五大连池钾质火山岩的Sr、Nd、Pb同位素地球化学及岩浆的化学演化

五大连池火山岩是我国东部新生代最典型的钾质玄武岩。以富Ti、Na、K为特点，结晶分异使岩浆向富Si、富碱方向演化。岩石中Rb、Sr、Sin、Nd丰度与熔岩的碱质同步增长。Pb、Sr、Nd同位素组成很特殊，富放射成因Sr和Nd，但贫放射成因Pb，^37Sr/^34Sr，高于全球未分异现代值,^143Nd/^144Nd为0．512381-0.512433，低于全球未分异现代值；^206Pb/^204Pb,^207Pb/^204Pb,^208Pb/^204Pb分别对16.712-16.992,115,371-15.407,36.315-36.948,比许多大洋玄武岩和大陆玄武岩偏低。上述数据表明，其源区为无明显地壳物质混染的，未遭改造的原始富集地幔，同大洋玄武岩明显不同，暗示地幔的物质组成有区域性和不均匀性。     

Auriferous Quartz Veins from the Dongping Gold Deposit,NW Hebei Province and Metallogenesis—Fluid Inclusion Rb—Sr Isochron Evidence

The Dongping gold deposit, situated on the northern margin of the North China Platform, is a composite deposit composed of auriferous quartz vein-type and altered rock-type ore bodies. It is hosted in the inner contact zone of an alkaline intrusion which was intruded into Archean metamorphic rocks and was formed not later than the Hercynian period. Auriferous quartz veins of the deposit are dated with the fluid inclusion Rb-Sr isochron method at 103 ± 4 Ma, indicating that the gold deposit was formed in the Yenshanian period.⁸⁷Sr/⁸⁶Sr sourcetracing shows the ore forming materials came dominantly from alkaline intrusions. These results, combined with other isotope and REE data, suggest that the Dongping gold deposit is not a traditional magmatic hydrothermal deposit, but a reworked hydrothermal deposit related to heated and evolved meteoric water. This project (49372105) is financially supported by the National Natural Science Foundation of China.     

Lead in K－Feldspar and Its Relations to Rb Metallogenesis

In intermediate-acid magmatic rocks,alkaline magmatic rocks,gneisses and migmatitic rocks K-feldspar is a rock-forming rock in which the contents of Pb are highest,just 2-10 times those of the whole rock,3-16 times those of mica minerals and 6-32 times those of quartz.The lowest contents of K-feldspar are recognized in Early Proterozoic and Achaean rocks,with Pb in the K-feldspar accounting for less than 10% of that in the whole rock;in post Middle Proterozoic alkaine magmatic rocks,K-feldspar-rich granites and metamorphic rocks the contents of K-feldspar tend to increase,with the proportion granites and metamorphic rocks the contents of K-feldspar tend to increase,with the proportion of Pb over that in the whole rock being obviously increased.In the alkaline rocks in which K-feldspar accounts for 50%-70% of the total in the whole rock,the contents of Pb in K-feldspar account approximately for 70%-95% of the total lead in the whole rock.Being accessible to hydrothermal alteration in the late periods,K-feldspar was conversed to sericite,calcite,quartz,etc.In the process of such conversion the lead would be leached out and then find its way into fluid phase.This kind of trans-formation can provide sufficient ore-forming material for later Pb metallogenesis.     

中亚造山带天河石花岗岩及相关铷矿床的主要特征与研究进展

铷是重要的"关键金属"矿产资源,是未来各国资源争夺的焦点。虽然我国铷矿资源总量丰富,但主要为低品位难以加工利用的花岗岩型铷矿床,而以铁锂云母、锂云母和铯沸石等作为矿石矿物的高品位易加工花岗伟晶岩型铷矿床非常有限。因此,富铷花岗岩及相关铷矿床的形成过程、元素分异机制以及铷在不同矿物相中的赋存状态和控制因素是铷矿床成矿机制研究和找矿工作的关键。本文在对花岗(伟晶)岩铷矿主要研究进展进行综述的基础上,简介中亚造山带东、西段典型天河石花岗岩及相关铷等稀有金属矿床的主要特征和时空分布,并对未来研究重点进行了展望。本文认为,中亚造山带是全球最重要的天河石花岗岩和相关稀有金属矿床成矿域,其西段大量发育三叠纪天河石花岗岩,而东段大量发育晚侏罗至早白垩世天河石花岗岩。两者形成时代和构造背景分别与古亚洲洋向古特提斯洋构造域,以及古亚洲洋向古太平洋构造域的巨大转折相对应,铷等稀有金属成矿潜力巨大,值得开展深入的年代学、岩石学和矿床成因研究。     

赣西北大湖塘钨矿富锂-云母化岩锂元素富集机制及其对锂等稀有金属找矿的启示

赣西北大湖塘钨矿具有低品位、大储量、热液蚀变强等特征。在热液蚀变类型和空间分带特征的厘定,以及富锂-云母矿物学特征的认识基础上,通过云母类矿物原位主微量元素组成特征的分析,揭示大湖塘钨矿锂等稀有金属元素的富集,可能是大量热液成因黑鳞云母、铁锂云母和锂-多硅白云母的先后沉淀叠加聚集的结果。其中铁锂云母的锂元素含量最高(Li₂O=4.15%～4.86%),黑鳞云母(Li₂O=0.81%～1.72%)次之,然后是锂-多硅白云母(Li₂O=0.24%～0.45%)。大湖塘钨矿富锂-云母在蚀变岩中比例非常高,分布又均匀,而蚀变岩的规模更是巨大,因而具有巨大锂等稀有金属成矿的潜力。典型蚀变岩的全岩主微量元素分析显示,在晋宁期花岗闪长岩黑鳞云母+铁锂云母蚀变带的锂、铷和钾等元素含量最高。即富钾热液蚀变岩,其K₂O=5.94%～8.06%,Li₂O=0.34%～1.548%和Rb₂O=0.175%～0.784%,而黑鳞云母+铁锂云母+石英蚀变则次之。在燕山期花岗岩中,则以...     

岩石铷-锶和钐-钕同位素标准物质的研制

通常样品的87 Sr/86 Sr和143 Nd/144 Nd同位素比值分析采用SRM987、JNdi-1作为标准物质,它们分别是纯的碳酸盐和氧化物,适用于监控质谱测试过程.中国现有的钐-钕地质和铷-锶年龄标准物质,分别为玄武岩和钾长石,它们与很多地质样品的基质存在差别.仅有这两种基质的标准物质不能有效地监控不同地质样品...