Composition and major sources of organic compounds in urban aerosols

Total suspended particles (TSP), collected during June 2002 to July 2003 in Guangzhou, a typical economically developed city in South China, were analyzed for the organic compound compositions using gas chromatography–mass spectrometry (GC/MS). Over 140 organic compounds were detected in the aerosols and grouped into different classes including n-alkanes, hopanoids, polycyclic aromatic hydrocarbons, alkanols, fatty acids, dicarboxylic acids excluding oxalic acid, polyols/polyacids, lignin products, phytosterols, phthalates and water-soluble sugars. The total amounts of the identified organic compounds including unresolved complex mixture (UCM) ranged from 3112 ng/m³ in spring to 5116 ng/m³ in winter, comprising on seasonal average 2.8% of TSP. Primary organic compounds peaked in winter although there are no heating systems burning fuels in Guangzhou. The highest saccharide levels occurred in fall due to agricultural activities. This study demonstrated that utilization of fossil fuels, biomass burning, soil resuspension and plastic/refuse burning are the major contributors to the identified organic compounds in the urban atmosphere of South China.     

The influence of water retention curve hysteresis on the stability of unsaturated soil slopes

Hysteresis is a common feature exhibited in hydraulic properties of an unsaturated soil. The movement of wetting front and the hysteresis effect are important factors which impact the shear strength of the unsaturated soil and the mechanics of shallow landslides. These failures are mainly triggered by the deepening of the wetting front accompanied by a decrease in matric suction induced by infiltration. This research establishes a method for determining a stability analysis of unsaturated infinite soil slopes, integrating the influence of infiltration and the water retention curve hysteresis. Furthermore, the present stability analysis method including the infiltration model and the advanced Mohr–Coulomb failure criterion calculates the variations of the safety factor (FS) in accordance with different slope angle, depth and hydrological processes. The experimentally measured data on the effect of hysteresis are also carried out for comparison. Numerical analyses, employing both wetting and drying hydraulic behaviour of unsaturated soil, are performed to study the difference in soil‐water content as observed in the experiments. The simulating approximations also fully responded to the experimental data of sand box. The results suggest that the hysteresis behaviour affect the distribution of soil‐water content within the slope indeed. The hysteresis made the FS values a remarkable recovery during the period of non‐rainfall in a rainfall event. The appropriate hydraulic properties of soil (i.e. wetting or drying) should be used in accordance with the processes that unsaturated soil actually experience. This method will enable us to acquire more accurate matric suction head and the unsaturated soil‐shear strength as it changes with the hysteretic flow, in order to calculate into the stability analysis of shallow landslides. An advanced understanding of the process mechanism afforded by this method is critical to realizing a reliable and appropriate design for slope stabilization. It also offers some immediate reference information to the disaster reduction department of the government. Copyright © 2011 John Wiley & Sons, Ltd.     

Rate and historical change of direct recharge from precipitation constrained by unsaturated zone profiles of chloride and oxygen‐18 in dry river bed of North China Plain

Quantifying of direct recharge derived from precipitation is crucial for assessing sustainability of well‐irrigated agriculture. In the North China Plain, the land use is dominated by groundwater‐irrigated farmland where the direct recharge derived from precipitation and irrigation. To characterize the mean rate and historical variance of direct recharge derived from precipitation, unsaturated zone profiles of chloride and δ¹⁸O in the dry river bed of the Beiyishui River were employed. The results show that archival time scale of the profile covers the duration from 1980 to 2002 (corresponding to depths from 5 to 2 m) which is indicated by matching the δ¹⁸O peaks in the isotope profile with the aridity indexes gained by instrumental records of annual precipitation and annual potential evaporation. Using the chloride mass balance method, the mean rate of the direct recharge corresponding to the archival time scale is estimated to be 3·8 ± 0·8 mm year^?1, which accounts for about 0·7% of the long‐term average annual precipitation. Further, the direct recharge rates vary from 2·1 to 6·8 mm year^?1 since 1980. Despite the subhumid climate, the estimate of recharge rates is in line with other findings in semiarid regions. The low rate of direct recharge is considered as a result of the relative dry climate in recent decades. In dry river bed, unsaturated zone profiles of chloride and δ¹⁸O combined with instrumental records could offer valuable information about the direct recharge derived from precipitation during droughts. Copyright © 2011 John Wiley & Sons, Ltd.     

