Geochemical Eccentricity of Ground Water Allied to Weathering of Basalts from the Deccan Volcanic Province,India: Insinuation on CO<Subscript>2</Subscript> Consumption

Analyses of 72 samples from Upper Panjhara basin in the northern part of Deccan Plateau, India, indicate that geochemical incongruity of groundwater is largely a function of mineral composition of the basaltic lithology. Higher proportion of alkaline earth elements to total cations and HCO₃>Cl + SO₄ reflect weathering of primary silicates as chief source of ions. Inputs of Cl, SO₄, and NO₃ are related to rainfall and localized anthropogenic factors. Groundwater from recharge area representing Ca + Mg–HCO₃ type progressively evolves to Ca + Na–HCO₃ and Na–Ca–HCO₃ class along flow direction replicates the role of cation exchange and precipitation processes. While the post-monsoon chemistry is controlled by silicate mineral dissolution + cation exchange reactions, pre-monsoon variability is attributable chiefly to precipitation reactions + anthropogenic factors. Positive correlations between Mg vs HCO₃ and Ca + Mg vs HCO₃ supports selective dissolution of olivine and pyroxene as dominant process in post-monsoon followed by dissolution of plagioclase feldspar and secondary carbonates. The pre-monsoon data however, points toward the dissolution of plagioclase and precipitation of CaCO₃ supported by improved correlation coefficients between Na + Ca vs HCO₃ and negative correlation of Ca vs HCO₃, respectively. It is proposed that the eccentricity in the composition of groundwater from the Panjhara basin is a function of selective dissolution of olivine > pyroxene followed by plagioclase feldspar. The data suggest siallitization (L < R and R _k) as dominant mechanism of chemical weathering of basalts, stimulating monosiallitic (kaolinite) and bisiallitic (montmorillonite) products. The chemical denudation rates for Panjhara basin worked out separately for the ground and surface water component range from 6.98 to 36.65 tons/km²/yr, respectively. The values of the CO₂ consumption rates range between 0.18 × 10⁶ mol//km²/yr (groundwater) and 0.9 × 10⁶ mol/km²/yr (surface water), which indicates that the groundwater forms a considerable fraction of CO₂ consumption, an inference, that is, not taken into contemplation in most of the studies.     

Structural evolution of the Bayanhongor region, west-central Mongolia

Most of previous models suggest that the Central Asia Orogenic Belt grew southward in the Phanerozoic. However, in the Bayanhongor region in west-central Mongolia, volcanic arc, accretionary prism, ophiolite, and passive margin complexes accreted northeastward away from the Baydrag micro-continent, and hence the region constitutes the southwestern part of a crustal-scale syntaxis close to the west. The syntaxis should be original, because presumably reorientation due to strike-slip faulting can be ignored. It is reconfirmed that the Baydrag eventually collided with another micro-continent (the Hangai) to the northeast. A thick sedimentary basin developed along the southern passive margin of the Hangai micro-continent. This region is also characterized by an exhumed metamorphosed accretionary complex and a passive margin complex, which are both bounded by detachment faults as well as basal reverse faults which formed simultaneously as extrusion wedges. This part of the Central Asia Orogenic Belt lacks exhumed crystalline rocks as observed in the Himalayas and other major collisional orogenic belts. In addition, we identified two phases of deformation, which occurred at each phase of zonal accretion as D1 through Cambrian and Devonian, and a synchronous phase of final micro-continental collision of Devonian as D2. The pre-collisional ocean was wide enough to be characterized by a mid-ocean ridge and ocean islands. Two different structural trends of D1 and D2 are observed in accretionary complexes formed to the southwest of the late Cambrian mid-ocean ridge. That is, the relative plate motions on both sides of the mid-ocean ridge were different. Accretionary complexes and passive margin sediments to the northeast of the mid-ocean ridge also experienced two periods of deformation but show the same structural trend. Unmetamorphosed cover sediments on the accretionary prism and on the Hangai micro-continent experienced only the D2 event due to micro-continental collision. These unmetamorphosed sediments form the hanging walls of the detachment faults. Moreover, they were at least partly derived from an active volcanic arc formed at the margin of the Baydrag micro-continent.     

