Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters     

Isotopes and Geochronology of the Meixian-type Pb-Zn-(Ag)Deposits,Central Fujian Rift,South China:Implications for Geological Events

Central Fujian Rift is another new and important volcanogenic massive sulfide Pb-Zn polymetallic metallogenetic belt. In order to find out the material genesis and mineralization period of Meixian-type Pb-Zn-Ag deposits, S and Pb isotope analysis and isotope geochronology of ores and wall rocks for five major deposits are discussed. It is concluded that the composition of sulfur isotope from sulfide ore vary slightly in different deposits and the mean value is close to zero with the 834S ranging from -3.5‰ to ＋5.6‰ averaging at ＋2.0‰, which indicates that the sulfur might originate from magma or possibly erupted directly from volcano or was leached from ore-hosted volcanic rock. The lead from ores in most deposits displays radioactive genesis character （206pb/204pb〉18.140, 207Pb/204pb〉15.584, 208pb/204pb〉38.569） and lead isotope values of ores are higher than those of wall rocks, which indicates that the lead was likely leached from the ore-hosted volcanic rocks. Based on isotope data, two significant Pb-Zn metallogenesis are delineated, which are Mid- and Late-Proterozoic sedimentary exhalative metailogenesis （The single zircon U-Pb, Sm-Nd isochronal and Ar-Ar dating ages of ore- hosted wall rocks are calculated to be among 933-1788 Ma.） and Yanshanian magmatic hydrothermal superimposed and alternated metallogenesis （intrusive SHRIMP zircon U-Pb and Rb-Sr isochronal ages between 127-154 Ma）.     

鄂尔多斯地块早白垩世构造-热事件:杭锦旗玄武岩的Ar-Ar年代学证据

在鄂尔多斯地块北部杭锦旗黑石头沟,于下白垩统砂岩之上发现了一层玄武岩。其SiO2(46.93%)较低而碱含量(K2O+Na2O=6.21%)较高,组合指数σ=8.0,含标准矿物Ne,属于碱性橄榄玄武岩。Ar-Ar激光阶段加热定年结果表明,该玄武岩具有126.2±0.4Ma的Ar-Ar年龄。年龄数据表明杭锦旗黑石头沟玄武岩形成于早白垩世,反映鄂尔多斯地块在早白垩世发生了一次构造-岩浆-热事件,这与华北、乃至整个中国东部在早白垩世发生了较普遍的构造-岩浆-热事件具有一致性。这次构造-岩浆-热事件可能引起深部流体自地下深部上涌及在地块内部运移,为各种成矿元素的迁移、沉淀、富集和成矿创造了合适条件。     

南海北部深水盆地沉积-构造的差异性及其油气意义

南海北部深水区自西向东依次分布着琼东南盆地、珠江口盆地、台西南盆地等新生代被动陆缘盆地,这些盆地经历了大致相当的从裂陷到坳陷的构造演化史,但在张裂活动过程中存在着明显的沉积-构造的差异性。构造沉降特征分析显示:在同一构造带上自西向东有盆地主要构造沉降发生的时段逐步变晚的趋势;在不同构造带上自北向南有盆地主要构造沉降发生的时段逐步变晚的趋势。这种沉积-构造的差异性对烃源岩的发育类型、分布及生储盖组合等方面有明显的控制作用,表现为:裂谷期构造沉降幅度大的盆地,陆相烃源岩发育,以陆生陆储陆盖型成藏组合为主;裂后期构造沉降幅度大的盆地,海相烃源岩发育规模较大,海生海储海盖型成藏组合及混生海储海盖型生储盖组合所占分量逐渐增多。推测渐新统湖相-湖沼相及海陆过渡相源岩和中新统海相烃源岩应是南海北部深水区油气的主要来源,陆生海储海盖型、海生海储海盖型及混生海储海盖型生储盖组合应是深水区基本生储盖组合类型。     

神木北部矿区5-2煤层厚度及其底板高程趋势分析

为了查清神木北部矿区5-2煤层赋存特征及成因,选取了该矿区172个典型钻孔数据,用趋势分析法研究了5-2煤层的厚度及其底板高程度变化特征。结果显示:该区煤层厚度总体为南北厚中部薄,东厚西薄;底板高程为南北高中部低,东高西低;煤层厚度和其底板高程间普遍存在正相关关系。在该区构造稳定的背景下,后期改造对煤层厚度及其底板的影响很小,煤层赋存特征主要受沉积与剥蚀的控制。     

粤东成矿地质背景及银-铜-铅-锌成矿物质来源探讨

通过对粤东地区地层和岩石中成矿元素含量和区域地质背景的分析,认为粤东地区铜铅-锌-银成矿作用与燕山期的构造-岩浆作用关系密切,成矿物质中银-铜-锌以下地壳来源为主,铅则以上地壳及沉积地层来源为主。     

湖北竹山寒武纪碳硅质板岩中蓝色似绿松石的特征分析

湖北竹山县寒武纪碳硅质板岩层间破碎带内有大量蓝色的磷钙铝矾、纤磷钙铝石混合物与绿松石共生,物理性质表现为致密坚硬而性脆,吸水性强。化学成分分析硅和铝的含量高,磷含量少,并含有少量的硫和铜,是溶液为酸性时的产物。     

土壤吸湿-湿过程中水力传导度的拟合研究

非饱和含水介质在吸湿和脱湿的不同过程中,水力传导度随介质含水率的变化规律是不同的。本文选取大沽河流域两种代表性砂土,对其吸湿-脱湿两个过程分别进行试验观测,并使用VanGenuchten—Mualem模型对其吸湿-脱湿过程进行水力传导度的拟合。研究结果表明：砂土在吸湿过程的非饱和水力传导度与脱湿过程的非饱和水力传导度大小并不相同,在含水率相同的情况下,吸湿过程的水力传导度要比脱湿过程大,在含水率较低时（小于15％）相差可达1个数量级。     

富宁阳文冲-广南菜子垣热液淋滤卡林型金矿区

金矿区构造活动具有多期性：加里东期及海西期在矿区形成的薄弱角度不整合面、近南北向平行的滑脱断层,是含矿热液的运移、沉淀的通道和空间。金矿床应属地下热液淋滤卡林型金矿床。     

辽宁白云三道沟沉积变质改造型金矿

金矿脉受推覆构造带控制,矿质来自辽河群含金层位,属硅钾蚀变沉积变质改造型金矿。