Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

关岭-贞丰石漠化治理示范区植被覆盖变化及其对气候因子的响应

为揭示喀斯特石漠化治理示范区植被覆盖变化以及气候因子对植被覆盖变化的影响,利用2006—2015年Landsat 30 m/16 d分辨率影像数据,采用最大合成法、NDVI差值指数和相关、偏相关分析法,系统分析示范区归一化植被指数的时空变化特征及其与气候因子的关系。结果表明:(1)2006—2015年最大NDVI平均值为0.39,NDVI较高覆盖区域在示范区南北边界,而较低覆区域以花江南岸为主;(2)2006年以来示范区极低(-1.210)、低(-0.669)和中等(-0.729)植被覆盖度呈减少趋势,高(1.359)和极高(1.247)植被覆盖度增加,整体上呈显著增加趋势;(3)本月NDVI与本月、上月、上上月降雨量和气温的相关性均通过显著水平0.05检验,且本月NDVI与本月降雨量相关性高于本月气温(RNDVI降雨 =0.782),本月NDVI与上月气温相关性高于上月降雨量(RNDVI气温 =0.771);(4)在月尺度上,示范区植被生长对降雨量无滞后期,而对气温存在1个月的滞后期。      

Mapping fractional landscape soils and vegetation components from Hyperion satellite imagery using an unsupervised machine-learning workflow

An unsupervised machine-learning workflow is proposed for estimating fractional landscape soils and vegetation components from remotely sensed hyperspectral imagery. The workflow is applied to EO-1 Hyperion satellite imagery collected near Ibirací, Minas Gerais, Brazil. The proposed workflow includes subset feature selection, learning, and estimation algorithms. Network training with landscape feature class realizations provide a hypersurface from which to estimate mixtures of soil (e.g. 0.5 exceedance for pixels: 75% clay-rich Nitisols, 15% iron-rich Latosols, and 1% quartz-rich Arenosols) and vegetation (e.g. 0.5 exceedance for pixels: 4% Aspen-like trees, 7% Blackberry-like trees, 0% live grass, and 2% dead grass). The process correctly maps forests and iron-rich Latosols as being coincident with existing drainages, and correctly classifies the clay-rich Nitisols and grasses on the intervening hills. These classifications are independently corroborated visually (Google Earth) and quantitatively (random soil samples and crossplots of field spectra). Some mapping challenges are the underestimation of forest fractions and overestimation of soil fractions where steep valley shadows exist, and the under representation of classified grass in some dry areas of the Hyperion image. These preliminary results provide impetus for future hyperspectral studies involving airborne and satellite sensors with higher signal-to-noise and smaller footprints.     

Assessing soil salinity using WorldView-2 multispectral images in Timpaki,Crete, Greece

Salinization is one of the major soil degradation threats occurring worldwide. This study evaluates the feasibility of operational surface soil salinity mapping based on state-of-the-art Earth Observation (EO) products captured by sensors on-board WorldView-2 (WV2) and Landsat 8 satellites. The proposed methods are tested in Timpaki, south-central Crete,Greece, where brackish water irrigation puts soil health at risk of soil salinization. In all cases, EO products are calibrated against soil samples collected from bare soil locations. Results indicate a moderate correlation of observed EC_e values with the investigated remote sensing parameters. Regarding sensitivity to saline soil, the yellow band displays higher values. Comparison between methods used in the literature shows that those developed specifically for soil salinity, and especially index S5, perform better. The proposed ‘detection index’ and 3D PCA transformation methodology perform reasonably well in detecting areas with high EC_e values and provide a simple and effective operational alternative for saline topsoil detection and mapping.     

Soil salinity and vegetation cover change detection from multi-temporal remotely sensed imagery in Al Hassa Oasis in Saudi Arabia

Detecting soil salinity changes and its impact on vegetation cover are necessary to understand the relationships between these changes in vegetation cover. This study aims to determine the changes in soil salinity and vegetation cover in Al Hassa Oasis over the past 28 years and investigates whether the salinity change causing the change in vegetation cover. Landsat time series data of years 1985, 2000 and 2013 were used to generate Normalized Difference Vegetation Index (NDVI) and Soil Salinity Index (SI) images, which were then used in image differencing to identify vegetation and salinity change/no-change for two periods. Soil salinity during 2000–2013 exhibits much higher increase compared to 1985–2000, while the vegetation cover declined to 6.31% for the same period. Additionally, highly significant (p < 0.0001) negative relationships found between the NDVI and SI differencing images, confirmed the potential long-term linkage between the changes in soil salinity and vegetation cover.     

