有关湖泊沉积137Cs深度分布资料解译的探讨

讨论了国内有关湖泊沉积^137Cs断代资料解译的一些问题。一些高寒地区的湖泊,上世纪60年代主核爆期以后,入湖泥沙的^137Cs含量变化不大,因此沉积剖面^137Cs浓度达峰值后无明显降低趋势。一些浅水湖泊,由于人类活动扰动湖底表层泥沙,剖面表层泥沙的^137Cs浓度比较均一。根据核尘埃沉降监测资料,中国湖泊沉积应存在明显的1963年^137Cs蓄积峰,不应存在所谓的1974年^137Cs次蓄积峰,可能存在不很明显的1986年次蓄积峰。沉积剖面中^137Cs浓度的深度变化,不仅和”’CS大气沉降通量变化有关,也和流域内近几十年来的环境变化有关,1963年以后的^137Cs次蓄积峰的确定要慎重。黔中红枫湖沉积物^137Cs面积活度高于滇西湖泊,主要是由于石漠化严重的喀斯特山地,裸岩面积大,裸岩坡地几无土壤吸附^137Cs尘埃,核爆期间^137Cs降尘随降雨径流直接流失进入湖泊比例高的缘故,不是青藏高原的大气污染物散落屏蔽效应的结果。     

Soil erosion modelled with USLE and PESERA using QuickBird derived vegetation parameters in an alpine catchment

The focus of soil erosion research in the Alps has been in two categories: (i) on-site measurements, which are rather small scale point measurements on selected plots often constrained to irrigation experiments or (ii) off-site quantification of sediment delivery at the outlet of the catchment. Results of both categories pointed towards the importance of an intact vegetation cover to prevent soil loss. With the recent availability of high-resolution satellites such as IKONOS and QuickBird options for detecting and monitoring vegetation parameters in heterogeneous terrain have increased. The aim of this study is to evaluate the usefulness of QuickBird derived vegetation parameters in soil erosion models for alpine sites by comparison to Cesium-137 (Cs-137) derived soil erosion estimates. The study site (67 km²) is located in the Central Swiss Alps (Urseren Valley) and is characterised by scarce forest cover and strong anthropogenic influences due to grassland farming for centuries. A fractional vegetation cover (FVC) map for grassland and detailed land-cover maps are available from linear spectral unmixing and supervised classification of QuickBird imagery. The maps were introduced to the Pan-European Soil Erosion Risk Assessment (PESERA) model as well as to the Universal Soil Loss Equation (USLE). Regarding the latter model, the FVC was indirectly incorporated by adapting the C factor. Both models show an increase in absolute soil erosion values when FVC is considered. In contrast to USLE and the Cs-137 soil erosion rates, PESERA estimates are low. For the USLE model also the spatial patterns improved and showed “hotspots” of high erosion of up to 16 t ha⁻¹ a⁻¹. In conclusion field measurements of Cs-137 confirmed the improvement of soil erosion estimates using the satellite-derived vegetation data.     

4A沸石吸附模拟核素Sr,Cs后的组分变化和结构表征

通过4A沸石吸附模拟核素Sr,Cs前后的化学成分分析、X衍射分析和红外光谱分析等手段方法,分析探讨了模拟核紊Sr,Cs在4A沸石的赋存状态,结果表明：4A沸石与模拟核素Sr,Cs之间主要以离子交换的方式发生作用,Sr^2 ,Cs^ 取代4A沸石中的可交换离子Na^ ,占据4A沸石a笼中的6元环和8元环。导致4A沸石的晶胞参数增大,晶格发生畸变。     

南极阿德雷岛湖泊沉积210Pb、137Cs定年及其环境意义

测试了南极阿德雷岛两个湖泊 (Y2和G)沉积物的2 10 Pb和137Cs比度 .根据2 10 Pb和137Cs比度垂向变化特征 ,采用CRS模式对G湖进行了定年 ,年龄跨度大约为 134± 43年 ,并据此计算了G湖的沉积速率 .近大约 10 0年来G湖呈增长变化的沉积速率以及沉积物2 10 Pb ,137Cs蓄积量和沉降通量远大于大气直接沉降 ,可能是温度升高引起该地区大量冰雪 (盖 )融水携带补充的结果 .     

