河南板厂银多金属矿床钾长石氩-氩年龄及其地质意义

河南内乡板厂矿床通过近年来的勘查工作,为一大型斑岩-热液型银铜铅锌(钼)矿床.本文对该矿床斑岩型铜矿石中钾长石进行了Ar-Ar定年,获得两个年龄坪:900～1150℃年龄坪包括了43.4%的39Ar,坪年龄为(148.1±1.6)Ma,反等时线年龄为(145.7±2.3)Ma;1200～1450℃年龄坪包括了48.8%的39Ar,坪年龄为(161.0±1.6)Ma,反等时线年龄(159.0±14.0)Ma.前者代表了该矿床的成矿年龄,后者代表了含矿斑岩的成岩年龄.该二阶段年龄谱特征反映了板厂矿床成岩成矿的阶段性.在我国不少矿区的Ar-Ar法年龄谱上均有多坪显示,这与我国许多矿区成矿作用和构造事件的多期多阶段特征一致.     

Origin of Paleofluids in Dabashan Foreland Thrust Belt:Geochemical Evidence of 13C,18O and 87Sr/86Sr in Veins and Host Rocks

In the last ten years, with important discoveries from oil and gas exploration in the Dabashan foreland depression belt in the borderland between Shanxi and Sichuan provinces, the relationship between the formation and evolution of, and hydrocarbon accumulation in, this foreland thrust belt from the viewpoint of basin and oil and gas exploration has been studied. At the same time, there has been little research on the origin of fluids within the belt. Based on geochemical system analysis including Z values denoting salinity and research on δ13C, δ18O and 87Sr/86Sr isotopes in the host rocks and veins, the origin of paleofluids in the foreland thrust belt is considered. There are four principal kinds of paleofluid, including deep mantle-derived, sedimentary, mixed and meteoric. For the deep mantle-derived fluid, the δ13C is generally less than ?5.0‰PDB, δ18O less than -10.0‰PDB, Z value less than 110 and 87Sr/86Sr less than 0.70600; the sedimentary fluid is mainly marine carbonate-derived, with the δ13C generally more than ?2.0‰PDB, δ18O less than ?10.0‰PDB, Z value more than 120 and 87Sr/86Sr ranging from 0.70800 to 0.71000; the mixed fluid consists mainly of marine carbonate fluid (including possibly a little mantle-derived fluid or meteoric water), with the δ13C generally ranging from ?2.0‰ to ?8.0‰PDB, δ18O from ?10.0‰ to ?18.0‰ PDB, Z value from 105 to 120 and 87Sr/86Sr from 0.70800 to 0.71000; the atmospheric fluid consists mainly of meteoric water, with the δ13C generally ranging from 0.0‰ to ?10.0‰PDB, δ18O less than ?8.0‰PDB, Z value less than 110 and 87Sr/86Sr more than 0.71000. The Chengkou fault belt encompasses the most complex origins, including all four types of paleofluid; the Zhenba and Pingba fault belts and stable areas contain a simple paleofluid mainly of sedimentary type; the Jimingsi fault belt contains mainly sedimentary and mixed fluids, both consisting of sedimentary fluid and meteoric water. Jurassic rocks of the foreland depression belt contain mainly meteoric fluid.     

南秦岭钡成矿带重晶石与毒重石成矿特征

在我国扬子地块北缘南秦岭一带的早古生代硅质岩建造中,存在一大批重晶石矿床和毒重石矿床,构成世界上极为罕见的大型钡成矿带。根据流体包裹体显微测温分析,重晶石流体包裹体均一温度峰值低于毒重石流体包裹体峰值。这些矿床中重晶石的3δ4S值比同期海水3δ4S值高(除去文峪矿区重晶石一个3δ4S值与同期海水3δ4S值接近),表明当时细菌对硫酸盐的还原作用引起了重S的富集。各钡矿床中的毒重石有各自的1δ3C和1δ8O值范围,毒重石中的C来自有机质事件反应。根据热力学计算表明,小于162.42℃的温度有利于形成重晶石矿石;在温度高于162.42℃时,海水中积累充足的CO32-(来自有机事件)有利于形成毒重石矿石。在重晶石矿床形成的晚期,如出现贫Ba2+热液,且海水中积累足够的CO32-和温度高于162.42℃,CO32-可以交代重晶石中的SO42-,形成交代成因的毒重石。     

