高效铝合金牺牲阳极的研究

在铝中添加合金元素Zn,Mg,In,Ga,Ca,利用正交设计方法,研制出一种高效的铝合金牺牲阳极,它在海水中的电流效率达95.6％,电位为-1.09V(SCE)。并研究了合金元素In,Ga,Ca对铝合金电化学性能的影响及阳极活化机理。     

Laser Ablation ICP-MS Analysis of Geological Materials Prepared as Lithium Borate Glasses

A simple, rapid and precise method is described for determining trace elements by laser ablation (LA)-ICP-MS analysis in bulk geological materials that have been prepared as lithium borate glasses following standard procedures for XRF analysis. This approach reliably achieves complete sample digestion and provides for complementary XRF and LA-ICP-MS analysis of a full suite of major and trace elements from a single sample preparation. Highly precise analysis is enabled by rastering an ArF excimer laser (λ= 193nm) across fused samples to deliver a constant sample yield to the mass spectrometer without inter-element fractionation effects during each analysis. Capabilities of the method are demonstrated by determination of twenty five trace elements (Sc, Ti, V, Ga, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Hf, Ta, Pb, Th and U) in a diverse range of geological reference materials that includes peridotites, basalts, granites, metamorphic rocks and sediments. More than 90% of determinations are indistinguishable from published reference values at the 95% confidence level. Systematic bias greater than 5% is observed for only a handful of elements (Zr, Nb and U) and may be attributed in part to inaccurate calibration values used for the NIST SRM 612 glass in the case of Zr and Nb. Detection limits for several elements, most notably La, are compromised at ultra-trace levels by impurities in the lithium borate flux but can be corrected for by subtracting appropriate procedural blanks. Reliable Pb analysis has proved problematic due to variable degrees of contamination introduced during sample polishing prior to analysis and from Pt-crucibles previously used to fuse Pb-rich samples. Scope exists for extending the method to include internal standard element/isotope spiking, particularly where integrated XRF analysis is not available to characterise major and trace elements in the fused lithium borate glasses prior to LA-ICP-MS analysis.     

纳滤分离铝锂过程研究

本文探讨了纳滤分离Al~(3+)和Li~+的可行性,研究了含盐量和铝锂比对分离效率的影响,提出了从锂云母浸出液中分离回收锂的新方法。实验结果表明,纳滤膜对Al~(3+)和Li~+的截留率随含盐量的升高而降低,其中Li~+始终呈现负浓度梯度扩散的趋势,而Al~(3+)的截留率始终稳定在99%以上。当含盐量为45 g/L时,铝锂分离因子最高可达248.33,膜面相应Zeta电位的绝对值达到最大。随着溶液中铝锂比的变化,Al~(3+)和Li~+的截留率分别在不同铝锂比的条件下出现拐点,溶液的pH呈现先下降后上升最后下降的复杂趋势。本实验研究发现,DK膜能够在酸性环境下实现高效的铝锂分离和锂的浓缩,从而为锂云母浸出液中锂的提取提供新的思路。     

