中国高放废物地质处置缓冲材料大型试验台架和热-水-力-化学耦合性能研究

缓冲材料作为高放废物深地质处置库中一道重要的人工屏障,与高放废物容器和处置库围岩直接接触,在高放废物衰变热、辐射作用和地下水等影响下产生复杂的热-水-力-化学耦合作用,为了验证缓冲材料是否能长期有效地发挥其屏障材料的作用,核工业北京地质研究院利用高庙子钠基膨润土组装并运行了模拟中国高放废物地质处置室 尺寸的大型缓冲材料膨润土试验台架（China-Mock-Up）。建立了缓冲材料试验台架的安装和试验方法,依据实测数据和理论分析,揭示了热-水-力-化学耦合作用条件下膨润土中的相对湿度是在加热器的热效应和外部供水的湿效应共同作用下发生变化的,压实膨润土中应力的变化主要是由于膨润土遇水膨胀和加热器的热效应引起的,试验验证了模拟高放废物地质处置室内加热器（废物罐）运行初期的位移过程,为缓冲材料和高放废物地质处置库的设计提供了重要的工程参数和理论依据。     

利用液态磷渣制备乳浊玻璃

为实现炼磷排放的高温液态磷渣的热能、物质的同步回收利用, 并消除其环境污染问题, 通过现场试验, 以高温液态磷渣为主要原料, 直接与16.5%的石英粉和8.5%的高岭土热配合, 再经1450℃熔炼、浇铸成型和850℃乳化热处理, 制得了乳浊玻璃板材.磷渣乳浊玻璃的抗折强度为43.68MPa, 耐酸性为0.51%, 耐碱性为0.04%, 能满足建筑装饰材料的质量要求.ESEM、XRD和EDS分析结果共同表明, 母玻璃的乳浊机理在于主体玻璃中析出了富Ca元素的粒径为0.1~0.4μm的非晶质球形颗粒.由于高温液态磷渣掺量高达75%, 改性剂掺量低且成本低廉, 生产线易于配置, 本研究具有较高的工业化生产可行性、较佳的经济效益和应用前景.      

浙东沿海某地区大气干湿沉降对土壤重金属 元素含量的影响

基于对浙东沿海某典型固废拆解区重金属元素大气干湿沉降特征的研究,探讨了重金属元素干湿沉降输入对土壤环境的影响。结果表明,研究区露天焚烧等不规范的固废拆解行为造成大气质量恶化,对土地质量造成严重的负面影响。区内干、湿沉降中Cd、Cu、Pb、Zn、Ni等重金属元素的含量均远高于浙江省干、湿沉降平均值和其它相关标准值,并且其年沉降通量在省内居高,尤其是Cu、Zn两种元素每年每平方百米沉降通量分别达7108g、11420g。研究显示,大气沉降能大大增加研究区土壤重金属元素的含量水平,Cu、Zn、Cd、Pb平均年增加量分别达3426ng/g、5819ng/g、6.50ng/g、582ng/g,并且年增加率较大,Pb、Cu、Zn等重金属元素的年增加率达0.5%以上。     

高放废物处置库新疆阿奇山预选地段区域水文地质特征

新疆阿奇山地区是我国高放废物处置库预选地段之一。在野外调查、样品采集和测试的基础上,讨论了该地段区域水文地质特征,结果表明,阿奇山地段地下水可划分为松散岩类孔隙水、碎屑岩类裂隙孔隙水和基岩裂隙水3种类型,其单井涌水量一般10m~3/d,属于典型的低含水介质;区域地下水流向为自南东流向北西;位于吐鲁番盆地的艾丁湖一带为阿奇山地段地下水的最终排泄区。     

Preservation of coal-waste geochemical markers in vegetation and soil on self-heating coal-waste dumps in Silesia,Poland

Occurrence and distributions of geochemical markers on vegetation and in soils covering two self-heating coal waste dumps were investigated with gas chromatography-mass spectrometry (GC–MS) and compared with those of bitumen expelled on the coal waste dump surface. Presence of biomarkers, alkyl aromatic hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), and such polar compounds as phenols indicate that components of self-heating coal wastes indeed migrate to soils and plants surface and their characteristic fingerprints can be applied in passive monitoring to investigate migration of contaminants from self-heating coal wastes. Moreover, results allow to discriminate between the Upper- and Lower Silesian coal basins, notwithstanding value shifts caused by heating. Mechanisms enabling the migration of geochemical compounds into soils include mixing with weathered coal-waste material, transport in gases emitted due to self-heating and, indirectly, by deposition of biomass containing geochemical substances. Transport in gases involves mostly lighter compounds such as phenols, methylnaphthalenes, methylbiphenyls, etc. Distributions and values of geochemical ratios are related to differences in their boiling temperatures in the case of lighter compounds but preserve geochemical features in the case of heavier compounds such as pentacyclic trierpanes.     

