天鹅寨火山地质特征的研究

天鹅寨火山杂岩体是湘南－粤北地区唯一面积出露的陆相酸性火山岩，内有铀矿点产出。通过对火山杂岩体的研究。论述了火山杂岩体产出特点、岩石学及地球特征，提出了火山岩层和火山活动旋回的划分、岩相新归属以及火山构造类型。     

区域采样法测定水中硫酸根离子的研究

在分散度不同的区域内进行区域采样用于水中硫酸根离子的测定，结果令人满意。应用此方法测定硫酸根离子的线性范围为２００．０～３０００ｍｇ／Ｌ；进样频率为１２０次／ｈ；相对标准偏差为１．７０％     

浅谈勘察设计企业文化建设

本文认为,在新形势下,勘察设计企业需建立全新的本企业文化,需突出自己的特色,并探讨了勘察设计企业文化建设的途径。     

碳酸盐岩储层缝洞发育带预测:以塔河油田为例

塔河油田碳酸盐岩为古岩溶喀斯特化与受后期构造叠置改造的孔、洞、缝等组成的非均质储层,储层具有规模不同、空间形态不规则、充填性质各异的复杂组合特征以此为对象通过分解地震波场不同特征信号,开发了一系列针对不同储层目标的叠前叠后地震预测技术,不同特征地震预测结果经综合叠置验证分析,实现了残丘体上叠置的孔、洞、缝及古地貌的精细刻画及表征,展示了缝洞空间纵横交错的叠置关系,提高了复杂储层空间展布规律的认识及精确定位。     

人工土层冻结法加固在盾构出洞施工中的应用

软土地区盾构出洞施工中洞口土体易失稳、渗水,上海明珠线二期工程浦东大道站至张扬路站区间,隧道在盾构出洞施工中,为确保地面建筑及地下管线的安全及正常使用,首次采用了人工土层冻结加固,取得了良好的效果;本文介绍了该工程出洞口土体加固的方案选择、关键技术处理及实际取得的效果,并探讨了人工土层冻结加固在含水松软土层的地下工程中的应用前景.     

多元统计在雅砻江某电站水文地质调查中的应用

对雅砻江某电站的水样进行多元统计分析，水样的八个指标Q型聚类，对地表水及地下水进行了水文地质初步分类，主因子分析反映了与地下水形成作用有关的三个重要的水文地球化学作用，即岩溶作用、黄铁矿的氧化作用以及地下水的溶滤作用。结合多元统计结果以及本区的水文地质条件，对地下水系进行了分类。     

Sorption Characteristics of Rare Earth Element Eu^3＋ onto Silica-Water Interfaces Studied by Fluorescence Spectroscopy

The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ～1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=～5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献   

Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

Water soluble components of PM10 Chongqing, China

The concentrations of water soluble ions (Na⁺, NH₄ ⁺, K⁺, Mg²⁺, Ca²⁺, NO₃ ^-, Cl^-, and SO ₄ ^2- ) in PM₁₀ samples collected on cellulose filters by a medium-volume cascade impactor were determined, which were obtained from three kinds of areas in Chongqing: industrial area (Jiulongpo district), commercial and residential area (Jiangbei district) and background area (Jinyun Mountain in the Beibei district). The results showed that except for the background site, the annual average values of PM₁₀ are 23% – 61% higher than the national air quality standard (GradeII) (0.1 mg/m³), even that the value of the control site is still 20% higher than American standard (0.05 mg/m³). This implied that serious pollution of fine particles occurred in Chongqing. Nine kinds of soluble ions in water of PM₁₀ were analyzed by ion chromatography (IC) and the annual average concentrations follow the order of [SO ₄ ^2- ] > [NO³ _-] > [Cl^-] > [F^-], and [Ca²⁺] > [NH₄ ⁺] > [K⁺] > [Na⁺] > [Mg²⁺]. Their values were different in these areas: the industrial area > the commercial and living area > the control area. As for NH_{4 +}, K⁺, Ca²⁺, NO₃ ^- and SO ₄ ^2- , their seasonal average concentrations show a similar variation trend: the values in spring and fall were higher than those in summer and winter. The seasonal average concentrations of [Cl^-], [F^-], [Na⁺] and [Mg²⁺] are much lower than those of other ions. However, the concentrations of [Na⁺] changed more greatly in different seasons than those of the other three ions. Correlation coefficients showed that the three areas have been polluted by coal smoke and dust to different extents, while some local resources of pollution should be taken into consideration as well.     

浓硫酸钠水溶液中的离子对

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。