Dissolved aluminium and the silicon cycle in the Arctic Ocean

Concentrations of dissolved (0.2 µm filtered) aluminium (Al) have been determined for the first time in the Eurasian part of the Arctic Ocean over the entire water column during expedition ARK XXII/2 aboard R.V. Polarstern (2007). An unprecedented number of 666 samples was analysed for 44 stations along 5 ocean transects. Dissolved Al in surface layer water (SLW) was very low, close to 1 nM, with lowest SLW concentrations towards the Canadian part of the Arctic Ocean and higher values adjacent to and in the shelf seas. The low SLW concentrations indicate no or little influence from aeolian dust input. Dissolved Al showed a nutrient-type increase with depth up to 28 nM, but large differences existed between the different deep Arctic basins. The differences in concentrations of Al between water masses and basins could largely be related to the different origins of the water masses. In the SLW and intermediate water layers, Atlantic and Pacific inflows were of importance. Deep shelf convection appeared to influence the Al distribution in the deep Eurasian Basin. The Al distribution of the deep Makarov Basin provides evidence for Eurasian Basin water inflow into the deep Makarov Basin. A strong correlation between Al and Silicon (Si) was observed in all basins. This correlation and the nutrient-like profile indicate a strong biological influence on the cycling and distribution of Al. The biological influence can be direct by the incorporation of Al in biogenic silica, indirect by preferential scavenging of Al onto biogenic siliceous particles, or by a combination of both processes. From the slope of the overall Al–Si relationship in the intermediate water layer (AIDW; ~ 200–2000 m depth), an Al/Si ratio of 2.2 atoms Al per 1000 atoms Si was derived. This ratio is consistent with the range of previously reported Al/Si uptake ratio in biogenic opal frustules of diatoms. In the deepest waters (>2000 m depth) a steeper slope of the Al–Si relationship of 7.4 to 13 atoms Al per 1000 atoms Si likely results from entrainment of cold shelf water into the deep basins, carrying the signal of dissolution of terrigenous particles with a much higher Al:Si ratio of crustal abundance. Only a small enrichment with such crustal Al and Si component may readily account for the higher Al:Si slope in the deepest waters.     

三元体系Na_2B_4O_7-NaHCO_3-H_2O和Na_2CO_3-NaBO_2-H_2O等温溶解度研究

作为研究四元体系Ｎａ２Ｂ４Ｏ７－Ｎａ２ＣＯ３－ＮａＨＣＯ３－ＮａＢＯ２－Ｈ２Ｏ的开端，测定了三元体系Ｎａ２Ｂ４Ｏ７－ＮａＨＣＯ３－Ｈ２Ｏ和Ｎａ２ＣＯ３－ＮａＢＯＨ２－Ｈ２Ｏ在０℃、１５℃－４５℃时的溶解度，绘制了相应的组成－性质图。两个三元体系的溶度图在研究温度范围内均属于低共饱型，平衡固相为组分化合物或其水合物。     

Phase Equilibria of Salt-water Systems Containing Magnesium and Borate Ions

正1 Introduction A salt lake is a naturally occurring complex body of water and salt interaction.More than 700 salt lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous for their abundance of lithium,potassium,magnesium,and boron resources.It is     

Ca-H-Al exchanges and aluminium mobility in two Chinese acidic forest soils: a batch experiment

Exchange reactions between Ca²⁺, H⁺ and Al species and their effects on the aluminium mobility in two Chinese acidic forest soils were studied. The study was based on a batch experiment using extractant solutions with different base cation (calcium) concentrations and pH. The experimental data showed that increased Ca²⁺ concentrations increased the release of soil hydrogen—and aluminium ions, especially from the more acid soil. In agreement with a cation exchange process, the treatment with Ca²⁺ extracts gave significantly decreased soil aluminium saturation (AlS) and increased calcium saturation (CaS) on the ion exchanger. Geochemical calculation using AlCHEMI program showed that activities of Al³⁺ in the extracts were all strongly under-saturated with respect to any gibbsite mineral in the studied pH region (i.e. below 4.1). There were instead apparently two different mechanisms controlling the activities of Al³⁺ in extracts. At pH between about 4.1 and 3.7, the Al³⁺ activity did not change significantly with pH. This is especially the case in the more acid soil. Apparently there are no sizeable pools available to release Al in this pH region. At pH below 3.7 (induced by higher Ca²⁺concentration) the activity of Al³⁺ increased with H⁺ though not in a pattern that complies with a gibbsite solubility control. An increase of base cation deposition would therefore mainly enhance the release of hydrogen ions between pH 4.1 and 3.7 and aluminium ions below pH 3.7 from Chinese mature acidic soils. This will cause an increased acidity of soil water in the short term and a decrease in the soil acidity in the long term. More attention should be paid to this fact in Chinese acid rain studies and control options.     

