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31.
Fe‐rich metapelitic granulites of the Musgrave Block, central Australia, contain several symplectic and coronal reaction textures that post‐date a peak S2 metamorphic assemblage involving garnet, sillimanite, spinel, ilmenite, K‐feldspar and quartz. The earliest reaction textures involve spinel‐ and quartz‐bearing symplectites that enclose garnet and to a lesser extent sillimanite. The symplectic spinel and quartz are in places separated by later garnet and/or sillimanite coronas. The metamorphic effects of a later, D3, event are restricted to zones of moderate to high strain where a metamorphic assemblage of garnet, sillimanite, K‐feldspar, magnetite, ilmenite, quartz and biotite is preserved. Quantitative mineral equilibria calculations in the system K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3 (KFMASHTO) using Thermocalc 3.0 and the accompanying internally consistent dataset provide important constraints on the influence of TiO2 and Fe2O3 on biotite‐bearing and spinel‐bearing equilibria, respectively. Biotite‐bearing equilibria are shifted to higher temperatures and spinel‐bearing equilibria to higher pressures and lower temperatures in comparison to the equivalent equilibria in K2O–FeO–MgO–Al2O3–SiO2–H2O (KFMASH). The sequence of reaction textures involving spinel is consistent with a D2 P–T path that involved a small amount of decompression followed predominantly by cooling within a single mineral assemblage stability field. Thus, the reaction textures reflect changes in modal proportions within an equilibrium assemblage rather than the crossing of a univariant reaction. The D3 metamorphic assemblage is consistent with lower temperatures than those inferred for D2. 相似文献
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Anton VaksMiryam Bar-Matthews Avner AyalonBettina Schilman Mabs GilmourChris J Hawkesworth Amos FrumkinAaron Kaufman Alan Matthews 《Quaternary Research》2003,59(2):182-193
High-resolution 230Th/234U ages and δ18O and δ13C compositions of speleothems in Ma’ale Efrayim Cave located to the east of the central mountain ridge of Israel enable us to examine the nature of the rain shadow aridity during glacial and interglacial intervals. Speleothem growth occurred during marine glacial isotopic periods, with no growth during the two last marine isotope interglacial intervals and during the peak of the Last Glacial Maximum. This contrasts with speleothem growth in caves located on the western flank of the central mountain ridge, in the Eastern Mediterranean semiarid climatic zone, which continued throughout the last 240,000 yr. Thus, during glacial periods water reached both sides of the central mountain ridge. A comparison of the present-day rain and cave water isotopic compositions and amounts at the Ma’ale Efrayim Cave site with those on the western flank shows that evaporation and higher temperatures on the eastern flank are major influences on isotopic composition and the lack of rainfall. The δ18O and δ13C profiles of the speleothems deposited between 67,000 and 25,000 yr B.P. match the general trends of the isotopic profiles of Soreq Cave speleothems, suggesting a similar source (eastern Mediterranean Sea) and similar climatic conditions. Thus, during glacial periods the desert boundary effectively migrated further south or east from its present-day location on the eastern flank, whereas interglacial periods appear to have been similar to the present, with the desert boundary at the same position. The decrease in overall temperature and a consequent reduction in the evaporation to precipitation ratios on the eastern flank are viewed as the major factors controlling the decay of the rain shadow effect during glacial periods. 相似文献
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应用增量方法不仅能够从理论上准确计算所有固体矿物的O同位素分馏系数,而且能够定量预测;(1)热力学平衡条件下共生矿物之间的18O富集顺序;(2)岩石化学成分与O同位素组成之间的关系;(3)矿物结构变化对O同位素组成的影响;(4)同质多相转变和矿物反应中的氧同位素继承性。本文对这些规律性预测进行了概要性介绍,并给出实例予以说明。 相似文献
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用差热和热(失)重法、pH值检验、离子色谱等分析方法考察和证实了Cl-对平菲尔特管重量法测定化合水(H2O+)的干扰,研究其影响规律,提出用系数校正方法可获得H2O+的准确结果。方法用于含氯深海沉积物和大洋多金属结核标准物质中H2O+的定值分析,取得满意结果 相似文献
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地幔流体的前缘研究 总被引:19,自引:8,他引:19
地幔流体是与地幔环境处于平衡的气体和挥发分。其主要化学组分为碳、氢、氧、氮、硫(CHONS)。它以富于地球内部原始组分为特征,但也包含部分再循环组分。地幔挥发分在弱还原条件下主要为CO2-H2O,强还原环境则以CH4-H2O-H2为主。地幔流体地球化学的重要性质为:(1)易溶于硅酸盐熔体;(2)净化作用;(3)再沉淀作用。近年来,有关地幔流体中稀有气体和挥发分的起源、分布及同位素组成等前缘领域的研究已取得重要进展。当前拟优先探索的问题包括气体裂化与金刚石成因,非生物成因地幔烃,地幔流体与成矿作用,以及地幔挥发分注入与地壳重熔等。 相似文献
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