Comparison of numerical models of two debris flows in the Cortina d’ Ampezzo area,Dolomites, Italy

The accurate prediction of runout distances, velocities and the knowledge of flow rheology can reduce the casualties and property damage produced by debris flows, providing a means to delineate hazard areas, to estimate hazard intensities for input into risk studies and to provide parameters for the design of protective measures. The application of most of models that describe the propagation and deposition of debris flow requires detailed topography, rheological and hydrological data that are not always available for the debris-flow hazard delineation and estimation. In the Cortina d’Ampezzo area, Eastern Dolomites, Italy, most of the slope instabilities are represented by debris flows; 325 debris-flow prone watersheds have been mapped in the geomorphological hazard map of this area. We compared the results of simulations of two well-documented debris flows in the Cortina d’Ampezzo area, carried on with two different single-phase, non-Newtonian models, the one-dimensional DAN-W and the two-dimensional FLO-2D, to test the possibility to simulate the dynamic behaviour of a debris flow with a model using a limited range of input parameters. FLO-2D model creates a more accurate representation of the hazard area in terms of flooded area, but the results in terms of runout distances and deposits thickness are similar to DAN-W results. Using DAN-W, the most appropriate rheology to describe the debris-flow behaviour is the Voellmy model. When detailed topographical, rheological and hydrological data are not available, DAN-W, which requires less detailed data, is a valuable tool to predict debris-flow hazard. Parameters obtained through back-analysis with both models can be applied to predict hazard in other areas characterized by similar geology, morphology and climate.     

姬塬油田长4＋5砂岩储层孔隙类型与成岩作用

通过常规物性、岩石及铸体薄片、重矿物、X射线衍射、扫描电镜等多项测试方法,对鄂尔多斯盆地姬塬油田长4 5含油砂体的岩石学特征、成岩作用、储集类型进行了分析和研究。长4 5储层孔隙主要以粒间孔和长石溶孔为主,粒间溶孔次之,孔隙组合一般以粒间孔和溶孔-粒间孔为主。本区破坏性成岩作用包括机械压实作用、石英及长石的次生加大、碳酸盐胶结作用等,其中压实作用是造成本区砂岩原生孔隙大量丧失的主要原因。建设性成岩作用为溶蚀作用、绿泥石粘土膜形成作用,但溶蚀作用产生的次生孔隙对储层物性的改善不足。     

测井仪器的故障分析与排除思路

TYSC-3Q与PSJ-2型数字测井仪是目前煤田测井中常用的二种测井仪器,在使用过程中难免发生诸如测井控制故障、声速探管故障、密度三侧向探管故障、井温、井液电阻率探管故障、电法面板故障、数字测井面板故障、电测井故障等常见故障类型。通过对各类故障因素进行剖析,指出了故障易发生的部位,并详细的介绍了检查的方法及故障的排除步骤。     

Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.     

冀西北长城纪宣龙式铁矿层中微体植物化石的发现及其意义

本文研究的是笔者等在冀西北长城系串岭沟组宣龙式铁矿层中发现的微体植物化石,这些化石都保存在铁质叠层石(肾状赤铁矿)和铁质核形石(鲕状赤铁矿)的基本层中。微化石以丝状体为主,部分为球状体。归属于原核生物蓝藻门颤藻科的两个属和色球藻科的一个属。化石层同位素年龄约在1800—1757Ma。这些化石与北美冈弗林特组微化石比较,既有些相似,又有些区别。该化石的发现为研究铁矿的成因,指示沉积环境及层位对比都很有意义。     

Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.     

The bimodal rift-related Juscelândia volcanosedimentary sequence in central Brazil: Mesoproterozoic extension and Neoproterozoic metamorphism

The Barro Alto Complex and Juscelândia volcanosedimentary sequence are exposed in the central part of the Neoproterozoic Brasília belt of central Brazil. The former is a large (approximately 150 km long), boomerang-shaped, mafic-ultramafic, layered complex formed by two different intrusions metamorphosed under granulite facies. These rocks are tectonically overlain by rocks of the Juscelândia volcanosedimentary sequence, represented mainly by biotite-gneiss and amphibolite, or amphibolite facies metamorphic equivalents of rhyolite and basalt, respectively. New SIMS U–Pb zircon data and Sm–Nd isochron data presented herein help clarify the igneous and metamorphic evolution of the Juscelândia volcanosedimentary sequence, as well as its relationship with the Barro Alto Complex. Zircon grains from two biotite gneisses were analyzed by SIMS (SHRIMP) and indicate Mesoproterozoic dates, approximately 1.28 Ga, interpreted as the time of bimodal volcanism in a tectonic setting transitional between a continental rift and an ocean basin. Metamorphism is constrained by Sm–Nd garnet-whole-rock isochrons for garnet amphibolite and pelitic schists of the Juscelândia sequence, as well as for clinopyroxene-garnet amphibolite and garnet granulite of the Barro Alto Complex, which give ages between 0.74 and 0.76 Ga, in agreement with SIMS dates for metamorphic zircon rims. These new data are significant, because they establish that a single metamorphic event affected both the Barro Alto Complex and the Juscelândia sequence. Based on these new data, we present a modified tectonic model for the Brasília belt.