THE RELATIVE CONTRIBUTION OF SOIL TILLAGE AND OVERLAND FLOW EROSION TO SOIL REDISTRIBUTION ON AGRICULTURAL LAND

This study uses evidence for the long-term (35 years) pattern of soil redistribution within two agricultural fields in the UK to identify the relative importance of tillage and overland flow erosion. Spatially distributed long-term total soil redistribution data for the fields (Dalicott Farm and Rufford Forest Farm) were obtained using the caesium-137 (¹³⁷Cs) technique. These data were compared with predicted patterns of soil redistribution. Recent studies have demonstrated that the redistribution of soil by tillage may be described as a diffusive process. A two-component model was, therefore, developed which accounts for soil redistribution by both overland flow and diffusive processes. Comparison of the predicted patterns of overland flow erosion alone with the observed (¹³⁷Cs-derived) data indicated a poor agreement (r² = 0.17 and 0.11). In contrast, a good agreement exists between the predicted pattern of diffusive redistribution and the observed data (r² = 0.43 and 0.41). These results give a clear indication that diffusive processes are dominant in soil redistribution within these fields. Possible diffusive processes include splash erosion, soil creep and tillage. However, the magnitude of the diffusion coefficients for the optimum predicted pattern (c. 350–400 kg m⁻¹ a⁻¹) demonstrates that tillage is the only process capable of explaining the very significant soil redistribution which is indicated by the ¹³⁷Cs data. Consideration is given to the implications of these results for both soil erosion prediction and landscape interpretation.     

Na+,K+,Rb+,Cs+//SO2-4-H2O体系固液相平衡热力学模拟

锂云母、铯榴石等矿物的硫酸盐焙烧浸出,是从中提取锂铷铯钾等碱金属元素的重要步骤,所得硫酸盐浸出液可近似看作Li⁺,Na⁺,K⁺,Rb⁺,Cs+ // SO₄2--H₂O六元水盐体系;其在浓缩过程呈现复杂的成盐特征,增加了各碱金属元素分离提取的难度,研究其相关水盐体系相图和相平衡性质对理解浸出液中碱金属的分离具有重要的理论指导意义。本文采用Pitzer-Simonson-Clegg超额Gibbs自由能方程和具有内在热力学一致性的CALPHAD方法,构建了Na⁺,K⁺,Rb⁺,Cs⁺//SO₄2--H₂O五元体系的多温固液相平衡热力学模型。借助该模型:1)实现了对Na₂SO₄₊Rb₂SO₄₊H₂O、Na₂SO₄₊Cs₂SO₄₊H₂O和K₂SO₄₊Cs₂SO₄₊H₂O三元体系的多温溶解度等温线的准确描述,并进一步构建了这些体系在240.15~380.15 K温度范围内的多温相图;2)实现了对K₂SO₄+Rb₂SO₄₊H₂O和Rb₂SO₄₊Cs₂SO₄₊H₂O体系中存在的固溶体相—水溶液平衡关系的准确描述,确认了(K,Rb)₂SO₄连续固溶体、以及(Rb,Cs)₂SO₄(α)和(Rb,Cs)₂SO₄(β)间断固溶体存在的合理性;3)预测了上述五元体系中所包含的全部4个四元子体系(Na₂SO₄₊ K₂SO₄₊ Rb₂SO₄+H₂O、Na₂SO₄ + K₂SO₄₊Cs₂SO₄₊ H₂O、Na₂SO₄₊ Rb₂SO₄₊Cs₂SO₄ + H₂O和K₂SO₄₊Rb₂SO₄₊Cs₂SO₄₊ H₂O)的相图,明确了四元相图中固溶体的类型及形成区域。然而,模型预测结果与现有四元体系实验数据间存在普遍的不一致性,尤其是固溶体形成区域,但模型预测结果从非实验角度给出了重要参考,对现有实验提出了挑战,未来对这些体系开展更为精细的实验研究非常必要。     