Late Pleistocene and Holocene Afromontane vegetation and headwater wetland dynamics within the Eastern Mau Forest,Kenya

The Mau Forest Complex is Kenya's largest fragment of Afromontane forest, providing critical ecosystem services, and has been subject to intense land use changes since colonial times. It forms the upper catchment of rivers that drain into major drainage networks, thus supporting the livelihoods of millions of Kenyans and providing important wildlife areas. We present the results of a sedimentological and palynological analysis of a Late Pleistocene–Holocene sediment record of Afromontane forest change from Nyabuiyabui wetland in the Eastern Mau Forest, a highland region that has received limited geological characterization and palaeoecological study. Sedimentology, pollen, charcoal, X-ray fluorescence and radiocarbon data record environmental and ecosystem change over the last ~16 000 cal a bp. The pollen record suggests Afromontane forests characterized the end of the Late Pleistocene to the Holocene with dominant taxa changing from Apodytes, Celtis, Dracaena, Hagenia and Podocarpus to Cordia, Croton, Ficus, Juniperus and Olea. The Late Holocene is characterized by a more open Afromontane forest with increased grass and herbaceous cover. Continuous Poaceae, Cyperaceae and Juncaceae vegetation currently cover the wetland and the water level has been decreasing over the recent past. Intensive agroforestry since the 1920s has reduced Afromontane forest cover as introduced taxa have increased (Pinus, Cupressus and Eucalyptus).     

The relationship between groundwater and natural vegetation in Qaidam Basin

To accurately evaluate ecological risks trigged by groundwater exploitation, it must be clarified the relationship between vegetation and groundwater. Based on remote sensing data sets MOD13Q1, groundwater table depth (WTD) and total dissolved solids (TDS), the relationship between groundwater and natural vegetation was analyzed statistically in the main plain areas of Qaidam Basin. The results indicate that natural vegetation is groundwater-dependent in areas where WTD is less than 5.5 m and TDS is less than 7.5 g/L. Aquatic vegetation, hygrophytic vegetation and hygrophytic saline-alkali tolerant vegetation are mainly distributed in areas with WTD <1.1 m. Salt-tolerant and mesophytic vegetation mainly occur in areas with WTD of 1.4-3.5 m, while the xerophytic vegetation isprimarily present in areas where WTD ranges from 1.4 m to 5.5 m. Natural vegetation does not necessarily depend on groundwater in areas with WTD >5.5 m. For natural vegetation, the most suitable water TDS is less than 1.5 g/L, the moderately suitable TDS is 1.5-5.0 g/L, the basically suitable TDS is 5.0-7.5 g/L, and the unsuitable TDS is more than 7.5 g/L.     

Polar WRF模式海冰密集度方案对北极海雾模拟效果的个例研究

全球变暖的背景下,北极航线的常规通航甚至商业运营有望实现,而海雾会严重影响航道上船只的航行安全。海冰的存在使海气之间相互作用变得更为复杂,是研究北极海雾不可忽略的因素。船载观测发现,与中纬度常见平流冷却雾形成时气温下降速度往往超过海水降温速度不同,北极海雾发生时海冰的存在还会使海水降温速度超过空气降温速度。然而目前海冰分布是否会影响模式模拟海雾的准确性还不得而知,因此本文利用Polar WRF（Polar Weather Research and Forecasting）模式模拟了中国第七次北极考察中观测到的一次海雾过程,并进行海冰密集度敏感性试验。通过与船载观测和欧洲中期天气预报中心再分析数据比对发现,在低浮冰区内（海冰密集度小于50%）考虑海冰分布时可以更加准确地刻画潜热通量与水汽通量,模拟出与观测事实相符的表层空气降温与增湿过程以及相对湿度的变化,因此能够更好地刻画海雾的三维结构及其生消演变。     

基于时序遥感的庐山自然保护区植被分类及其变化分析

自然保护区是生物多样性最丰富的区域,针对近年来庐山自然保护区森林生物多样性进行调查,了解保护区内植被的分布及其变化,对于保护庐山境内的林业资源具有重要的意义.论文利用2015-2018年Proba-Ⅴ卫星100m分辨率5d植被指数产品,使用最大值合成法、Hants时间序列谐波分析方法对数据进行平滑降噪处理,并采用随机森...     

气候变化对石羊河流域生态环境的影响分析

利用石羊河流域1959—2018年气象、水文和卫星遥感资料,采用线性倾向率、滑动t检验和相关系数(Pearson)等方法,分析石羊河流域内生态环境因素的变化事实及相互关系,得到气候变化对流域生态环境的影响程度。结果表明：石羊河流域气温呈显著上升趋势,增温速度为下游0.42℃·(10 a)^-1>中游0.36℃·(10 a)^-1>上游0.35℃·(10 a)^-1,近10 a增温最显著,较20世纪60年升高了1.67℃。四季气温均呈显著上升趋势,增温速度为冬季>秋季>春季>夏季。降水呈缓慢增加趋势,增幅为上游8.3 mm·(10 a)^-1>中游7.0 mm·(10 a)^-1>下游4.1 mm·(10 a)^-1,近10 a增加最显著,较20世纪60年代增加了17%。四季降水呈弱增加趋势,增加幅度为夏季>春季>秋季>冬季。河流流量基本持平,植被覆盖面积和归一化植被指数(NDVI)显著增大。近20 a流域气候...