俄罗斯远东岗仁地体金铜矿床地质、地球化学特征及其LA-ICP-MS锆石U-Pb年龄

岗仁地体位于额尔古纳超地体北部边缘,蒙古—鄂霍茨克构造带南部,该区分布着大量的大型、超大型金矿床,这些矿床在成因上与中酸性侵入岩和浅成次火山岩关系密切。岩石地球化学研究表明,花岗闪长岩-闪长岩组合明显富集大离子亲石元素、不相容元素和轻稀土元素,亏损高场强元素和重稀土元素。球粒陨石标准化稀土配分模式为轻稀土元素富集、重稀土元素亏损的右倾型,具有微弱的负Eu异常或基本无Eu异常,无Ce异常,元素地球化学性质反映出花岗闪长岩-闪长岩组岩浆具有壳幔混合的特征,且形成于大陆边缘的火山弧环境。LA-ICP-MS锆石U-Pb测年结果揭示,皮奥涅尔金银矿床含矿闪长玢岩的206Pb/238U年龄加权平均值为113.8±2.0Ma,博尔古利坎铜金钼矿床赋矿二长闪长斑岩的206Pb/238U年龄加权平均值为112.7±2.8Ma,与皮奥涅尔金银矿床和博尔古利坎铜金钼矿床成矿有关的奥列佳花岗闪长岩体的年龄分别为117.2±1.3Ma和117.0±3.6Ma。由此可知,皮奥涅尔金银矿床和博尔古利坎铜金钼矿床形成于燕山早期,与中国黑龙江地区三道湾子金矿、东安金矿等金矿床形成时代一致。     

阿尔泰造山带南缘昆格依特岩体LA-ICP-MS锆石U-Pb年代学、岩石成因及其地质意义

昆格依特岩体出露于阿尔泰造山带南缘青河县大青格里河昆格依特一带,主要为角闪黑云英云闪长岩。LA-ICP-MS锆石U-Pb定年结果显示,锆石的²⁰⁶Pb/²³⁸U年龄加权平均值为(403.4±7.4)Ma,表明该岩体形成于早泥盆世。岩体的SiO₂含量介于52.39%~71.89%之间,里特曼指数为0.68~1.53,A/CNK 值为0.76~1.06,属中钾、钙碱性、准铝质-弱过铝质岩石。具有富集Cs、Rb、Th、U等大离子亲石元素和轻稀土元素,相对亏损Nb、Ta、Hf、Ti等高场强元素和重稀土元素,弱的负Eu异常(δEu=0.56~0.86)的岛弧岩浆岩特征。结合区域地质资料,认为阿尔泰造山带南缘早泥盆世昆格依特岩体形成于活动大陆边缘的陆缘弧构造环境,是古亚洲洋俯冲过程中幔源的基性岩浆底侵下地壳使之熔融,并发生了岩浆混合和分异作用的产物。     