Retardation capacity of altered granitic rock distributed along fractured and faulted zones in the orogenic belt of Japan

There are wide areas of granitic rocks in the Japanese orogenic belt. These granitic bodies inevitably contain fracture and fault systems associated with alteration zones. However, relatively little attention has been given to the possible influence of such widely distributed alteration zones on the migration of radionuclides from any radioactive waste repository that might in future be sited within granitic rock. In particular, the influences of alteration products and micro-fractures, due to chemical sorption and/or physical retardation require further consideration. In order to understand the retardation capacity of the altered deep granitic rocks, detailed geometrical characterization of pores, geochemical analysis, and batch sorption and flow-through experiments have been carried out. Those results show that the altered granite has a large volume of accessible pores, particularly in potassium-feldspar grains, which would influence nuclide retardation more than the accessible porosity in other minerals present, such as biotite. The distribution coefficients, Kd estimated from batch sorption tests and flow-through experiments suggest that altered granite has a high capability to retard the migration of nuclides. The retardation would probably be due to sorption on altered minerals such as sericite and iron hydroxides formed along grain boundaries and in pores created by dissolution, in addition to sorption on primary sorptive minerals. These results provide confidence that even altered and fractured parts of any granitic rock that might be encountered in a site for the disposal of high level radioactive waste may still retard radionuclide migration and thereby help the geosphere to function as a barrier.     

废弃泥浆底部真空−上部堆载预压模型试验研究

针对工程泥浆回填废弃矿坑处置的安全问题,开展底部真空和上部堆载预压处理废弃工程泥浆的模型试验,探讨该技术在废弃矿坑回填处置工程应用的可行性。试验结果表明,底部真空和上部堆载预压使得泥浆含水率显著降低及泥土的强度明显提高,处理一个月后,含水率从初始450%降低至95%～105%,体积减量达到73.4%;不排水强度由初始为0的状态提高至9.8～13.4 kPa。在初始的静置阶段,泥浆颗粒沉积存在重力分异现象,粗颗粒在底部沉积有助于缓解真空预压过程中淤堵问题。底部真空作用下,泥浆中孔隙水渗流方向并非完全一维向下,在径向存在水力梯度。处理后泥土压缩性与软土相近,渗透性优于软土。基于试验结果和大应变固结理论,考虑泥浆的自重固结以及压缩性与渗透性的非线性变化,利用有限差分法分析了单次回填厚度对泥浆层固结时间和减量效果的影响,提出了现场实施的工艺参数建议。     

山西（交城）花岗岩体地质环境与理化特征研究

本论文对交城花岗岩体的地质环境、工程力学和理化特征作了初步研究。认为交城岗花岩体的地质构造稳定、水文地质条件良好,岩性均匀,故选择交城花岗岩作为研究主岩,并对典型核素在填隙物和花岗岩上的吸附性能进行了试验。     

辽宁省危险废物管理战略研究

随着环保工作的深入,特别是“非典”之后,危险废物管理已引起政府高度重视。辽宁作为国家重化工业基地,危险废物产生量加上历史积累量居全国首位;由于历史原因,存在处置能力低、技术落后、管理起步晚、严重滞后等问题,严重威胁环境安全。妥善解决这些问题是全新课题。通过借鉴国内外危险废物管理方面的理论与实践经验,开展了辽宁省危险废物管理战略性研究,从减量化、资源化、再利用及最终安全处置方面分析,围绕提高危险废物利用处置能力,加快处置设施建设,提出合理规划布局及所应遵循的原则,促进危险废物利用处置应采取的政策性措施及加强管理等建议,最终实现全省危险废物在未来“十一五”期间安全处置的目标,为建设和谐辽宁提供环境安全。     

高放废物处置库甘肃北山预选区同位素水文学研究及设想

甘肃省北山地区是我国高放废物处置库场址重要预选区之一,花岗岩是处置库候选围岩。10余年来,在北山地区开展了水文地质和同位素水文学调查、研究工作,为场址评价提供了重要的水文地质依据。今后,在深入开展预选区水文地质研究工作中,应进一步开展同位素水文学研究,示踪地下水的补给来源,揭示水循环过程,测定地下水滞留时间和流速等,以获得高放废物处置场址特性评价所需的水文地质参数资料。