贵州茂兰峰丛草地洼地小流域侵蚀产沙的137Cs法研究

在贵州茂兰峰丛洼地区的工程碑草地洼地典型小流域进行了洼地沉积泥沙^137Cs示踪分析研究。研究结果表明：（1）草地洼地土壤剖面属于堆积土壤剖面,土壤剖面中^137Cs浓度分布特征反映了泥沙堆积与表层土壤侵蚀的信息。受岩土分布、微地形的影响,^137Cs初始沉降后出现不均匀再分布,面积活度的空间变化较大,变异系数为1.35,不能表征土壤侵蚀状况。（2）根据草地洼地典型堆积农耕地土壤剖面A-1的^137Cs浓度分布特征,1963年以来的流域平均堆积泥沙数量是16.6t/km^2.a,流域平均土壤侵蚀速率为45.95t/km^2.a,约占侵蚀产沙数量63.88%的泥沙以地下流失的形式散失;（3）草地洼地小流域内地面土壤流失与地下土壤流失的相对贡献率分别是70.13%和29.87%;（4）以茂兰地区最大成土速率为依据推算出的允许土壤侵蚀量是13.51t/km^2.a,草地洼地的土壤侵蚀危险程度极高。     

Concentrations of 137Cs, 90Sr, 108m Ag, 239+240 Pu and atom ratio of 240Pu/239Pu in tanner crabs, Chionoecetes japonicus and Chionoecetes opilio collected around Japan

The anthropogenic radionuclides, ¹³⁷Cs, ⁹⁰Sr, ^108mAg, ^239+240Pu, were measured in two Chionoecetes species, red queen crab (Chionoecetes japonicus) and snow crab (Chionoecetes opilio) collected around Japan during 1996–2007. There was no increase in the concentrations of these radionuclides and no large variation of the atom ratio of ²⁴⁰Pu/²³⁹Pu during this research period. These results indicated that the source of the radionuclides was not the radioactive wastes dumped by the former USSR and Russia and originated from past nuclear weapon tests. The higher atom ratio in the crab species than that from global fallout would be contributed by the Pacific Proving Grounds close-in fallout. The variability of the concentration of radionuclides in the crab species would result from the variability of the composition and quantity in the diet. However, the decrease in the concentration of radionuclides with sampling depth would depend on the concentration in the seawater and diet.     

Distribution of 137Cs and 210Pb in sediments of tidal flats in north Jiangsu Province

Seven cores were collected from different sediment zones of tidal flats at Xinyanggang in north Jiangsu province in August 2007. Sediment grain-size distribution and radioisotopes of 137Cs and 210Pb analysis were carried out for these cores. Sediment rates of the cores and radioisotopes distribution in surface sediment in different zones of the tidal flat were calculated from the 137Cs and 210Pb activities in sediments cores. The results indicated that each tidal zone had experienced different evolution phases, hydrological dynamics in the tidal flats made the grain-size of the surface sediment change gradually. 137Cs and 210Pb activities on the superficial layer of the cores varied spatially and the reason was discussed. On tidal flats, the fluctuation of 137Cs and 210Pb activities in the cores reflected the special sedimentary characteristics. Vegetation affects the grain-size distribution and the vertical profiles of 137Cs and 210Pb in the upper depths. 137Cs and 210Pb chronology got the comparable average sediment rates on the tidal flat. The characteristics of 137Cs and 210Pb in the cores reflected various depositional dynamical environments in different tidal zones and gave information on the different evolvement phases of the tidal zones. Based on the information of grain-size distribution, texture of the cores, sediment rates and topography, the evolution lines of the tidal flat were reconstructed.     

~(137)Cs示踪法土壤侵蚀量估算的本底值问题

137Cs示踪法因能快速、相对简便地估算土壤侵蚀量而在土壤侵蚀定量研究中得到广泛应用。本底值获取是137Cs示踪法的关键和基础。在具有空间异质性多因素综合作用下,本底值呈现高度的空间异质性。针对本底值空间变异性,从气候气象要素、地形、土壤属性、土地利用/覆被四个方面阐明各因素与本底值空间变异的作用机理。分析了当前137Cs示踪法应用中在本底值获取时参考点存在性及选点的准确性、单个或几个本底值对研究区本底值的代表性和参考点采样设计。提出划分侵蚀测定单元、建立多本底值体系和进行地形校正解决当前137Cs示踪法中本底值存在问题的对策。侵蚀测定计算单元的划分原则和方法、根据已有参考点的137Cs本底值推算各单元137Cs本底值的技术方法、定量化研究各因素对137Cs的作用是今后需要深入的工作。