Verringerung der Schwermetall‐ und Sulfatbelastung in sauren bergbaubelasteten Gewässern durch Aluminiumpräzipitate

Attenuation of Heavy Metals and Sulfate by Aluminium Precipitates in Acid Mine Drainage During the mixing of acid mine waters with nearly neutral tributaries, often precipitates are formed which are high in iron or aluminium. These precipitates cover the river bed for many kilometres. Near the town of Lehesten (Thuringian slate mining area), leachates of slate quarries and waste rock dumps contain high amounts of aluminium, sulfate, copper, nickel, zinc, manganese, and H⁺ ions as a result of the oxidation of incorporated pyrite. These leachates enter the brooks Loquitz, Kleine Sormitz, and Rehbach leading to the phenomenon named above. The contribution of the forming aluminium‐rich precipitates on the attenuation of sulfate and heavy metals by sorption or coprecipitation was studied by analysing the composition of water and sediment samples as well as samples of suspended matter. Sulfate is often considered as conservative tracer in acid mine drainage. However, sulfate does not behave conservatively in this system what might be explained by the adsorption of sulfate to the aluminium precipitates. Instead, conservative behaviour was found for calcium, potassium, chloride, zinc, manganese, and nickel. A formation of jurbanite can be excluded because of the low sulfate contents. The sulfate content of the sediment depends on the pH. At low pH values (4.8) the S/Al ratio corresponds to the theoretical ratio in basaluminite and decreases with rising pH. Sulfate is weakly bound to the solid phase and can easily be replaced by OH^– ions. A formation of basaluminite is possible at low pH values with a fluent transition to aluminium hydroxide. Therefore the precipitates are assumed to consist predominantly of aluminium hydroxide with sulfate being adsorbed to the surface.     

Geological features and genesis of Gaotaigou borate deposit, Jilin, China

Gaotaigou borate deposit in Ji'an area, southeastern Jilin, is located in the easten end of Liaoning-Jilin (Liaoji)Proterozoic paleo-rift, which is a medium-sized deposit and makes up 67% of the total borate reserves in Jilin Province.The original borate ore bodies were formed by sedimentary exhalative process in Paleoproterozoic, but were activated and enriched by later metamorphism. In late stage of metamorphism, hydrothermal fluid of metamorphic origin made wallrocks be altered and the borate ore bodies be reformed. Ore bodies are strictly controlled by strata and their lithologies. In addition, the shape and spatial distribution of ore bodies are also defined by the Gaotaigou syncline. Combined with the ore-controlling factors and mineralizing features, it has been proposed that Gaotaigou borate deposit is a metamorphosed and hydrothermally altered sedimentary exhalative deposit.     

Bioavailability and toxicity of aluminium in a model planktonic food chain (Chlamydomonas-Daphnia) at neutral pH

Dissolved aluminium (Al) is generally at low concentrations in neutral freshwater due to its insolubility. However, a fall in pH resulting from acid deposition and mining alters the mobility of Al and so entry to adjacent neutral waters. The present study examines the environmental behaviour, cell-associated surface adsorption/absorption and toxicity of Al at neutral pH to the alga Chlamydomonas gigantea in the presence and absence of the key Al-binding ligand silica. We then examined transfer of Al from C. gigantea to the planktonic crustacean Daphnia pulex. Finally, the effect of Al on the elemental composition (and hence nutritional value) of the two organisms was compared to unexposed controls. C. gigantea increased the amount of Al in the algal culture medium. Binding of Al to extracellular glycoprotein is probably the reason why only one-third of the biosorbed Al was absorbed (accumulated) by C. gigantea. Aluminium concentrations between 50 and 500 μg l⁻¹ reduced growth of C. gigantea at 16 days exposure to the metal. Silica reduced biosorption, accumulation and toxicity of Al by C. gigantea. The concentration of Al in D. pulex fed Al-contaminated C. gigantea for 16 days did not differ from those fed alga grown in the absence of added Al. C. gigantea contaminated with Al contained less sulphur, magnesium, potassium and sodium although only sulphur fell in D. pulex subsequently fed the contaminated alga. Chloride, calcium, iron and silicon were significantly higher in D. pulex.