caused to some extent by 34 S enrichment from the host carbonates, resulting in the low SSS contents observed. 相似文献
The SSS and sulfide sulfurs have often higher δ
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54.
Antonio Longinelli Paola IacuminMichele Ramigni 《Earth and Planetary Science Letters》2002,203(1):445-459
Belemnite guards of Cretaceous and Jurassic age were found to contain varying amounts of quartz deposited both on the external surface and inside the rostrum. The oxygen isotopic composition of coexisting carbonate, quartz and phosphate from the same rostrum was measured according to well-established techniques. None of these compounds showed isotopic values in equilibrium with one another. Assuming δ18O values of the diagenetic water within the range of meteoric waters, the δ18O(SiO2) yield temperatures in agreement with the apparent secondary origin of this phase. The δ18O(CO32−) range, with a certain continuity, between −10.8 and +0.97 PDB-1 with most of the intermediate values being within the range of the carbonate isotopic values of Mesozoic fossils. The most positive isotopic results obtained from phosphate are close to +23/+24‰ (V-SMOW). They can hardly be related to a secondary origin of the phosphate, or to the presence of diagenetic effects, since these results are among the most positive ever measured on phosphate. As far as we know there is no widespread diagenetic process determining an 18O enrichment of phosphate. The very low concentration of phosphate did not allow the determination of its mineralogical composition. All the available δ18O(PO43−) values from belemnite and non-belemnite fossils of marine origin of Tertiary and Mesozoic age are reported along with the newly measured belemnites. The following conclusions may be drawn from the data reported: (1) the pristine oxygen isotope composition of fossil marine organisms (either carbonate or phosphate) may easily undergo fairly large changes because of oxygen isotope exchange processes with diagenetic water; this process is apparent even in the case of geologically recent fossils; (2) the δ18O(PO43−) of belemnite rostra seems to be, at least in the case of the most positive results, in isotopic equilibrium with environmental water because of the similarity between the results from Cretaceous belemnites and the results from Cretaceous and Lower Tertiary pelecypods and fish teeth; 3) if so, the only feasible interpretation that can be suggested for the 18O enriched data is the possibility of a relatively large variation of the oxygen isotopic composition of ocean paleowater from Jurassic to recent time. 相似文献
55.
2001年11月14日新疆-青海交界8.1级地震 总被引:3,自引:0,他引:3
简要介绍了2001年11月14日新疆-青海交界8.1级地震的预测情况,给出了中、美、日等对此次地震的震源参数测定和震源机制,以及余震的分布和加卸载响应比随时间的变化。进而对震区近期地震趋势进行预测。 相似文献
56.
57.
Shear wave statics using receiver functions 总被引:1,自引:0,他引:1
58.
59.
PowerBuilder 8.0中C/S模式应用过渡到B/S模式应用的实现技术 总被引:1,自引:0,他引:1
简要分析了PowerBuilder 8.0中各种B/S解决方案的优劣,探讨了适用于已有C/S模式应用过渡到B/S模式应用的实现方法,以及利用ASP技术实现对不同类型的客户测览器隐藏底层实现方法的技术,并给出了C/S模式应用过渡到B/S模式应用的一个实例。 相似文献
60.
数字地籍测绘是目前土地管理部门的首选方案,需要制定街坊划分、界址线设定、工作底图与采集草图一体化作业、数据文件管理、街坊线、图斑的绘制等技术措施。 相似文献