三峡库区千将坪滑坡滑带土干-湿循环条件下强度特性试验研究

三峡库区滑坡的失稳,主要是水库水位的升降、大气降雨和人类活动等因素的影响引起的,滑坡的滑带土在水的反复浸泡作用下,其强度降低是导致大量古滑坡复活或产生新生型滑坡的主要原因。通过对千将坪滑坡滑带土在干―湿循环试验（DWC）条件下与天然非饱和土CU试验结果比较,研究了干-湿循环条件下滑坡滑带土强度特性及其变形特性,揭示了千将坪滑坡失稳机制。     

孔隙介质毛细滞回简化模型研究

土-水特征曲线的研究是非饱和孔隙介质研究的重要部分。完整的土-水特征曲线包括初始脱湿曲线（IDC）、主吸湿线(MWC)和主脱湿线(MDC)3部分。传统的土-水特征曲线实验需要花费较长的时间和精力。以文献中的试验数据为依据,对非饱和土土-水特征关系和岩石的汞注入抽出试验的滞回现象进行了深入研究,提出一个经验模型来模拟MDC曲线。如果已根据试验得到了孔隙介质的IDC和MWC,此模型只需要一个参数,即可得到增量形式的MDC。通过与试验结果相比较,验证了模型对MDC模拟的有效性。     

Total Lipid and Fatty Acid Classes in Decomposing Mangrove Leaves of <Emphasis Type="Italic">Bruguiera gymnorrhiza</Emphasis> and <Emphasis Type="Italic">Kandelia candel</Emphasis>: Significance with respect to Lipid Input

Changes in the concentration of total lipid and fatty acids (FAs) during the decomposition of mangrove leaves were investigated by field experiments using yellow leaves of Bruguiera gymnorrhiza (L.) Lamk. and Kandelia candel (L.) Druce, in order to quantify mangrove contribution to lipid and fatty acid inputs to marine sediments. Total lipid and total FA in the fresh (green and yellow) and decomposing leaves of both species were significantly higher during winter than summer. During decomposition, total lipid content and FA concentration, in particular branched chain fatty acids (BrFAs) and bacterial fatty acids (BFAs), increased to a maximum concentration in 45 days during winter and in 17 days during summer. Lipids were lost faster in K. candel leaf detritus than in B. gymnorrhiza leaf detritus in which >90% of the total lipid original weight was lost during the summer experiment and <60% during the winter experiment. The changes in the concentrations of total lipids and FAs in the decomposing leaves also indicate that mangrove leaves are significant sources of fatty acids and probably other lipid compounds to estuarine ecosystems and that tidal waters transport the lipids and FAs adsorbed to particulate matter from mangroves to adjacent estuarine sediments and the ocean.     

Study of Adsorption Isotherm Curves of Amino Acids on the Kaolinite

This paper studies the adsorption isotherm curves of four amino acids (glyucine,aspartic acid,glutamic acid and lysine)and the effects of existences of different concentrations of Cu(Ⅱ) on them.Both the adsorption isotherm of the amino acids on the kaolinite and that when the copper ion Cu(Ⅱ） exists belong to the Langmuir type.The slopes of these adsorption isotherm increase with the increasing concentrations of Cu(Ⅱ） added.It can be explained in terms of formation of the type(Ⅰ） ternary surface complexes in these systems.The regular pattern of the effects of copper ion Cu(Ⅱ) on the adsorption isotherm of amino acids on the kaolinite is identical with that of its effects on the exchange and adsorption percentage E(%)-pH on the kaolinite in the same system.