江南造山带西南段梵净山地区镁铁质-超镁铁质岩:形成时代、地球化学特征与构造环境

梵净山地区位于江南造山带的西南缘,这里新元古代的镁铁质-超镁铁质岩浆岩广泛发育,岩性包括枕状熔岩、超镁铁质-镁铁质岩床群以及浅成侵入的辉长岩,成分属拉斑玄武岩系列。其中枕状熔岩以富集轻稀土元素和Rb、Ba、Th、U等强不相容元素,亏损高场强元素Nb和Ta,低的εNd(t)值为特征,明显不同于洋脊玄武岩,推测其成因可能与富集型地幔的部分熔融有关,形成于与俯冲有关的弧后小洋盆环境。超镁铁质-镁铁质岩床群主要由辉绿岩和碳酸辉橄岩组成,其中超镁铁质岩床群中出现大量的原生碳酸盐矿物,指示它们形成于拉张(甚至裂谷)的构造环境。辉长岩可能是区内最晚形成的岩浆岩,其SHRIMP锆石U-Pb年龄为821±4Ma。由枕状熔岩经超镁铁质-镁铁质岩床群到辉长岩,高场强元素Nb和Ta的亏损程度减弱、轻稀土元素的富集程度降低、εNd(t)值由负值变为正值,指示随时间的由早到晚,来自亏损地幔的物质不断增加。推测梵净山地区新元古代岩浆作用的顺序大致为:枕状熔岩(～840Ma)→白云母花岗岩(～838Ma)→碳酸超镁铁质岩床群→镁铁质岩床群→辉长岩(～821Ma),构造环境由俯冲-碰撞到拉张-裂谷。     

Caledonian high-pressure metamorphism in the Strona-Ceneri Zone (Southern Alps of southern Switzerland and northern Italy)

The Strona-Ceneri Zone comprises a succession of polymetamorphic, pre-Alpidic basement rocks including ortho- and paragneisses, metasedimentary schists, amphibolites, and eclogites. The rock pile represents a Late Proterozoic or Palaeozoic subduction accretion complex that was intruded by Ordovician granitoids. Eclogites, which occur as lenses within the ortho-paragneiss succession and as xenoliths within the granitoids record a subduction related high-pressure event (D1) with peak metamorphic conditions of 710 ± 30 °C at 21.0 ± 2.5 kbar. After isothermal uplift, the eclogites experienced a Barrowtype (D2) tectonometamorphic overprint under amphibolite facies conditions (570-630 °C, 7-9 kbar). U-Pb dating on zircon of the eclogites gives a metamorphic age of 457 ± 5 Ma, and syn-eclogite facies rutile gives a ²⁰⁶Pb/²³⁸U age of 443 ± 19 Ma classifying the subduction as a Caledonian event. These data show that the main tectonometamorphic evolution of the Strona-Ceneri Zone most probably took place in a convergent margin scenario, in which accretion, eclogitization of MOR-basalt, polyphase (D1 and D2) deformation, anatexis and magmatism all occurred during the Ordovician. Caledonian high-pressure metamorphism, subsequent magmatism and Barrow-type metamorphism are believed to be related to subduction and collision within the northern margin of Gondwana. Editorial handling: Edwin Gnos     

内蒙额济纳旗霍布哈尔地区构造片岩带的发现及其构造意义

野外调查发现在靠近中蒙边界的额济纳旗霍布哈尔地区存在带状构造片岩,片理倾向南东,拉伸线理沿北东向,片岩内存在指示左行剪切的旋转碎斑系、不对称压力影等显微剪切组构。显微构造尺度上,片理结构由片理域与微片石组成,形成极易开裂的潜在破裂面。区内构造片岩是北东向韧性剪切带的组成部分,成因与韧性的剪切运动有关,经样品UY-1的LA-ICP-MS锆石U-Pb测年法测定,得到糜棱岩化的流纹斑岩年龄为286.3Ma±2.0Ma,后期侵入的闪长岩年龄为284.2Ma±2.4Ma,约束了构造片岩的形成时代为286.3Ma^284.2Ma(早二叠世)。结合区域地质资料,认为构造片岩带的形成与早二叠世阿尔金-东蒙古断裂的左行走滑剪切活动有关。     

高温气相色谱与石油分析

气相色谱最高柱温主要受柱系统技术水平的限制。使用耐高温如４００℃以上的固定相,改善配套部件的某些性能,可以将传统气相色谱的柱温提高到３２５℃以上。高温气相色谱的应用将为高分子量烃类研究提供重要的分离鉴定手段。综合国内外研究动态论述了高温气相色谱在原油的模拟蒸馏、高蜡原油分析及石蜡产品表征等几方面的研究现状和发展方向。     

AGE OF THE ALTYN TAGH STRIKE—SLIP FAULT

AGE OF THE ALTYN TAGH STRIKE—SLIP FAULT